Tag: M.W=100-150

Name: (4-Methoxyphenyl)methanol. In 2021 CHEMSUSCHEM published article about BORROWING HYDROGEN; ALPHA-ALKYLATION; AROMATIC-AMINES; BOND FORMATION; COMPLEXES; EFFICIENT; KETONES; STRATEGY; LIGANDS; IMINES in [Lan, Xiao-Bing; Ye, Zongren; Yang, Chenhui; Li, Weikang; Liu, Jiahao; Huang, Ming; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Mat Sci & Engn, PCFM Lab, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China; [Lan, Xiao-Bing] Xiangnan Univ, Sch Chem & Biol & Environm Engn, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423000, Hunan, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

The implementation of non-noble metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of non-noble metal catalysts. Herein, we report a tungsten-catalyzed N-alkylation reaction of anilines with primary alcohols via BH/HA. This phosphine-free W(phen)(CO)(4) (phen=1,10-phenthroline) system was demonstrated as a practical and easily accessible in-situ catalysis for a broad range of amines and alcohols (up to 49 examples, including 16 previously undisclosed products). Notably, this tungsten system can tolerate numerous functional groups, especially the challenging substrates with sterically hindered substituents, or heteroatoms. Mechanistic insights based on experimental and computational studies are also provided.

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Product Details of 105-13-5. Authors Yamamoto, Y; Ota, M; Kodama, S; Michimoto, K; Nomoto, A; Ogawa, A; Furuya, M; Kawakami, K in AMER CHEMICAL SOC published article about in [Yamamoto, Yuki; Ota, Miyuto; Kodama, Shintaro; Michimoto, Kazuki; Nomoto, Akihiro; Ogawa, Akiya] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Sakai, Osaka 5998531, Japan; [Furuya, Mitsunori; Kawakami, Kiminori] Mitsubishi Chem Corp, Sci & Innovat Ctr, Yokohama, Kanagawa 2278502, Japan in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A green method for the oxidation of alcohols to carboxylic acids was developed using a novel co-catalytic system based on gold, silver, and copper catalysts. This reaction system was conducted under atmospheric oxygen in water and mild conditions to selectively oxidize 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid, as a building block for polyethylene furanoate, which is a 100% bio-based, future alternative to the petroleum-based polyethylene terephthalate. Furthermore, various primary alcohols were conveniently oxidized to their corresponding carboxylic acids in up to quantitative yields.

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Safety of (4-Methoxyphenyl)methanol. Authors Aydin, BO; Anil, D; Demir, Y in WILEY-V C H VERLAG GMBH published article about in [Aydin, Busra O.; Anil, Derya] Ataturk Univ, Dept Chem, Fac Sci, Erzurum, Turkey; [Anil, Derya] Ataturk Univ, Tech Sci Vocat Sch, Dept Chem & Chem Proc Technol, Erzurum, Turkey; [Demir, Yeliz] Ardahan Univ, Nihat Delibalta Gole Vocat Sch, Dept Pharm Serv, Ardahan, Turkey in 2021, Cited 53. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Fused pyrimidines, especially pyrazolo[3,4-d]pyrimidines, are among the most preferred building blocks for pharmacology studies, as they exhibit a broad spectrum of biological activity. In this study, new derivatives of pyrazolo[3,4-d]pyrimidine were synthesized by alkylation of the N1 nitrogen atom. We synthesized 3-iodo-1H-pyrazolo[3,4-d]pyrimidin-4-amine 2 from commercially available aminopyrazolopyrimidine 1 using N-iodosuccinimide as an iodinating agent. The synthesis of compound 2 started with nucleophilic substitution of 3-iodo-1H-pyrazolo[3,4-d]pyrimidin-4-amine with R-X (X: -OMs, -Br, -Cl), affording N-alkylated pyrazolo[3,4-d]pyrimidine. We performed this synthesis using a weak inorganic base and the mild temperature was also used for a two-step procedure to generate N-alkylated pyrazolo[3,4-d]pyrimidine derivatives. Also, all compounds were tested for their ability to inhibit acetylcholinesterase (AChE) and the human carbonic anhydrase (hCA) isoforms I and II, with K-i values in the range of 15.41 +/- 1.39-63.03 +/- 10.68 nM for AChE, 17.68 +/- 1.92-66.27 +/- 5.43 nM for hCA I, and 8.41 +/- 2.03-28.60 +/- 7.32 nM for hCA II. Notably, compound 10 was the most selective and potent CA I inhibitor with a significant selectivity ratio of 26.90.

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Authors Hu, M; Jiang, Y; Sun, N; Hu, BX; Shen, ZL; Hu, XQ; Jin, LQ in ROYAL SOC CHEMISTRY published article about C BOND FORMATION; ALPHA-ALKYLATION; UNACTIVATED AMIDES; KETONES; METHYLATION; ESTERS; ARYLACETONITRILES; FUNCTIONALIZATION; COMPLEXES; METHANOL in [Hu, Miao; Jiang, Yong; Sun, Nan; Hu, Baoxiang; Shen, Zhenlu; Hu, Xinquan; Jin, Liqun] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Peoples R China; [Jin, Liqun] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China in 2021, Cited 65. Application In Synthesis of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

An efficient method for the Ni-catalyzed C3-alkylation of indoles using readily available alcohols as the alkylating reagents has been developed. The alkylation was addressed with an air and moisture-stable binuclear nickel complex ligated by tetrahydroquinolin-8-one as the effective pre-catalyst. The newly developed transformation could accommodate a broad substrate scope including primary/secondary benzylic and aliphatic alcohols and substituted indoles. Mechanistic studies suggested that the reaction proceeds through a borrowing hydrogen pathway.

Application In Synthesis of (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Hu, M; Jiang, Y; Sun, N; Hu, BX; Shen, ZL; Hu, XQ; Jin, LQ or send Email.

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Recently I am researching about SOLUBLE RECEPTOR TIE-2; CARDIOVASCULAR MORTALITY; ANGPTL4; DISEASE; RISK; ANGIOGENESIS; BIOMARKER; EVENTS, Saw an article supported by the . Published in WILEY in HOBOKEN ,Authors: Aarsetoy, R; Ueland, T; Aukrust, P; Michelsen, AE; de la Fuente, RL; Ponitz, V; Brugger-Andersen, T; Grundt, H; Staines, H; Nilsen, DWT. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. Application In Synthesis of (4-Methoxyphenyl)methanol

Background Plasma levels of angiopoietin-2 (ANGPT2) and angiopoietin-like 4 protein (ANGPTL4) reflect different pathophysiological aspects of cardiovascular disease. We evaluated their association with outcome in a hospitalized Norwegian patient cohort (n = 871) with suspected acute coronary syndrome (ACS) and validated our results in a similar Argentinean cohort (n = 982). Methods A cox regression model, adjusting for traditional cardiovascular risk factors, was fitted for ANGPT2 and ANGPTL4, respectively, with all-cause mortality and cardiac death within 24 months and all-cause mortality within 60 months as the dependent variables. Results At 24 months follow-up, 138 (15.8%) of the Norwegian and 119 (12.1%) of the Argentinian cohort had died, of which 86 and 66 deaths, respectively, were classified as cardiac. At 60 months, a total of 259 (29.7%) and 173 (17.6%) patients, respectively, had died. ANGPT2 was independently associated with all-cause mortality in both cohorts at 24 months [hazard ratio (HR) 1.27 (95% confidence interval (CI), 1.08-1.50) for Norway, and HR 1.57 (95% CI, 1.27-1.95) for Argentina], with similar results at 60 months [HR 1.19 (95% CI, 1.05-1.35) (Norway), and HR 1.56 (95% CI, 1.30-1.88) (Argentina)], and was also significantly associated with cardiac death [HR 1.51 (95% CI, 1.14-2.00)], in the Argentinean population. ANGPTL4 was significantly associated with all-cause mortality in the Argentinean cohort at 24 months [HR 1.39 (95% CI, 1.15-1.68)] and at 60 months [HR 1.43 (95% CI, 1.23-1.67)], enforcing trends in the Norwegian population. Conclusions ANGPT2 and ANGPTL4 were significantly associated with outcome in similar ACS patient cohorts recruited on two continents. Clinical Trial Registration ClinicalTrials.gov Identifier: NCT00521976. ClinicalTrials.gov Identifier: NCT01377402.

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An article Mesoporous (001)-TiO2 nanocrystals with tailored Ti3+ and surface oxygen vacancies for boosting photocatalytic selective conversion of aromatic alcohols WOS:000644065100024 published article about EXPOSED 001 FACETS; SOOT OXIDATION ACTIVITY; VISIBLE PHOTOCATALYST; DOPED TIO2; PERCENTAGE; NANOCOMPOSITES; PERFORMANCE; NANOSHEETS; CATALYSTS; CRYSTALS in [Li, Dianfeng; Wang, Jinguo; Xu, Fengxia; Zhang, Nianchen; Men, Yong] Shanghai Univ Engn Sci, Sch Chem & Chem Engn, Shanghai 201620, Peoples R China in 2021, Cited 46. COA of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Selective conversion of aromatic alcohols to value-added chemicals is becoming an emerging research hotspot in heterogeneous photocatalysis, but its critical challenge is how to construct highly efficient photocatalysts. Herein, mesoporous (001)-TiO2 nanocrystals with tailored Ti3+ and surface oxygen vacancies have been fabricated by a facile hydrothermal route, showing remarkably boosted photoactivity for selective conversion of aromatic alcohols to carbonyl compounds in water medium under visible-light irradiation. Results attest that the remarkably boosted photoactivity was mainly correlated with the strong synergetic effect of exposed (001) facets, Ti3+ self-doping, and surface oxygen vacancies, leading to the enhanced reactant (aromatic alcohols and O-2) activation via the high surface energy of (001) facets, the improved visible-light absorbance via the intrinsic band gap narrowing, and the escalated photoelectron-hole separation efficiency via Ti3+ and surface oxygen vacancies acting as electron sinks. Meanwhile, a plausible photocatalytic mechanism for selective conversion of aromatic alcohols to carbonyl compounds has been elucidated in detail based on active species identified by capture experiments. It is hoped that this work can deliver some new insights into the rational design of highly efficient photocatalysts applied in future green organic selective transformation reactions.

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I found the field of Chemistry very interesting. Saw the article Fe Doped MIL-101/Graphene Nanohybrid for Photocatalytic Oxidation of Alcohols Under Visible-Light Irradiation published in 2021. Application In Synthesis of (4-Methoxyphenyl)methanol, Reprint Addresses Yang, ZW (corresponding author), Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Polymer Mat Gansu Prov, Key Lab Ecofunct Polymer Mat,Minist Educ, Lanzhou 730070, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A novel photoactive porous material of GR/FeMIL-101 based on FeMIL-101 metal organic frameworks (MOFs) was successfully synthesized via a simple hydrothermal method. The structural and photoelectric properties of the GR/FeMIL-101 was analyzed by XRD, SEM, TEM, TGA, XPS, UV-vis DRS, FT-IR, PL and EIS methods. The photocatalytic performance for the selective oxidation of benzyl alcohol with GR/FeMIL-101 as catalysts was evaluated under visible light irradiation. The results showed that the GR/FeMIL-101 nanohybrid had better photocatalytic performance than both of FeMIL-101 and the pristine MIL-101. It was further found that the incorporation of Fe and MIL-101 caused valence fluctuations of Fe3+/Fe2+ which improved the absorption of visible-light and increased the separation efficiency of photogenerated charges. In addition, the combination of FeMIL-101 and GR could further promote the transfer rate of the photoelectrons. The mechanism of the reaction revealed that center dot O-2(-) was the dominating active specie in this reaction through active species trapping experiments. [GRAPHICS] .

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An article Synthesis of Glycosyl Fluorides by Photochemical Fluorination with Sulfur(VI) Hexafluoride WOS:000606842300036 published article about REDUCTION; GAS; SF6; BENZOPHENONE; POTENTIALS; ENERGIES; ION in [Kim, Sungjin; Khomutnyk, Yaroslav; Bannykh, Anton; Nagorny, Pavel] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA in 2021, Cited 42. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Safety of (4-Methoxyphenyl)methanol

This study describes a new convenient method for the photocatalytic generation of glycosyl fluorides using sulfur(VI) hexafluoride as an inexpensive and safe fluorinating agent and 4,4′-dimethoxybenzophenone as a readily available organic photocatalyst. This mild method was employed to generate 16 different glycosyl fluorides, including the substrates with acid and base labile functionalities, in yields of 43%-97%, and it was applied in continuous flow to accomplish fluorination on an 7.7 g scale and 93% yield.

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In 2021 MOL CATAL published article about SELECTIVE N-ALKYLATION; ONE-POT SYNTHESIS; BORROWING HYDROGEN; EFFICIENT CATALYSTS; BETA-ALKYLATION; IRIDIUM COMPLEX; ALCOHOLS; RUTHENIUM; SULFONAMIDES; AMINATION in [Wu, Di; Bu, Qingqing; Dai, Bin; Liu, Ning] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, North Fourth Rd, Shihezi 832003, Xinjiang, Peoples R China; [Guo, Cheng] Zhejiang Univ, Affiliated Hosp 2, Sch Med, Canc Inst, Hangzhou 310009, Zhejiang, Peoples R China in 2021, Cited 73. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. COA of Formula: C8H10O2

Multi-amino groups and nitrogen donors compound was discovered as an organocatalyst for N-alkylation of alcohols with amines in the presence of Mo(CO)6. The Mo(CO)6/organocatalyst binary system has shown to be a highly active catalyst for the N-alkylation reaction between alcohols and amines with excellent tolerance of variable starting materials bearing different functional groups. Of particular note, this method possessing a superiority selectivity in the synthesis of N-alkylated amines or imines, which can be controlled by the reaction temperature. The cooperative catalysis mechanism in combination of Mo(CO)6 with organocatalyst was elucidated by control experiments.

COA of Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Recently I am researching about CATALYZED SELECTIVE OXIDATION; AEROBIC OXIDATION; HYDROGEN-PEROXIDE; C-N; COPPER; METAL; ALDEHYDES; NANOPARTICLES; COMPLEXES; EFFICIENT, Saw an article supported by the DST, IndiaDepartment of Science & Technology (India) [CSIR/02/1151/20, SERB/EMR /2016/006898]; S&T department Govt. of Odisha [27562800512107/20/1919]; Planning and convergence department, Govt. of Odisha [L.N./716/P/ 2016]; University Grants Commission (UGC)University Grants Commission, India [F-4-5(58)/2014 (BSR/FRP)]; Oyster Scholar Fund; NSFNational Science Foundation (NSF) [CHE-1039925]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Behera, PK; Choudhury, P; Sahu, SK; Sahu, RR; Harvat, AN; McNulty, C; Stitgen, A; Scanlon, J; Kar, M; Rout, L. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. Recommanded Product: 105-13-5

Though concept of oxygen bridged bimetallic catalyst for organic reaction is not well understood. Herein, we have tried to explain the concept by experimental as well as its support by full DFT study. We report here a competent protocol for dehydrogenative oxidation of benzylic alcohol using an oxygen bridged bimetallic CuMoO4 nano catalyst. Careful demonstration reveals that oxidation is not effective either with mono-metallic Cu (II) or Mo(VI); instead combination of both the metals through the oxygen bridge [Cu-O-Mo] unexpectedly and interestingly catalyzed the reaction efficiently. The new concept is strongly supported by computational DFT study. DFT study reveals dehydrogenative oxidation is preferred at copper centre over molybdenum and aromatic benzyl alcohols are greatly stabilised. Interaction barrier energy of monometallic CuO and MoO3 catalyst is much higher than bimetallic CuMoO4. Hydrogen transfer has larger barrier heights for CuO (31.5 kcal/mol) and MoO3 (40.3 kcal/mol) than bimetallic CuMoO4.

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