Category: alcohols-buliding-blocks

Category: alcohols-buliding-blocks. In 2021 CHEMSUSCHEM published article about BORROWING HYDROGEN; ALPHA-ALKYLATION; AROMATIC-AMINES; BOND FORMATION; COMPLEXES; EFFICIENT; KETONES; STRATEGY; LIGANDS; IMINES in [Lan, Xiao-Bing; Ye, Zongren; Yang, Chenhui; Li, Weikang; Liu, Jiahao; Huang, Ming; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Mat Sci & Engn, PCFM Lab, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China; [Lan, Xiao-Bing] Xiangnan Univ, Sch Chem & Biol & Environm Engn, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423000, Hunan, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

The implementation of non-noble metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of non-noble metal catalysts. Herein, we report a tungsten-catalyzed N-alkylation reaction of anilines with primary alcohols via BH/HA. This phosphine-free W(phen)(CO)(4) (phen=1,10-phenthroline) system was demonstrated as a practical and easily accessible in-situ catalysis for a broad range of amines and alcohols (up to 49 examples, including 16 previously undisclosed products). Notably, this tungsten system can tolerate numerous functional groups, especially the challenging substrates with sterically hindered substituents, or heteroatoms. Mechanistic insights based on experimental and computational studies are also provided.

Category: alcohols-buliding-blocks. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Lan, XB; Ye, ZR; Yang, CH; Li, WK; Liu, JH; Huang, M; Liu, Y; Ke, ZF or concate me.

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Safety of (4-Methoxyphenyl)methanol. Authors Epifanov, M; Mo, JY; Dubois, R; Yu, H; Sammis, GM in AMER CHEMICAL SOC published article about in [Epifanov, Maxim; Mo, Jia Yi; Dubois, Rudy; Yu, Hao; Sammis, Glenn M.] Univ British Columbia, Dept Chem, Columbia, BC V6T 1Z1, Canada in 2021, Cited 48. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Sulfuryl fluoride is a valuable reagent for the one-pot activation and derivatization of aliphatic alcohols, but the highly reactive alkyl fluorosulfate intermediates limit both the types of reactions that can be accessed as well as the scope. Herein, we report the SO2F2-mediated alcohol substitution and deoxygenation method that relies on the conversion of fluorosulfates to alkyl halide intermediates. This strategy allows the expansion of SO2F2-mediated one-pot processes to include radical reactions, where the alkyl halides can also be exploited in the one-pot deoxygenation of primary alcohols under mild conditions (52-95% yield). This strategy can also enhance the scope of substitutions to nucleophiles that are previously incompatible with one-pot SO2F2-mediated alcohol activation and enables substitution of primary and secondary alcohols in 54-95% yield. Chiral secondary alcohols undergo a highly stereospecific (90-98% ee) double nucleophilic displacement with an overall retention of configuration.

Safety of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Epifanov, M; Mo, JY; Dubois, R; Yu, H; Sammis, GM or concate me.

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In 2021 ORGANOMETALLICS published article about AEROBIC OXIDATIVE SYNTHESIS; CASCADE SYNTHESIS; QUINAZOLINONES; LIGANDS; FUNCTIONALIZATION; AMINOBENZAMIDES; BENZIMIDAZOLES; HYDROPEROXIDE; HETEROCYCLES; CHEMISTRY in [Balaji, Sundarraman; Balamurugan, Gunasekaran; Ramesh, Rengan] Bharathidasan Univ, Ctr Organometall Chem, Sch Chem, Tiruchirappalli 620024, Tamil Nadu, India; [Semeril, David] Univ Strasbourg, Inst Chim, Lab Chim Inorgan & Catalyse, UMR 7177,CNRS, F-67070 Strasbourg, France in 2021, Cited 78. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. HPLC of Formula: C8H10O2

A convenient protocol for the one-pot synthesis of quinazolin-4(3H)-ones using palladium(II) complexes via dehydrogenative coupling of readily available benzyl alcohols and 2-aminobenzamide has been described. New structurally related Pd(II) N boolean AND O chelating complexes of general configuration [Pd(L)Cl(PPh3)] (where L = dimethylamino benzoylhydrazone ligands) have been designed and synthesized. The formation of the complexes has been recognized by analytical and spectral methods (FT-IR, NMR, HR-MS). The presence of a square-planar geometry around the palladium(II) ion was confirmed by single crystal X-ray diffraction study. A wide range of substituted quinazolinones have been successfully achieved from a diverse range of benzyl alcohols in good to excellent yields using 1.0 mol % of catalyst loading under aerobic conditions. Furthermore, control experiments reveal that the dehydrogenative coupling reaction involves initially the formation of an aldehyde intermediate and subsequent formation of a cyclic aminal intermediate.

HPLC of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Balaji, S; Balamurugan, G; Ramesh, R; Semeril, D or concate me.

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Quality Control of (4-Methoxyphenyl)methanol. Authors Jin, B; Wang, JG; Xu, FX; Li, DF; Men, Y in ELSEVIER published article about in [Jin, Bei; Wang, Jinguo; Xu, Fengxia; Li, Dianfeng; Men, Yong] Shanghai Univ Engn Sci, Sch Chem & Chem Engn, Shanghai 201620, Peoples R China in 2021, Cited 59. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Selective conversion of biomass-derived alcohols into carbonyl compounds via visible-light photocatalysis is realized over hierarchical hollow WO3 microspheres with tailored surface oxygen vacancies, which presents the remarkably boosted photoactivity in terms of selectivity and activity, intrinsically attributing to the strong synergetic effect of hierarchical spherical cavity and surface oxygen vacancies simultaneously. The hierarchical spherical cavity, substantially constructed by the self-interconnected nanosheets, enhances the light-harvesting ability via multiple light reflections not only in spherical cavity but also among the self-interconnected nanosheets. Surface oxygen vacancies favor the energy band gap narrowing via forming a miniband just below the conduction band and then extend the photoresponse region, further boosting the light-harvesting ability. Importantly, surface oxygen vacancies function as the electron sinks to capture photoelectrons and thus restrict their recombination probability with holes, finally improving the photoelectron-hole separation efficiency. Meanwhile, this photocatalyst presents excellent reusability, showing its promising potential in practical applications. This work sheds light on a new application of hierarchical WO3 microspheres with tailored surface oxygen vacancies and its strong synergetic effect of hierarchical structures and surface oxygen vacancies on photocatalytic performance, delivering new insights for rationally designing highly active photocatalysts applied in future green and sustainable organic transformation reactions.

Quality Control of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Jin, B; Wang, JG; Xu, FX; Li, DF; Men, Y or concate me.

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In 2021 CURR TOP MED CHEM published article about BINDING MODE ANALYSIS; DIHYDROPYRIDINE DERIVATIVES; ANTIMOSQUITO PROPERTIES; MULTIDRUG-RESISTANT; LARVICIDAL ACTIVITY; INHA INHIBITORS; DESIGN; 1,4-DIHYDROPYRIDINES; POLYMORPHISM; DISCOVERY in [Venugopala, Katharigatta N.; Morsy, Mohamed A.; Aldhubiab, Bandar E.; Attimarad, Mahesh; Nair, Anroop B.; Sreeharsha, Nagaraja] King Faisal Univ, Coll Clin Pharm, Dept Pharmaceut Sci, Al Hasa 31982, Saudi Arabia; [Venugopala, Katharigatta N.; Mohanlall, Viresh] Durban Univ Technol, Dept Biotechnol & Food Technol, ZA-4001 Durban, South Africa; [Deb, Pran Kishore] Philadelphia Univ, Fac Pharm, Dept Pharmaceut Sci, Amman 19392, Jordan; [Pillay, Melendhran] Inkosi Albert Luthuli Cent Hosp, Dept Microbiol, Natl Hlth Lab Serv, KZN Acad Complex, ZA-4001 Durban, South Africa; [Chopra, Deepak] Indian Inst Sci Educ & Res Bhopal, Dept Chem, Bhopal By Pass Rd, Bhopal 462066, Madhya Pradesh, India; [Chandrashekharappa, Sandeep] GKVK, Inst Stem Cell Biol & Regenerat Med, TIFR, NCBS, Bangalore 560065, Karnataka, India; [Morsy, Mohamed A.] Menia Univ, Fac Med, Dept Pharmacol, El Minia 61511, Egypt; [Sreeharsha, Nagaraja] Vidya Siri Coll Pharm, Dept Pharmaceut, Off Sarjapura Rd, Bengaluru 560035, India; [Kandeel, Mahmoud] King Faisal Univ, Coll Vet Medi Cine, Dept Biomed Sci, Al Hasa 31982, Saudi Arabia; [Kandeel, Mahmoud] Kafrelsheikh Univ, Fac Vet Med, Dept Pharmacol, Kafrelsheikh 33516, Egypt; [Venugopala, Rashmi] Univ KwaZulu Natal, Dept Publ Hlth Med, Howard Coll Campus, ZA-4001 Durban, South Africa in 2021, Cited 93. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. COA of Formula: C8H10O2

Background: Tuberculosis remains one of the most deadly infectious diseases worldwide due to the emergence of multi-drug resistance (MDR) and extensively drug resistance (XDR) strains of Mycobacterium tuberculosis (MTB). Aims: Currently, available drugs are getting resistant and toxic. Hence, there is an urgent need for the development of potent molecules to treat tuberculosis. Materials and Methods: Herein, the screening of a total of eight symmetrical 1,4-dihydropyridine (1,4-DHP) derivatives (4a-4h) was carried out for whole-cell anti-TB activity against the susceptible H37Rv and MDR strains of MTB. Results and Discussion: Most of the compounds exhibited moderate to excellent activity against the susceptible H37Rv. Moreover, the most promising compound 4f (against H37Rv) having para-trifluoromethyl phenyl group at 4-position and bis para-methoxy benzyl ester group at 3- and 5-positions of 1,4- dihydropyridine pharmacophore, exhibited no toxicity, but demonstrated weak activity against MTB strains resistant to isoniazid and rifampicin. In light of the inhibitory profile of the title compounds, enoyl-acyl carrier protein reductase (InhA) appeared to be the appropriate molecular target. A docking study of these derivatives against InhA receptor revealed favorable binding interactions. Further, in silico predicted ADME properties of these compounds 4a-4h were found to be in the acceptable ranges, including satisfactory Lipinski’s rule of five, thereby indicating their potential as drug-like molecules. Conclusion: In particular, the 1,4-DHP derivative 4f can be considered an attractive lead molecule for further exploration and development of more potent anti-TB agents as InhA inhibitors.

COA of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Venugopala, KN; Deb, PK; Pillay, M; Chopra, D; Chandrashekharappa, S; Morsy, MA; Aldhubiab, BE; Attimarad, M; Nair, AB; Sreeharsha, N; Kandeel, M; Venugopala, R; Mohanlall, V or concate me.

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Authors Li, YT; Sun, S; Cheng, J; Yu, JT in ROYAL SOC CHEMISTRY published article about ONE-POT SYNTHESIS; HOMOPHTHALIC ANHYDRIDE; 3-COMPONENT REACTION; RADICAL CYCLIZATION; TANDEM CATALYSIS; BOND; FUNCTIONALIZATION; BENZAMIDES; ACIDS; HYDROXYALKYLATION in [Li, Yiting; Sun, Song; Cheng, Jiang; Yu, Jin-Tao] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China in 2020, Cited 56. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A radical-initiated cascade addition and cyclization of N-allylbenzamides with simple ethers to construct ether-substituted dihydroisoquinolinones was performed in the presence of CuI. The cleavage of the sp(3) C-H bond in ether and the sp(2) C-H bond in phenyl was involved in this reaction. Moreover, the arylalkylation of N-allylanilines was also realized under similar reaction conditions, providing ether-functionalized indolines in good to moderate yields.

Product Details of 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Li, YT; Sun, S; Cheng, J; Yu, JT or concate me.

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Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Tabaru, K; Nakatsuji, M; Itoh, S; Suzuki, T; Obora, Y in ROYAL SOC CHEMISTRY published article about in [Tabaru, Kazuki; Nakatsuji, Masato; Itoh, Satoshi; Obora, Yasushi] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Suita, Osaka 5648680, Japan; [Suzuki, Takeyuki] Osaka Univ, Inst Sci & Ind Res ISIR, Comprehens Anal Ctr, 8-1 Mihogaoka, Osaka 5670057, Japan in 2021, Cited 16. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

We report N,N-dimethylformamide-stabilised Pd nanoparticle (Pd NP)-catalysed transfer vinylation of alcohols from vinyl ether. Pd NPs combined with bathophenanthroline exhibited high catalytic activity. This reaction proceeded with low catalyst loading and the catalyst remained effective even after many rounds of recycling. The observation of the catalyst using transmission electron microscopy and dynamic light scattering implied no deleterious aggregation of Pd NPs.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Tabaru, K; Nakatsuji, M; Itoh, S; Suzuki, T; Obora, Y or concate me.. Application In Synthesis of (4-Methoxyphenyl)methanol

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An article Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power WOS:000664034700001 published article about GAS SHIFT REACTION; PRIMARY AMINES; NUCLEOPHILIC ALLYLATION; MOLECULAR COMPLEXITY; ALDEHYDES; RUTHENIUM; HYDROGEN; KETONES; CL; NITROARENES in [Biriukov, Klim O.; Vinogradov, Mikhail M.; Afanasyev, Oleg, I; Tsygankov, Alexey A.; Godovikova, Maria; Nelyubina, Yulia, V; Loginov, Dmitry A.; Chusov, Denis] Russian Acad Sci INEOS RAS, AN Nesmeyanov Inst Organoelement Cpds, Vavilova St 28, Moscow, Russia; [Vasilyev, Dmitry V.] Forschungszentrum Julich, Helmholtz Inst Erlangen Nurnberg Renewable Energy, Egerlandstr 3, D-91058 Erlangen, Germany; [Loginov, Dmitry A.; Chusov, Denis] GV Plekhanov Russian Univ Econ, 36 Stremyanny Per, Moscow 117997, Russia in 2021, Cited 71. Category: alcohols-buliding-blocks. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Herein, we present the first example of Os-catalyzed efficient reductive amination under water-gas shift reaction conditions. The developed catalytic systems are formed in situ in aqueous solutions, employ as small as 0.0625 mol% osmium and are capable of delivering reductive amination products for a broad range of aliphatic and aromatic carbonyl compounds and amines. The scope of the reaction, active catalytic systems, possible limitations of the method and DFT-supported mechanistic considerations are discussed in detail in the manuscript.

Category: alcohols-buliding-blocks. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Biriukov, KO; Vinogradov, MM; Afanasyev, OI; Vasilyev, DV; Tsygankov, AA; Godovikova, M; Nelyubina, YV; Loginov, DA; Chusov, D or concate me.

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Recently I am researching about MESOPOROUS MOLECULAR-SIEVE; METAL-SUPPORT INTERACTION; SELECTIVE HYDROGENATION; UNSATURATED ALDEHYDES; CINNAMYL ALCOHOL; ACTIVATED CARBON; HIGHLY EFFICIENT; CINNAMALDEHYDE; RUTHENIUM; COMPLEXES, Saw an article supported by the C1 Gas Refinery Program [2018M3D3A1A01018006]; National Research Foundation of Korea (NRF) – Ministry of Science, ICT, and Future Planning, Republic of Korea [2020M3H7A1098259]. Published in ELSEVIER SCIENCE INC in NEW YORK ,Authors: Padmanaban, S; Lee, Y; Yoon, S. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. Category: alcohols-buliding-blocks

Selective hydrogenation of the carbonyl functional group of alpha,beta-unsaturated carbonyl compounds affords industrially important allylic alcohols. However, achieving the selective reduction of the carbonyl group in the presence of the activated olefinic group is challenging. Therefore, the development of a highly chemoselective, efficient, and recyclable catalyst for this transformation is greatly desirable from the industrial and environmental viewpoints. In this study, a Ru-immobilized bisphosphine-based porous organic polymer (Ru@PP-POP) was used as an efficient heterogeneous catalyst for chemoselective hydrogenation of cinnamaldehyde (CAL) to cinnamyl alcohol with high chemoselectivity (98%) and excellent recyclability. To the best of our knowledge, the catalyst, Ru@PP-POP showed a high turnover number (970) and a high turnover frequency (240h(1)) which is the best activity obtained using a phosphine based heterogeneous Ru-catalyst in this transformation. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

Category: alcohols-buliding-blocks. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Padmanaban, S; Lee, Y; Yoon, S or concate me.

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Formula: C8H10O2. Authors Luo, NH; Zhong, YH; Wen, HL; Shui, HL; Luo, RS in WILEY-V C H VERLAG GMBH published article about in [Luo, Nianhua; Zhong, Yuhong; Wen, Huiling; Shui, Hongling; Luo, Renshi] Gannan Med Univ, Sch Pharmaceut Sci, Ganzhou 341000, Jiangxi, Peoples R China in 2021, Cited 94. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Ketones are of great importance in synthesis, biology, and pharmaceuticals. This paper reports an iridium complexes-catalyzed cross-coupling of alcohols via hydrogen borrowing, affording a series of alpha-alkylated ketones in high yield (86 %-95 %) and chemoselectivities (>99 : 1). This methodology has the advantages of low catalyst loading (0.1 mol%) and environmentally benign water as the solvent. Studies have shown the amount of base has a great impact on chemoselectivities. Meanwhile, deuteration experiments show water plays an important role in accelerating the reduction of the unsaturated ketones intermediates. Remarkably, a gram-scale experiment demonstrates this methodology of iridium-catalyzed cross-coupling of alcohols has potential application in the practical synthesis of alpha-alkylated ketones.

Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Luo, NH; Zhong, YH; Wen, HL; Shui, HL; Luo, RS or concate me.

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