Category: alcohols-buliding-blocks

Authors Jing, WD; Li, H; Xiao, PW; Liu, BL; Luo, JH; Wang, RW; Qiu, SL; Zhang, ZT in ROYAL SOC CHEMISTRY published article about METAL-ORGANIC FRAMEWORK; SELECTIVE OXIDATION; SOLID NANOPARTICLES; CATALYZED REACTIONS; PHASE INVERSION; EMULSIONS; PARTICLES; INTERFACE; CLUSTERS; SIZE in [Jing, Wendan; Li, Hui; Liu, Bolun; Wang, Runwei; Qiu, Shilun; Zhang, Zongtao] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China; [Xiao, Peiwen; Luo, Jianhui] PetroChina, Res Inst Petr Explorat & Dev, Beijing 100083, Peoples R China; [Xiao, Peiwen; Luo, Jianhui] CNPC, Key Lab Nano Chem KLNC, Beijing 100083, Peoples R China in 2021, Cited 43. Computed Properties of C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Organic reactors in a green solvent (water) is the goal of sustainable development. Green nanoreactors with excellent amphiphilicity and catalytic activity are strongly desired. Herein, a novel amphiphilic nanoreactor Pd@amZSM-5 with ultrasmall size has been successfully synthesized via a simple one-step oil bath method, subjected to the modification-etching-modification strategy and in situ reduction of Pd2+. Ultrasmall Pd@amZSM-5 nanoreactors (60 nm) with hierarchical structures showed outstanding amphiphilicity for forming Pickering emulsions with fine uniform droplets (50 mu m). Fine droplets formed short diffusion distances, which can significantly improve the catalytic activity in biphasic reactions. Moroever, the ultrasmall Pd@amZSM-5 nanoreactors demonstrated excellent catalytic activity for the selective oxidation of alcohols in water using air as the oxidant. Alkali was not present in the reaction system. The hydrophilic aminopropyl groups on the surface of the Pd@amZSM-5 nanoreactors not only changed the affinity of the zeolite surface and provided targeting points for Pd nanoparticles but also provided an alkaline environment for the selective oxidation of alcohols. The ultrasmall Pd@amZSM-5 nanoreactors presented excellent universality for aromatic alcohols (with >90% conversion and >90% selectivity) and allylic alcohols (with 100% conversion and 100% selectivity).

Computed Properties of C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Jing, WD; Li, H; Xiao, PW; Liu, BL; Luo, JH; Wang, RW; Qiu, SL; Zhang, ZT or concate me.

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Palav, A; Misal, B; Ganwir, P; Badani, P; Chaturbhuj, G in [Palav, Amey; Misal, Balu; Ganwir, Prerna; Chaturbhuj, Ganesh] Inst Chem Technol, Mumbai 400019, Maharashtra, India; [Palav, Amey; Misal, Balu] Loba Chem Pvt Ltd, Res & Dev Ctr, Tarapur 401506, Thane, India; [Badani, Purav] Univ Mumbai, Dept Chem, Mumbai 400098, Maharashtra, India published Rapid, chemoselective and mild oxidation protocol for alcohols and ethers with recyclable N-chloro-N-(phenylsulfonyl)benzenesulfonamide in 2021, Cited 42. HPLC of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Chlorine is the 20th most abundant element on the earth compared to bromine, iodine, and fluorine, a sulfonimide reagent, N-chloro-N-(phenylsulfonyl)benzenesulfonamide (NCBSI) was identified as a mild and selective oxidant. Without activation, the reagent was proved to oxidize primary and secondary alcohols as well as their symmetrical and mixed ethers to corresponding aldehydes and ketones. With recoverable PS-TEMPO catalyst, selective oxidation over chlorination of primary and secondary alcohols and their ethers with electron-donating substituents was achieved. The reagent precursor of NCBSI was recovered quantitatively and can be reused for synthesizing NCBSI. (C) 2021 Elsevier Ltd. All rights reserved.

HPLC of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Palav, A; Misal, B; Ganwir, P; Badani, P; Chaturbhuj, G or concate me.

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Category: alcohols-buliding-blocks. Padmanaban, S; Lee, Y; Yoon, S in [Padmanaban, Sudakar; Yoon, Sungho] Chung Ang Univ, Dept Chem, 84 Heukseok Ro, Seoul 06974, South Korea; [Padmanaban, Sudakar; Lee, Yunho] Seoul Natl Univ, Dept Chem, Seoul 08826, South Korea published Chemoselective hydrogenation of alpha,beta-unsaturated carbonyl compounds using a recyclable Ru catalyst embedded on a bisphosphine based POP in 2021, Cited 77. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Selective hydrogenation of the carbonyl functional group of alpha,beta-unsaturated carbonyl compounds affords industrially important allylic alcohols. However, achieving the selective reduction of the carbonyl group in the presence of the activated olefinic group is challenging. Therefore, the development of a highly chemoselective, efficient, and recyclable catalyst for this transformation is greatly desirable from the industrial and environmental viewpoints. In this study, a Ru-immobilized bisphosphine-based porous organic polymer (Ru@PP-POP) was used as an efficient heterogeneous catalyst for chemoselective hydrogenation of cinnamaldehyde (CAL) to cinnamyl alcohol with high chemoselectivity (98%) and excellent recyclability. To the best of our knowledge, the catalyst, Ru@PP-POP showed a high turnover number (970) and a high turnover frequency (240h(1)) which is the best activity obtained using a phosphine based heterogeneous Ru-catalyst in this transformation. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Padmanaban, S; Lee, Y; Yoon, S or concate me.. Category: alcohols-buliding-blocks

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An article Cu-Mn Bimetallic Complex Immobilized on Magnetic NPs as an Efficient Catalyst for Domino One-Pot Preparation of Benzimidazole and Biginelli Reactions from Alcohols WOS:000567788200001 published article about AEROBIC OXIDATION; AROMATIC DIAMINES; MULTICOMPONENT REACTIONS; SELECTIVE OXIDATION; COUPLING REACTIONS; SCHIFF-BASE; NANOCATALYST; NANOPARTICLES; HANTZSCH; COPPER in [Nasseri, Mohammad Ali; Rezazadeh, Zinat; Kazemnejadi, Milad; Allahresani, Ali] Univ Birjand, Dept Chem, Fac Sci, Birjand 97175615, Iran in 2021, Cited 73. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

An efficient magnetically recyclable bimetallic catalyst by anchoring copper and manganese complexes on the Fe(3)O(4)NPs was prepared and named as Fe3O4@Cu-Mn. It was founded as a powerful catalyst for the domino one-pot oxidative benzimidazole and Biginelli reactions from benzyl alcohols as a green protocol in the presence of air, under solvent-free and mild conditions. Fe3O4@Cu-Mn NPs were well characterized by FT-IR, XRD, FE-SEM, TEM, VSM, TGA, EDX, DLS, and ICP analyses. The optimum range of parameters such as time, temperature, amount of catalyst, and solvent were investigated for the domino one-pot benzimidazole and Biginelli reactions to find the optimum reaction conditions. The catalyst was compatible with a variety of benzyl alcohols, which provides favorable products with good to high yields for all of derivatives. Hot filtration and Hg poisoning tests from the nanocatalyst revealed the stability, low metal leaching and heterogeneous nature of the catalyst. To prove the synergistic and cooperative effect of the catalytic system, the various homologues of the catalyst were prepared and then applied to a model reaction separately. Finally, the catalyst could be filtered from the reaction mixture simply, and reused for five consecutive cycles with a minimum loss in catalytic activity and performance. Graphic A new magnetically recyclable Cu/Mn bimetallic catalyst has been developed for domino one-pot oxidation-condensation of benzimidazole and Biginelli reactions from alcohols.

Product Details of 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Nasseri, MA; Rezazadeh, Z; Kazemnejadi, M; Allahresani, A or concate me.

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Product Details of 105-13-5. Authors Wei, DY; Yang, P; Yu, CM; Zhao, FK; Wang, YL; Peng, ZH in AMER CHEMICAL SOC published article about in [Wei, Dongyue; Yang, Peng; Yu, Chuanman; Zhao, Fengkai; Wang, Yilei; Peng, Zhihua] China Univ Petr East China, Coll Sci, Dept Chem, Qingdao 266580, Shandong, Peoples R China in 2021, Cited 51. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A manganese-catalyzed N-alkylation reaction of amines with alcohols via hydrogen autotransfer strategy has been demonstrated. The developed practical catalytic system including an inexpensive, nontoxic, commercially available MnCl2 or MnBr(CO) s as the metal salt and triphenylphosphine as a ligand provides access to diverse aromatic, heteroaromatic, and aliphatic secondary amines in moderate-to-high yields. In addition, this operationally simple protocol is scalable to the gram level and suitable for synthesizing heterocycles such as indole and resveratrol-derived amines known to be active for Alzheimer’s disease.

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Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Zhuang, XH; Shi, XY; Zhu, R; Sun, B; Su, WK; Jin, C in ROYAL SOC CHEMISTRY published article about in [Zhuang, Xiaohui; Sun, Bin; Su, WeiKe; Jin, Can] Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou, Peoples R China; [Shi, Xiayue; Zhu, Rui; Su, WeiKe; Jin, Can] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou, Peoples R China in 2021, Cited 58. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A mild and metal-free protocol for visible-light induced intramolecular radical cyclization of N-allyl(propargyl)-2-bromo-2,2-difluoro-N-arylacetamide has been developed. This strategy showed excellent regioselectivity and simple operation to synthesize 4-substituted 3,3-difluoro-gamma-lactams with a broad substrate scope. Moreover, mechanistic studies revealed that this transformation proceeded through a cascade radical-type cyclization and hydrogen atom transfer process with PMDETA as a hydrogen-atom donor.

Application In Synthesis of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Zhuang, XH; Shi, XY; Zhu, R; Sun, B; Su, WK; Jin, C or concate me.

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Recommanded Product: (4-Methoxyphenyl)methanol. I found the field of Chemistry very interesting. Saw the article Dinuclear Copper(II) Complexes with N,O Donor Ligands: Partial Ligand Hydrolysis and Alcohol Oxidation Catalysis published in 2021, Reprint Addresses Roy, P (corresponding author), Jadavpur Univ, Dept Chem, Kolkata 700032, India.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol.

Two copper(II) complexes [Cu-2(L-1)(2)] (1) and [Cu-2(L-2)(2)] (2) where H2L1=2-hydroxy-3-((3-hydroxy-2,2-dimethylpropylimino)methyl)-5-methylbenzaldehyde and H2L2=2-hydroxy-3-(((1-hydroxypropan-2-yl)imino)methyl)-5-methylbenzaldehyde have been synthesized and used as catalysts in alcohol oxidation. 2,6-Diformyl-4-methylphenol (DFP) based Schiff-base ligands, 3,3 ‘-(2-hydroxy-5-methyl-1,3-phenylene)bis(methan-1-yl-1-ylidene)bis(azan-1-yl-1-ylidene)bis(2,2-dimethylpropan-1-ol) (H3L ‘) and 2,2 ‘-(((2-hydroxy-5-methyl-1,3-phenylene)bis(methanylylidene))bis(azanylylidene))bis(propan-1-ol) (H3L ”), undergo partial hydrolysis to convert one of the azomethine groups to aldehyde group to give H2L1 and H2L2, and then react with copper(II) acetate to yield complex 1 and 2, respectively. These complexes have been characterized by standard methods such as elemental analysis, room temperature magnetic studies, FT-IR, UV-vis, ESI-mass spectral analyses, cyclic voltammogram, etc. The structures of dinuclear complexes with modified ligands have been confirmed by single crystal X-ray diffraction analysis. Complex 1 and 2 have been used as catalysts for the oxidation of benzyl alcohol, 4-methyl benzyl alcohol, 4-methoxy benzyl alcohol, 4-nitro benzyl alcohol and 4-bromo benzyl alcohol to the corresponding aldehyde as the sole product. Efficiency of the catalyst depends on the chain length and substitution on the chain of the ligand.

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Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Epifanov, M; Mo, JY; Dubois, R; Yu, H; Sammis, GM in AMER CHEMICAL SOC published article about in [Epifanov, Maxim; Mo, Jia Yi; Dubois, Rudy; Yu, Hao; Sammis, Glenn M.] Univ British Columbia, Dept Chem, Columbia, BC V6T 1Z1, Canada in 2021, Cited 48. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Sulfuryl fluoride is a valuable reagent for the one-pot activation and derivatization of aliphatic alcohols, but the highly reactive alkyl fluorosulfate intermediates limit both the types of reactions that can be accessed as well as the scope. Herein, we report the SO2F2-mediated alcohol substitution and deoxygenation method that relies on the conversion of fluorosulfates to alkyl halide intermediates. This strategy allows the expansion of SO2F2-mediated one-pot processes to include radical reactions, where the alkyl halides can also be exploited in the one-pot deoxygenation of primary alcohols under mild conditions (52-95% yield). This strategy can also enhance the scope of substitutions to nucleophiles that are previously incompatible with one-pot SO2F2-mediated alcohol activation and enables substitution of primary and secondary alcohols in 54-95% yield. Chiral secondary alcohols undergo a highly stereospecific (90-98% ee) double nucleophilic displacement with an overall retention of configuration.

Application In Synthesis of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Epifanov, M; Mo, JY; Dubois, R; Yu, H; Sammis, GM or concate me.

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Computed Properties of C8H10O2. Authors Xiao, WL; Mo, YH; Guo, J; Su, ZS; Dong, SX; Feng, XM in ROYAL SOC CHEMISTRY published article about in [Xiao, Wanlong; Mo, Yuhao; Guo, Jing; Su, Zhishan; Dong, Shunxi; Feng, Xiaoming] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China in 2021, Cited 64. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

New types of C-2-symmetric chiral macrodiolides are readily obtained via chiral N,N ‘-dioxide-scandium(iii) complex-promoted asymmetric tandem Friedel-Crafts alkylation/intermolecular macrolactonization of ortho-quinone methides with C3-substituted indoles. This protocol provides an array of enantioenriched macrodiolides with 16, 18 or 20-membered rings in moderate to good yields with high diastereoselectivities and excellent enantioselectivities through adjusting the length of the tether at the C3 position of indoles. Density functional theory calculations indicate that the formation of macrocycles is more favorable than that of 9-membered-ring lactones in terms of kinetics and thermodynamics. The potential utility of these intriguing chiral macrodiolide molecules is demonstrated in the enantiomeric recognition of aminols and chemical recognition of metal ions.

Computed Properties of C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Xiao, WL; Mo, YH; Guo, J; Su, ZS; Dong, SX; Feng, XM or concate me.

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Application In Synthesis of (4-Methoxyphenyl)methanol. Recently I am researching about BENZYL ALCOHOL; DYE DEGRADATION; CUS; EFFICIENT; EVOLUTION; TIO2; 1,2,3-TRIAZOLES; MICROSPHERES; NANOCRYSTALS; REDUCTION, Saw an article supported by the SERB, IndiaDepartment of Science & Technology (India)Science Engineering Research Board (SERB), India; SERB-DST, India [EEQ/2018/000326]; UGC, IndiaUniversity Grants Commission, India [F.30-467/2019-BSR]; DST, New Delhi, IndiaDepartment of Science & Technology (India) [EMR/2016/002345]; Department of Science and Technology under DST-FIST programmeDepartment of Science & Technology (DOST), PhilippinesDepartment of Science & Technology (India). Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Agarwal, S; Phukan, P; Sarma, D; Deori, K. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A series of copper sulfide (CS) nanoparticles (NPs) were synthesized just by varying the amount of the sulfur precursor and have been explored for the first time as a three-way heterogeneous catalyst in the photocatalytic oxidation of a number of aromatic alcohols, photocatalytic degradation and the reduction of water pollutants, and the facile synthesis of pharmaceutically important moiety 4-aryl-NH-1,2,3-triazoles. The green and novel protocol was successfully developed for the synthesis of covellite (CuS, Cu2+) and the covellite-villamaninite (CuS-CuS2) (copper in Cu2+, Cu1+) phases of copper sulfide, employing EDTA both as the chelating and capping agent via a simple precipitation method at room temperature using water as the solvent. A blue shift in the absorption spectra and band gap in the range of 2.02-2.07 eV prompted the investigation of the as-synthesized CS nanoparticles as the photocatalyst under visible light irradiation. In the absence of any oxidizing or reducing agent, covellite CuS nanoparticles showed the highest photocatalytic efficiency for the degradation of methylene blue (MB) and the reduction of carcinogenic and mutagenic Cr(vi) to non-toxic Cr(iii). Interestingly, the mixed phase of CS (CuS-CuS2), where Cu is present in both +1 and +2 oxidation states, was found to be the most efficient catalyst compared to CuS toward the visible light-mediated selective oxidation of various benzyl alcohols to their corresponding aldehydes. However, in the synthesis of substituted NH-1,2,3-triazoles, single-phase CS nanoparticles (i.e., CuS) provided the best catalytic result. This significant outcome certainly opens up the scope for realizing the present demand of low-cost multifunctional semiconductor nano-materials, which will have a huge impact on the economy and environment when they show more than two potential applications.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Agarwal, S; Phukan, P; Sarma, D; Deori, K or concate me.. Application In Synthesis of (4-Methoxyphenyl)methanol

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