Tag: 100-200

Growth of p-Type Tin(II) Monoxide Thin Films by Atomic Layer Deposition from Bis(1-dimethylamino-2-methyl-2propoxy)tin and H₂O was written by Han, Jeong Hwan;Chung, Yoon Jang;Park, Bo Keun;Kim, Seong Keun;Kim, Hyo-Suk;Kim, Chang Gyoun;Chung, Taek-Mo. And the article was included in Chemistry of Materials in 2014.Related Products of 14123-48-9 This article mentions the following:

A reliable at. layer deposition (ALD) scheme to fabricate p-type Sn monoxide (SnO) films at 90-210 oC is presented for the 1st time using the Sn(II) precursor, bis(1-dimethylamino-2-methyl-2-propoxy)tin, and H₂O. The self-limiting features of the SnO ALD process could clearly be observed under wide process conditions. The growth per cycle of the SnO ALD films were varied from 0.61 to 0.08 Å/cycle as the growth temperature was increased from 90 to 210°, and the O/Sn at. composition ratio of ∼1.2 was maintained at all studied temperatures Amorphous and crystalline SnO films were obtained at 90-120° and 150-210°, resp. The deposited SnO films exhibited p-type conductivity with Hall mobility values of 0.4-2.9 cm²/V•s. The carrier concentration and resistivity are in the range of 3.4×1017-1.6×1018 cm^-3 and 4.9-14.5 Ω•cm, resp. In the experiment, the researchers used many compounds, for example, 1-(Dimethylamino)-2-methylpropan-2-ol (cas: 14123-48-9Related Products of 14123-48-9).

1-(Dimethylamino)-2-methylpropan-2-ol (cas: 14123-48-9) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Related Products of 14123-48-9

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Davis-Beirut Reaction: A Photochemical Bronsted Acid Catalyzed Route to N-Aryl 2H-Indazoles was written by Kraemer, Niklas;Li, Clarabella J.;Zhu, Jie S.;Larach, Julio M.;Tsui, Ka Yi;Tantillo, Dean J.;Haddadin, Makhluf J.;Kurth, Mark J.. And the article was included in Organic Letters in 2019.HPLC of Formula: 80866-76-8 This article mentions the following:

The Davis-Beirut reaction provides access to 2H-indazoles from aromatic nitro compounds However, N-aryl targets have been traditionally challenging to access due to competitive alternate reaction pathways. Previously, the key nitroso imine intermediate was generated under alk. conditions, but as reported here, the photochem. of o-nitrobenzyl alcs. empowered Bronsted acid catalyzed conditions for accessing N-aryl targets. Anilines and alkyl amines give different outcomes under optimized conditions; the proposed mechanism was studied using quantum chem. calculations In the experiment, the researchers used many compounds, for example, (3-Methyl-2-nitrophenyl)methanol (cas: 80866-76-8HPLC of Formula: 80866-76-8).

(3-Methyl-2-nitrophenyl)methanol (cas: 80866-76-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.HPLC of Formula: 80866-76-8

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One-Pot Synthesis of B-Ring Ortho-Hydroxylated Sappanin-Type Homoisoflavonoids was written by Mrug, Galyna P.;Myshko, Nataliia V.;Bondarenko, Svitlana P.;Sviripa, Vitaliy M.;Frasinyuk, Mykhaylo S.. And the article was included in Journal of Organic Chemistry in 2019.Synthetic Route of C7H6O3 This article mentions the following:

A reliable method for the synthesis of B-ring hydroxylated homoisoflavonoids (e.g. I) and 3-hetarylmethyl chromones has been developed. The method involves an initial oxa-Diels-Alder reaction of ortho-quinone methides generated from aryl/hetaryl-substituted ortho-(N,N-dimethylaminomethyl)phenols with (2E)-3-(N,N-dimethylamino)-1-(2-hydroxyphenyl)prop-2-en-1-ones and the subsequent cascade of reactions. This synthetic strategy avoids conventional multistep protocols and does not require the protection of hydroxyl groups, thus allowing the facile synthesis of a library of various aromatic and heterocyclic analogs of naturally occurring homoisoflavonoids. In the experiment, the researchers used many compounds, for example, Benzo[d][1,3]dioxol-4-ol (cas: 69393-72-2Synthetic Route of C7H6O3).

Benzo[d][1,3]dioxol-4-ol (cas: 69393-72-2) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Synthetic Route of C7H6O3

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Extraction of flavonoids from Glycyrrhiza residues using deep eutectic solvents and its molecular mechanism was written by Yu, Qiang;Wang, Fan;Jian, Yating;Chernyshev, Victor M.;Zhang, Yu;Wang, Zhongming;Yuan, Zhenhong;Chen, Xiaoyan. And the article was included in Journal of Molecular Liquids in 2022.Electric Literature of C10H20O This article mentions the following:

The re-extraction of bioactive compounds from Chinese herb residues is significant for the maximum utilization of biomass resources. However, conventional alc. and aqueous solvents are unsuitable for recovering those compounds In this study, 14 deep eutectic solvents (DESs) were used to improve the efficiency of flavonoid extraction from Glycyrrhiza residues. The maximal total extraction rate (10.68 mg/g) for four flavonoids (liquiritin, isoliquiritin, liquiritigenin, and isoliquiritigenin) was achieved using choline chloride-glycolic acid as the DES under optimal conditions. The extraction rate was 83.03% higher than that by 60% ethanol, a traditional solvent. Anal. of the associated mol. mechanism based on d. functional theory showed that interactions between the solvent and liquiritin were dominated by hydrogen bonds followed by Van der Waals forces, whereas the bonding between the solvent and liquiritigenin only involved Van der Waals forces, thereby verifying the significance of the strength of hydrogen bonding in the DES-flavonoid extraction process. In the experiment, the researchers used many compounds, for example, (1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5Electric Literature of C10H20O).

(1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Electric Literature of C10H20O

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Towards a New Generation of Potential Antipsychotic Agents Combining D₂ and 5-HT_1A Receptor Activities was written by Cuisiat, Stephane;Bourdiol, Nathalie;Lacharme, Vincent;Newman-Tancredi, Adrian;Colpaert, Francis;Vacher, Bernard. And the article was included in Journal of Medicinal Chemistry in 2007.Reference of 69393-72-2 This article mentions the following:

We report the discovery and the synthesis of novel, potential antipsychotic compounds combining potent dopamine D₂ receptor antagonist and serotonin 5-HT_1A receptor agonist properties in the same mol. We describe the structure-activity relationship that lead us to the promising derivative: N-[(2,2-dimethyl-2,3-dihydro-benzofuran-7-yloxy)ethyl]-3-(cyclopent-1-enyl)-benzylamine 16. The latter has high affinity for D₂ and 5-HT_1A receptors, whereas it possesses only a weak affinity for 5-HT_2A sites. In cellular models of signal transduction, 16 behaves as a silent antagonist at rD₂ receptors while activating h5-HT_1A receptors with an efficacy at least equivalent to that of the prototypical 5-HT_1A agonist (±)-8-OH-DPAT. These dual actions confer a unique pharmacol. profile to the product. In a behavioral model predictive of pos. symptoms, 16 has an activity comparable to that of the typical antipsychotic haloperidol, while it is devoid of cataleptogenic effects. Although it produces behaviors characteristic of 5-HT_1A receptor activation in rats, these occur at doses 100 times higher than those with (±)-8-OH-DPAT. We believe that the relative balance of D₂ and 5-HT_1A actions in 16 is appropriate, possibly optimal, to ensure superior efficacy and tolerability over existing antipsychotic drugs. In the experiment, the researchers used many compounds, for example, Benzo[d][1,3]dioxol-4-ol (cas: 69393-72-2Reference of 69393-72-2).

Benzo[d][1,3]dioxol-4-ol (cas: 69393-72-2) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Reference of 69393-72-2

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Alcohol – Wikipedia,
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Novel pyrazole-3-carboxamide derivatives as cannabinoid-1 (CB1) antagonists: Journey from non-polar to polar amides was written by Sasmal, Pradip K.;Reddy, D. Srinivasa;Talwar, Rashmi;Venkatesham, B.;Balasubrahmanyam, D.;Kannan, M.;Srinivas, P.;Kumar, K. Shiva;Devi, B. Neelima;Jadhav, Vikram P.;Khan, Sanjoy K.;Mohan, Priya;Chaudhury, Hira;Bhuniya, Debnath;Iqbal, Javed;Chakrabarti, Ranjan. And the article was included in Bioorganic & Medicinal Chemistry Letters in 2011.Product Details of 42514-50-1 This article mentions the following:

The synthesis and biol. evaluation of novel pyrazole-3-carboxamide derivatives, e.g. I, as CB1 antagonists are described. As a part of eastern amide SAR, various chem. diverse motifs were introduced. In general, a range of modifications were well tolerated. Several mols. with high polar surface area were also identified as potent CB1 receptor antagonists. The in vivo proof of principle for weight loss is exemplified with a lead compound from this series. In the experiment, the researchers used many compounds, for example, 3-Amino-3-methylbutan-1-ol (cas: 42514-50-1Product Details of 42514-50-1).

3-Amino-3-methylbutan-1-ol (cas: 42514-50-1) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Product Details of 42514-50-1

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Capillary gas chromatographic separation performances of a tetraphenyl porphyrin stationary phase was written by Yan, Yuan;Wang, Zhenzhong;Zhang, Zitong;He, Zhen;Luo, Lun;Fan, Jing. And the article was included in Frontiers in Chemistry (Lausanne, Switzerland) in 2022.Formula: C10H20O This article mentions the following:

Tetra-Ph porphyrin (TPP) has enormous potential for use as gas chromatog. stationary phases because it has a distinctive extended π-π conjugated coplanar structure and a range of interesting properties such as a good solubility in dichloromethane, high m.p., and good thermal stability. In this work, a TPP column was successfully prepared using a static method. The column was nonpolar and had a high efficiency. The chromatog. selectivity of the TPP column was assessed. The TPP column showed superiority retention and higher resolution for alicyclic, aromatic mols. through ring matching and π-π stacking interaction comparable to HP-5MS column. The unique mechanisms through which the TPP column retained polychlorinated biphenyls allowed the peak pair of 2,2′,5-trichlorobiphenyl and 4,4′-dichlorobiphenyl to be resolved better on the TPP column than the HP-5MS column. The TPP column was thermally stable even at 260°C for 2 h and gave results of a high degree of precision (run-to-run and column-to-column) with relative standard deviations <0.05% and <4.96%, resp. The results indicated that porphyrin derivatives will be useful gas chromatog. stationary phases. In the experiment, the researchers used many compounds, for example, (1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5Formula: C10H20O).

(1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Formula: C10H20O

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Propylphosphonic anhydride (T3P) catalyzed one-pot synthesis of α-aminonitriles was written by Reddy, Sirigireddy Sudharsan;Reddy, Bhoomireddy Rajendra Prasad;Reddy, Peddiahgari Vasu Govardhana. And the article was included in Chinese Chemical Letters in 2015.Electric Literature of C8H8O2 This article mentions the following:

The Strecker reaction was performed via a one-pot three component condensation of heteroaromatic/aromatic aldehydes, secondary amines and trimethylsilyl cyanide in the presence of propylphosphonic anhydride (T3P) to accomplish the corresponding α-aminonitriles. The main advantages of this method are very short reaction time and excellent yields. In the experiment, the researchers used many compounds, for example, 3-Hydroxy-5-methylbenzaldehyde (cas: 60549-26-0Electric Literature of C8H8O2).

3-Hydroxy-5-methylbenzaldehyde (cas: 60549-26-0) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Electric Literature of C8H8O2

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Alcohol – Wikipedia,
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Diastereoselective Substitution Reactions of Acyclic β-Alkoxy Acetals via Electrostatically Stabilized Oxocarbenium Ion Intermediates was written by Ramdular, Amanda;Woerpel, K. A.. And the article was included in Organic Letters in 2022.Name: (1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol This article mentions the following:

Substitution reactions of acyclic β-alkoxy acetals proceeded with generally high diastereoselectivities (>90:10) to form the anti product. Mechanistic experiments supplemented with computational studies suggest that, upon activation of the acetal, the resulting oxocarbenium ion is electrostatically stabilized by the β-alkoxy group. This stabilization defines the conformation of the reactive intermediate, which can be attacked preferentially from the more exposed face, leading to the observed products. In the experiment, the researchers used many compounds, for example, (1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5Name: (1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol).

(1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Name: (1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol

Referemce:
Alcohol – Wikipedia,
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One-step solid-state fermentation for efficient erythritol production from the simultaneous saccharified crop wastes by incorporating immobilized cellulase was written by Liu, Xiaoyan;Dong, Xiujin;Zhong, Sidan;Xia, Jun;He, Jianlong;Deng, Yuanfang;Xu, Jiaxing. And the article was included in Industrial Crops and Products in 2022.Recommanded Product: 149-32-6 This article mentions the following:

Crop wastes are advantaged feedstocks for low-cost erythritol production via Yarrowia procedure, whereas a high amount of cellulose remains in the fermentative medium due to the lack of cellulase. The present study proposed a one-step solid-state fermentation (SSF) for erythritol production from oil crop waste that was simultaneous saccharified by the incorporated exogenous cellulase. Cellulase was immobilized in alginate-chitosan beads, and the outstanding performance of the immobilized cellulase in erythritol cultivation was proven based on its tolerance to pH and osmotic pressure, with high stability and reusability (83% of activity maintained after five cycles of utilization). Under the optimal condition of pH 6.0 and 0.01 g/g dry substrate with the immobilized cellulase addition of 1.5% (weight/weight), persistent cellulase activity accompanied by the efficient consumption of total sugar was detected during the cultivation. Enhanced erythritol production was achieved with the highest titer of 226.8 mg/g dry substrate in scale-up batch fermentation, when the fed-batch cultivation contributed to a considerable total amount of erythritol. Cost anal. suggests that the present process leads toward the development of eco-friendly and economically feasible erythritol production In the experiment, the researchers used many compounds, for example, (2R,3S)-rel-Butane-1,2,3,4-tetraol (cas: 149-32-6Recommanded Product: 149-32-6).

(2R,3S)-rel-Butane-1,2,3,4-tetraol (cas: 149-32-6) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Recommanded Product: 149-32-6

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