Tag: M.W=100-150

Formula: C8H10O2. Islam, S; Khan, W in [Islam, Sayedul; Khan, Wahab] Bangladesh Univ Engn & Technol BUET, Fac Engn, Dept Chem, Dhaka 1000, Bangladesh published Synthesis of Dendritic Ligand Assisted Zn/Cu Bimetallic Nanoparticles as a Highly Active Green Catalyst for Chemoselective Oxidation and Reduction Reaction in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

The dendritic ligand 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:1) 4a, 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:2) 4b, and 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (2:1) 4cbimetallic nanoparticles (NPs) were synthesized successfully by following the co-complexation route in which the desired molar ratio of Zn and Cu was confirmed by the obtained results of electron diffraction X-ray and X-ray fluorescence spectroscopy analysis. The average particle size of these NPs was detected as 15-20 nm from transmission electron microscopy investigations and agglomerate spherical surface morphology was found by scanning electron microscopy, whereas the face-centered cubic structure of these bimetallic NPs was observed by X-ray diffraction assessment. Also, the formation of the ligand was proven by IR,(HNMR)-H-1,(CNMR)-C-13, and elemental analysis. Remarkably, the chemoselective oxidation of aromatic alcohols to the corresponding aldehydes or ketones at 25 min and reduction of aromatic nitro substituents to the corresponding aniline at 20 min in aqueous medium at room temperature have been studied by the most effective catalyst Zn/Cu (2:1) 4cNPs among other molar ratios of Zn/Cu (1:1)4aand Zn/Cu (1:2) 4bNPs under atmospheric air (O-2) conditions with good to excellent yields. This green catalytic approach of Zn/Cu (2:1) 4cNPs catalytic was easily recovered by simple filtration and recycled at least five consecutive runs without a noticeable loss of its catalytic effectiveness.

Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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An article Palladium-catalyzed one-pot synthesis of 2-substituted quinazolin-4(3H)-ones from o-nitrobenzamide and alcohols WOS:000640769800011 published article about CASCADE SYNTHESIS; QUINAZOLINONES; SYSTEM; 4(3H)-QUINAZOLINONES; 2-NITROBENZAMIDES; AMINOBENZAMIDES; CYCLIZATION; CHEMISTRY; EFFICIENT; STRATEGY in [Wang, Ke; Chen, Hao; Dai, Xinyan; Huang, Xupeng; Feng, Zhiqiang] Chinese Acad Med Sci & Peking Union Med Coll, Inst Mat Med, Beijing Key Lab Act Subst Discovery & Drugabil Ev, 1 Xiannongtan St, Beijing 100050, Peoples R China in 2021, Cited 41. SDS of cas: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Palladium-catalyzed 2-substituted quinazolin-4(3H)-one formation from readily available o-nitrobenzamides and alcohols using hydrogen transfer is described. Various quinazolin-4(3H)-ones were obtained in good to high yields. The cascade reaction including alcohol oxidation, nitro reduction, condensation, and dehydrogenation occurs without any added reducing or oxidizing agent.

SDS of cas: 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Wang, K; Chen, H; Dai, XY; Huang, XP; Feng, ZQ or send Email.

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Recommanded Product: (4-Methoxyphenyl)methanol. In 2021 ORG LETT published article about AEROBIC OXIDATION; SILICA; EPOXIDATION; TEMPO in [Tian, Yangwu; Guo, Xiaqun; Li, Meichao; Li, Chunmei; Hu, Xinquan; Jin, Liqun; Sun, Nan; Hu, Baoxiang; Shen, Zhenlu] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China; [Li, Chunmei] Shaoxing Univ, Sch Chem & Chem Engn, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China in 2021, Cited 38. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Herein, we designed and synthesized an SBA-15 supported 1-methyl-2-azaadamanane N-oxyl (1-Me-AZADO) and investigated its catalytic performance for selective oxidation of alcohols under Anelli’s conditions. The first example of immobilization of 1-Me-AZADO was very important to advance the oxgenation effectively because this supported N-oxyl has excellent catalytic activity for oxidation of alcohols to carbonyl compounds, and more importantly, it can be conveniently recovered and reused at least 6 times without significant effect on its catalytic efficiency.

Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.. Recommanded Product: (4-Methoxyphenyl)methanol

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Recommanded Product: (4-Methoxyphenyl)methanol. Guo, P; Wang, K; Jin, WJ; Xie, H; Qi, LL; Liu, XY; Shu, XZ in [Guo, Peng; Wang, Ke; Jin, Wen-Jie; Xie, Hao; Qi, Liangliang; Liu, Xue-Yuan; Shu, Xing-Zhong] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China published Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis in 2021, Cited 104. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Catalytic transformation of alcohols via metal-catalyzed cross-coupling reactions is very important, but it typically relies on a multistep procedure. We here report a dynamic kinetic cross-coupling approach for the direct functionalization of alcohols. The feasibility of this strategy is demonstrated by a nickel-catalyzed cross-electrophile arylation reaction of benzyl alcohols with (hetero)aryl electrophiles. The reaction proceeds with a broad substrate scope of both coupling partners. The electron-rich, electron-poor, and ortho-/meta-/para-substituted (hetero)aryl electrophiles (e.g., Ar-OTf, Ar-I, Ar-Br, and inert Ar-Cl) all coupled well. Most of the functionalities, including aldehyde, ketone, amide, ester, nitrile, sulfone, furan, thiophene, benzothiophene, pyridine, quinolone, Ar-SiMe3, Ar-Bpin, and Ar-SnBu3, were tolerated. The dynamic nature of this method enables the direct arylation of benzylic alcohol in the presence of various nucleophilic groups, including nonactivated primary/secondary/tertiary alcohols, phenols, and free indoles. It thus offers a robust alternative to existing methods for the precise construction of diarylmethanes. The synthetic utility of the method was demonstrated by a concise synthesis of biologically active molecules and by its application to peptide modification and conjugation. Preliminary mechanistic studies revealed that the reaction of in situ formed benzyl oxalates with nickel, possibly via a radical process, is an initial step in the reaction with aryl electrophiles.

Recommanded Product: (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Guo, P; Wang, K; Jin, WJ; Xie, H; Qi, LL; Liu, XY; Shu, XZ or send Email.

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Formula: C8H10O2. Authors Li, WZ; Wang, ZX in ROYAL SOC CHEMISTRY published article about in [Li, Wei-Ze; Wang, Zhong-Xia] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China; [Li, Wei-Ze; Wang, Zhong-Xia] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China; [Wang, Zhong-Xia] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China in 2021, Cited 99. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

alpha-Alkylation of methyldiarylphosphine oxides with (hetero)arylmethyl alcohols was performed under nickel catalysis. Various arylmethyl and heteroarylmethyl alcohols can be used in this transformation. A series of methyldiarylphosphine oxides were alkylated with 30-90% yields. Functional groups on the aromatic rings of methyldiarylphosphine oxides or arylmethyl alcohols including OMe, NMe2, SMe, CF3, Cl, and F groups can be tolerated. The conditions are also suitable for the alpha-alkylation reaction of dialkyl methylphosphonates.

Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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COA of Formula: C8H10O2. Authors Paul, A; Shipman, MA; Onabule, DY; Sproules, S; Symes, MD in ROYAL SOC CHEMISTRY published article about in [Paul, Avishek; Shipman, Michael A.; Onabule, Dolapo Y.; Sproules, Stephen; Symes, Mark D.] Univ Glasgow, Sch Chem, WestCHEM, Univ Ave, Glasgow G12 8QQ, Lanark, Scotland in 2021, Cited 30. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The enhancement of reactivity inside supramolecular coordination cages has many analogies to the mode of action of enzymes, and continues to inspire the design of new catalysts for a range of reactions. However, despite being a near-ubiquitous class of reactions in organic chemistry, enhancement of the reduction of carbonyls to their corresponding alcohols remains very much underexplored in supramolecular coordination cages. Herein, we show that encapsulation of small aromatic aldehydes inside a supramolecular coordination cage allows the reduction of these aldehydes with the mild reducing agent sodium cyanoborohydride to proceed with high selectivity (ketones and esters are not reduced) and in good yields. In the absence of the cage, low pH conditions are essential for any appreciable conversion of the aldehydes to the alcohols. In contrast, the specific microenvironment inside the cage allows this reaction to proceed in bulk solution that is pH-neutral, or even basic. We propose that the cage acts to stabilise the protonated oxocarbenium ion reaction intermediates (enhancing aldehyde reactivity) whilst simultaneously favouring the encapsulation and reduction of smaller aldehydes (which fit more easily inside the cage). Such dual action (enhancement of reactivity and size-selectivity) is reminiscent of the mode of operation of natural enzymes and highlights the tremendous promise of cage architectures as selective catalysts.

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Product Details of 105-13-5. Authors Choudhury, P; Behera, PK; Bisoyi, T; Sahu, SK; Sahu, RR; Prusty, SR; Stitgen, A; Scanlon, J; Kar, M; Rout, L in ROYAL SOC CHEMISTRY published article about in [Choudhury, Prabhupada; Behera, Pradyota Kumar; Bisoyi, Tanmayee; Sahu, Santosh Kumar; Sahu, Rashmi Ranjan; Prusty, Smruti Ranjita; Rout, Laxmidhar] Berhampur Univ, Dept Chem, Berhampur 760007, Odisha, India; [Stitgen, Abigail; Scanlon, Joseph] Ripon Coll, Dept Chem, Wisconsin Rapids, WI 54971 USA; [Sahu, Rashmi Ranjan; Kar, Manoranjan] IIT Patna, Dept Phys, Patna, Bihar, India; [Rout, Laxmidhar] Indian Inst Sci Educ & Res, Sch Chem Sci, Berhampur 760007, Odisha, India in 2021, Cited 25. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Herein, we report a new protocol for the dehydrogenative oxidation of aryl methanols using the cheap and commercially available catalyst CuSeO3 center dot 2H(2)O. Oxygen-bridged [Cu-O-Se] bimetallic catalysts are not only less expensive than other catalysts used for the dehydrogenative oxidation of aryl alcohols, but they are also effective under mild conditions and at low concentrations. The title reaction proceeds with a variety of aromatic and heteroaromatic methanol examples, obtaining the corresponding carbonyls in high yields. This is the first example using an oxygen-bridged copper-based bimetallic catalyst [Cu-O-Se] for dehydrogenative benzylic oxidation. Computational DFT studies reveal simultaneous H-transfer and Cu-O bond breaking, with a transition-state barrier height of 29.3 kcal mol(-1).

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Recommanded Product: (4-Methoxyphenyl)methanol. Authors Bolen, SD; Love, TE; Einstadter, D; Lever, J; Lewis, S; Persaud, H; Fiegl, J; Liu, RJ; Ali-Matlock, W; Bar-Shain, D; Caron, A; Misak, J; Wagner, T; Kauffman, E; Cook, L; Hebert, C; White, S; Kobaivanova, N; Cebul, R in SPRINGER published article about in [Bolen, Shari D.; Love, Thomas E.; Einstadter, Douglas; Lewis, Steven; Bar-Shain, David; Caron, Aleece; Cebul, Randall] Case Western Reserve Univ, Populat Hlth Res Inst, Ctr Hlth Care Res & Policy, MetroHlth Syst, Cleveland, OH 44106 USA; [Bolen, Shari D.; Love, Thomas E.; Einstadter, Douglas; Lever, Jonathan; Ali-Matlock, Wanda; Bar-Shain, David; Cebul, Randall] Better Hlth Partnership, Cleveland, OH USA; [Bolen, Shari D.; Love, Thomas E.; Einstadter, Douglas; Lewis, Steven; Caron, Aleece] Case Western Reserve Univ, Dept Med, MetroHlth Syst, Cleveland, OH 44106 USA; [Bolen, Shari D.; Love, Thomas E.; Einstadter, Douglas; Persaud, Harry; Cebul, Randall] Case Western Reserve Univ, Dept Populat & Quantitat Hlth Sci, Cleveland, OH 44106 USA; [Fiegl, Jordan] Univ Hosp, Dept Data Sci & Analyt, Cleveland, OH USA; [Liu, Rujia] Medpace Inc, Cincinnati, OH USA; [Bar-Shain, David] Case Western Reserve Univ, Dept Pediat, Cleveland, OH 44106 USA; [Misak, James] Case Western Reserve Univ, Dept Family Med, MetroHlth Syst, Cleveland, OH 44106 USA; [Wagner, Todd] Signature Hlth, Mentor, OH USA; [Kauffman, Erick] Neighborhood Family Practice, Cleveland, OH USA; [Cook, Lloyd] Med Mutual, Cleveland, OH USA; [Hebert, Christopher] Mercy Hlth, Cincinnati, OH USA; [Kobaivanova, Nana] Cleveland Clin, Cleveland, OH USA in 2021, Cited 28. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

BACKGROUND: Accelerated translation of real-world interventions for hypertension management is critical to improving cardiovascular outcomes and reducing disparities. OBJECTIVE: To determine whether a positive deviance approach would improve blood pressure (BP) control across diverse health systems. DESIGN: Quality improvement study using 1-year cross sections of electronic health record data over 5 years (2013-2017). PARTICIPANTS: Adults >= 18 with hypertension with two visits in 2 years with at least one primary care visit in the last year (N = 114,950 at baseline) to a primary care practice in Better Health Partnership, a regional health improvement collaborative. INTERVENTIONS: Identification of a positive deviant and dissemination of this system’s best practices for control of hypertension (i.e., accurate/repeat BP measurement; timely follow-up; outreach; standard treatment algorithm; and communication curriculum) using 3 different intensities (low: Learning Collaborative events describing the best practices; moderate: Learning Collaborative events plus consultation when requested; and high: Learning Collaborative events plus practice coaching). MAIN MEASURES: We used a weighted linear model to estimate the pre- to post-intervention average change in BP control (< 140/90 mmHg) for 35 continuously participating clinics. KEY RESULTS: BP control post-intervention improved by 7.6% [95% confidence interval (CI) 6.0-9.1], from 67% in 2013 to 74% in 2017. Subgroups with the greatest absolute improvement in BP control included Medicaid (12.0%, CI 10.5-13.5), Hispanic (10.5%, 95% CI 8.4-12.5), and African American (9.0%, 95% CI 7.7-10.4). Implementation intensity was associated with improvement in BP control (high: 14.9%, 95% CI 0.2-19.5; moderate: 5.2%, 95% CI 0.8-9.5; low: 0.2%, 95% CI-3.9 to 4.3). CONCLUSIONS: Employing a positive deviance approach can accelerate translation of real-world best practices into care across diverse health systems in the context of a regional health improvement collaborative (RHIC). Using this approach within RHICs nationwide could translate to meaningful improvements in cardiovascular morbidity and mortality. Recommanded Product: (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Bolen, SD; Love, TE; Einstadter, D; Lever, J; Lewis, S; Persaud, H; Fiegl, J; Liu, RJ; Ali-Matlock, W; Bar-Shain, D; Caron, A; Misak, J; Wagner, T; Kauffman, E; Cook, L; Hebert, C; White, S; Kobaivanova, N; Cebul, R or send Email.

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Quality Control of (4-Methoxyphenyl)methanol. Authors Sun, ZL; Yang, XL; Yu, XF; Xia, LH; Peng, YH; Li, Z; Zhang, Y; Cheng, JB; Zhang, KS; Yu, JQ in ELSEVIER published article about in [Sun, Zhaoli; Yang, Xiaolong; Xia, Linhong; Peng, Yanhua; Li, Zhuo; Zhang, Yan; Yu, Jianqiang] Qingdao Univ, Coll Chem & Chem Engn, 308 Ning Xia Rd, Qingdao 266071, Peoples R China; [Yu, Xue-Fang; Cheng, Jianbo] Yantai Univ, Sch Chem & Chem Engn, Lab Theoret & Computat Chem, 32 Qingquan Rd, Yantai 264005, Peoples R China; [Zhang, Kaisheng] Chinese Acad Sci, HFIPS, Inst Solid State Phys, Environm Mat & Pollut Control Lab, Hefei 230031, Peoples R China in 2021, Cited 55. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The recombination of photogenerated carriers seriously restricts their utilization efficiency in photocatalysis. Herein, surface oxygen vacancies (SOVs) were constructed in Pd-Bi2MoO6 interface to bridge ultra-low loading Pd cluster and Bi2MoO6 semiconductor (Pd/BMO-SOVs). It was found SOVs in Pd/Bi2MoO6-x serve as Electron Bridge to bridge ultra-low loading Pd cluster and Bi2MoO6-x, thus tremendously enhance utilization efficiency of photoexcited carriers and ultra-low loading Pd active sites for blue LED driven selective oxidation reaction. The Pd(0.05)/Bi2MoO6-SOVs exhibited 57.8 % conversion for selection oxidation of benzyl which are 6.5, 3.3 and 2.1 times higher than pristine Bi2MoO6, Bi2MoO6-x and Pd(0.05)/Bi2MoO6. Combined with theoretical calculations, SOVs was proposed as Electron Bridge to transfer photogenerated electrons from Bi2MoO6-x to ultra-low loading Pd clusters, thus greatly boosting separation and utilization efficiency of photogenerated electron-hole pairs.

Quality Control of (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Sun, ZL; Yang, XL; Yu, XF; Xia, LH; Peng, YH; Li, Z; Zhang, Y; Cheng, JB; Zhang, KS; Yu, JQ or send Email.

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Name: (4-Methoxyphenyl)methanol. Authors Bolen, SD; Love, TE; Einstadter, D; Lever, J; Lewis, S; Persaud, H; Fiegl, J; Liu, RJ; Ali-Matlock, W; Bar-Shain, D; Caron, A; Misak, J; Wagner, T; Kauffman, E; Cook, L; Hebert, C; White, S; Kobaivanova, N; Cebul, R in SPRINGER published article about in [Bolen, Shari D.; Love, Thomas E.; Einstadter, Douglas; Lewis, Steven; Bar-Shain, David; Caron, Aleece; Cebul, Randall] Case Western Reserve Univ, Populat Hlth Res Inst, Ctr Hlth Care Res & Policy, MetroHlth Syst, Cleveland, OH 44106 USA; [Bolen, Shari D.; Love, Thomas E.; Einstadter, Douglas; Lever, Jonathan; Ali-Matlock, Wanda; Bar-Shain, David; Cebul, Randall] Better Hlth Partnership, Cleveland, OH USA; [Bolen, Shari D.; Love, Thomas E.; Einstadter, Douglas; Lewis, Steven; Caron, Aleece] Case Western Reserve Univ, Dept Med, MetroHlth Syst, Cleveland, OH 44106 USA; [Bolen, Shari D.; Love, Thomas E.; Einstadter, Douglas; Persaud, Harry; Cebul, Randall] Case Western Reserve Univ, Dept Populat & Quantitat Hlth Sci, Cleveland, OH 44106 USA; [Fiegl, Jordan] Univ Hosp, Dept Data Sci & Analyt, Cleveland, OH USA; [Liu, Rujia] Medpace Inc, Cincinnati, OH USA; [Bar-Shain, David] Case Western Reserve Univ, Dept Pediat, Cleveland, OH 44106 USA; [Misak, James] Case Western Reserve Univ, Dept Family Med, MetroHlth Syst, Cleveland, OH 44106 USA; [Wagner, Todd] Signature Hlth, Mentor, OH USA; [Kauffman, Erick] Neighborhood Family Practice, Cleveland, OH USA; [Cook, Lloyd] Med Mutual, Cleveland, OH USA; [Hebert, Christopher] Mercy Hlth, Cincinnati, OH USA; [Kobaivanova, Nana] Cleveland Clin, Cleveland, OH USA in 2021, Cited 28. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

BACKGROUND: Accelerated translation of real-world interventions for hypertension management is critical to improving cardiovascular outcomes and reducing disparities. OBJECTIVE: To determine whether a positive deviance approach would improve blood pressure (BP) control across diverse health systems. DESIGN: Quality improvement study using 1-year cross sections of electronic health record data over 5 years (2013-2017). PARTICIPANTS: Adults >= 18 with hypertension with two visits in 2 years with at least one primary care visit in the last year (N = 114,950 at baseline) to a primary care practice in Better Health Partnership, a regional health improvement collaborative. INTERVENTIONS: Identification of a positive deviant and dissemination of this system’s best practices for control of hypertension (i.e., accurate/repeat BP measurement; timely follow-up; outreach; standard treatment algorithm; and communication curriculum) using 3 different intensities (low: Learning Collaborative events describing the best practices; moderate: Learning Collaborative events plus consultation when requested; and high: Learning Collaborative events plus practice coaching). MAIN MEASURES: We used a weighted linear model to estimate the pre- to post-intervention average change in BP control (< 140/90 mmHg) for 35 continuously participating clinics. KEY RESULTS: BP control post-intervention improved by 7.6% [95% confidence interval (CI) 6.0-9.1], from 67% in 2013 to 74% in 2017. Subgroups with the greatest absolute improvement in BP control included Medicaid (12.0%, CI 10.5-13.5), Hispanic (10.5%, 95% CI 8.4-12.5), and African American (9.0%, 95% CI 7.7-10.4). Implementation intensity was associated with improvement in BP control (high: 14.9%, 95% CI 0.2-19.5; moderate: 5.2%, 95% CI 0.8-9.5; low: 0.2%, 95% CI-3.9 to 4.3). CONCLUSIONS: Employing a positive deviance approach can accelerate translation of real-world best practices into care across diverse health systems in the context of a regional health improvement collaborative (RHIC). Using this approach within RHICs nationwide could translate to meaningful improvements in cardiovascular morbidity and mortality. Welcome to talk about 105-13-5, If you have any questions, you can contact Bolen, SD; Love, TE; Einstadter, D; Lever, J; Lewis, S; Persaud, H; Fiegl, J; Liu, RJ; Ali-Matlock, W; Bar-Shain, D; Caron, A; Misak, J; Wagner, T; Kauffman, E; Cook, L; Hebert, C; White, S; Kobaivanova, N; Cebul, R or send Email.. Name: (4-Methoxyphenyl)methanol

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