Tag: 100-200

Pan, Cong-yi et al. published their research in Xiandai Tuliao Yu Tuzhuang in 2017 | CAS: 115-84-4

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Category: alcohols-buliding-blocks

Influence of molecular structure on transparency of powder coating in synthesis of polyester was written by Pan, Cong-yi;Liu, Liang;Luo, Qing;Wang, Wei-yue;Li, Yong. And the article was included in Xiandai Tuliao Yu Tuzhuang in 2017.Category: alcohols-buliding-blocks The following contents are mentioned in the article:

From the perspective of the raw materials of synthetic polyester resin, curing agent, leveling agent and so on were added to the resin synthesized by different monomers. After melt-extrusion, blending, grinding and sieving, spray it on the glass mirror plate to detect the impact of different synthetic monomer on transparency of coating film. At the same time, the acid value, crystallinity and other indicators of polyester resins were also tested to determine their impact on the transparency of polyester powder coating. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Category: alcohols-buliding-blocks).

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Metzger, Erich et al. published their research in Helvetica Chimica Acta in 1986 | CAS: 115-84-4

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Category: alcohols-buliding-blocks

3,7-Dioxaazelaamides as ionophores for lithium ion selective liquid membrane electrodes was written by Metzger, Erich;Aeschimann, Roland;Egli, Martin;Suter, Gaby;Dohner, Rene;Ammann, Daniel;Dobler, Max;Simon, Wilhelm. And the article was included in Helvetica Chimica Acta in 1986.Category: alcohols-buliding-blocks The following contents are mentioned in the article:

Neutral lipophilic dioxaazelaamides I (R = H, Me, CMe2; R1 = H, Me, Et; R2 = H, Me, Bu) were prepared and incorporated in lipophilic liquid membranes. Li+-Na+ selectivities of these were ≤80; the membranes allow reliable measurements of Li+ in blood serum within the clin. concentration range. The structure of the LiSCN complex with I (R = H; R1 = R2 = Me) was determined by x-ray crystallog. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Category: alcohols-buliding-blocks).

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Kobayashi, Masaki et al. published their research in Organic & Biomolecular Chemistry in 2021 | CAS: 106-21-8

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Synthetic Route of C10H22O

Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles was written by Kobayashi, Masaki;Yamaguchi, Hiroki;Suzuki, Takeyuki;Obora, Yasushi. And the article was included in Organic & Biomolecular Chemistry in 2021.Synthetic Route of C10H22O The following contents are mentioned in the article:

A simple method for the cross β-alkylation of linear alcs. R(CH2)2OH (R = octyl, cyclohexylmethyl, Ph, 3-benzyl-4-hydroxybutyl, etc.) with benzyl alcs. R1CH2OH (R1 = Ph, cyclopropyl, thiophen-2-yl, etc.) in the presence of DMF-stabilized iridium nanoparticles was developed. The nanoparticles were prepared in one-step and thoroughly characterized. Furthermore, the optimum reaction conditions have a wide substrate scope and excellent product selectivity. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Synthetic Route of C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Synthetic Route of C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Matsumoto, Michiaki et al. published their research in Separation Science and Technology in 1997 | CAS: 115-84-4

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Category: alcohols-buliding-blocks

Recovery of boric acid from wastewater by solvent extraction was written by Matsumoto, Michiaki;Kondo, Kazuo;Hirata, Makoto;Kokubu, Shuzo;Hano, Tadashi;Takada, Tokio. And the article was included in Separation Science and Technology in 1997.Category: alcohols-buliding-blocks The following contents are mentioned in the article:

An extraction system for the recovery of boric acid using 2-butyl-2-ethyl-1,3-propanediol (BEPD) as an extractant was studied. Loss of the extractant to the aqueous solution was lowered by using 2-ethylhexanol as a diluent. The extraction equilibrium of boric acid with BEPD was clarified, and the equilibrium constants for various diluents were determined Furthermore, continuous operation for the recovery of boric acid using mixer-settlers for extraction and stripping was successfully conducted for 100 h. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Category: alcohols-buliding-blocks).

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Dantignana, Valeria et al. published their research in ACS Central Science in 2017 | CAS: 106-21-8

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.SDS of cas: 106-21-8

Chemoselective Aliphatic C-H Bond Oxidation Enabled by Polarity Reversal was written by Dantignana, Valeria;Milan, Michela;Cusso, Olaf;Company, Anna;Bietti, Massimo;Costas, Miquel. And the article was included in ACS Central Science in 2017.SDS of cas: 106-21-8 The following contents are mentioned in the article:

Using nonracemic manganese complexes, alkanes, alcs., amides, and amines underwent chemoselective and regioselective hydroxylation with H2O2 at unactivated C-H bonds when performed in fluorinated alc. solvents (particularly hexafluoroisopropanol and 2,2,2-trifluoroethanol) to yield monohydroxylated products with improved chemoselectivities relative to reactions performed in MeCN. The initial hydroxylated product is oxidized much less readily in fluoroalc. solvents than in MeCN. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8SDS of cas: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.SDS of cas: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Ardiansah, Bayu et al. published their research in Chemical Communications (Cambridge, United Kingdom) in 2021 | CAS: 106-21-8

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Category: alcohols-buliding-blocks

Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides was written by Ardiansah, Bayu;Tanimoto, Hiroki;Tomohiro, Takenori;Morimoto, Tsumoru;Kakiuchi, Kiyomi. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2021.Category: alcohols-buliding-blocks The following contents are mentioned in the article:

Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides such as 3-phenylpropyl azide, (3-azidopentyl)benzene, 1,12-diazidooctadecane, 7-azido-3,7-dimethyloctan-1-ol, etc. were converted to the corresponding carbonyl compounds such as 2-phenylpropanal, 1-phenylpentan-2-one, 12-oxooctadecanal, 1-phenylpropan-2-one, N-benzylpropan-2-amine, etc. and 2-phenylimino-indan-1,3-dione without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Category: alcohols-buliding-blocks).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Grolik, Jaroslaw et al. published their research in Tetrahedron Letters in 2022 | CAS: 106-21-8

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.HPLC of Formula: 106-21-8

Regioselective synthesis of the 4,5-dialkoxy-2-nitroanilines bearing two different alkoxy substituents was written by Grolik, Jaroslaw;Reka, Pawel;Gorczyca, Magdalena;Stadnicka, Katarzyna. And the article was included in Tetrahedron Letters in 2022.HPLC of Formula: 106-21-8 The following contents are mentioned in the article:

This article reported the regioselective and chemoselective synthesis of 4,5-dialkoxy-2-nitroanilines I [R1 = Me, Et, i-Bu, etc.; R2 = Me, i-Pr, n-Bu, etc.] substituted with two alkoxys at C-4 and C-5. Here the optimization protocol of the transetherification reaction used to synthesize 20 new compounds with good to excellent yields (50-92%) was showed. A simple and efficient one-step procedure was described that could be applied to obtain a significant number of pharmacol. active compounds, including antimalarial drug Primaquine analogs. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8HPLC of Formula: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.HPLC of Formula: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Shu, Wei et al. published their research in Organic Letters in 2019 | CAS: 106-21-8

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.HPLC of Formula: 106-21-8

γ-Alkylation of Alcohols Enabled by Visible-Light Induced 1,6-Hydrogen Atom Transfer was written by Shu, Wei;Zhang, Hui;Huang, Yan. And the article was included in Organic Letters in 2019.HPLC of Formula: 106-21-8 The following contents are mentioned in the article:

Site-selective remote alkylation of alc. is attractive but challenging in organic synthesis. Herein, we report a novel visible-light mediated γ-alkylation of alc. derivatives via the formation of Csp3-Csp3 bond through Csp3-H bond functionalization under mild conditions. The use of sulfamate esters enables the directed, otherwise rare 1,6-HAT to generate γ-selective C-centered radical, which is complementary to δ-selective 1,5-HAT of alcs. This redox-neutral protocol provides a general and operationally simple method to access γ-alkylated alcs. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8HPLC of Formula: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.HPLC of Formula: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Berger, F. M. et al. published their research in Journal of Pharmacology and Experimental Therapeutics in 1952 | CAS: 115-84-4

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Reference of 115-84-4

Anticonvulsant activity of carbamate esters of certain 2,2-disubstituted 1,3-propanediols was written by Berger, F. M.. And the article was included in Journal of Pharmacology and Experimental Therapeutics in 1952.Reference of 115-84-4 The following contents are mentioned in the article:

cf. C.A. 45, 265a; 46, 1651d. The intensity and duration of the anticonvulsant action against electroshock seizures in mice were determined for the 2,2-disubstituted dimethyl, methylethyl, methylisopropyl, diethyl, ethylbutyl, ethylphenyl, dipropyl, and diphenyl derivatives of 1,3-propanediol. The diols and their monocarbamates were short-acting and weak. The dicarbamates showed a longer and stronger anticonvulsant action. The cyclic carbonate esters, which may also be called 5,5-disubstituted 1,3-dioxan-2-one derivatives, showed a weak and transient anticonvulsant action. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Reference of 115-84-4).

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Reference of 115-84-4

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Bernane, A. et al. published their research in Latvijas PSR Zinatnu Akademijas Vestis, Kimijas Serija in 1987 | CAS: 115-84-4

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Product Details of 115-84-4

2-Substituted 1,3-propanediols as extractants of boric acid was written by Bernane, A.;Svarcs, E.;Timoteus, H.;Hansens, T.. And the article was included in Latvijas PSR Zinatnu Akademijas Vestis, Kimijas Serija in 1987.Product Details of 115-84-4 The following contents are mentioned in the article:

The distribution of H3BO3 in the organic and aqueous phases in extraction by diisobutyl-1,3-propanediol, 2-octyl-1,3-propanediol, 2-ethyl-2-butyl-1,3-propanediol, and 1-(3-bromophenyl)-2,2-dimethyl-1,3-propanediol was studied. The effects of diluents (HCCl3, PhMe, acetophenone, isoamyl alc., C2Cl4, decyl alc.) and salting out agents (NaCl, KCl, MgSO4, MgCl2) in H3BO3 extraction were determined The extraction effectiveness of the substituted propanediols was closely similar. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Product Details of 115-84-4).

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Product Details of 115-84-4

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts