Category: alcohols-buliding-blocks

An article Sustainable production of value-added chemicals and fuels by using a citric acid-modified carbon nitride optical semiconductor WOS:000599504600004 published article about SELECTIVE OXIDATION; HIGHLY EFFICIENT; PHOTOCATALYTIC OXIDATION; HYDROGEN EVOLUTION; AROMATIC ALCOHOLS; QUANTUM DOTS; G-C3N4; WATER; BENZALDEHYDE; FABRICATION in [Fernandes, Raquel A.; Sampaio, Maria J.; Da Silva, Eliana S.; Boumeriame, Hanane; Faria, Joaquim L.; Silva, Claudia G.] Univ Porto, Fac Engn, Associate Lab LSRE LCM, Rua Dr Roberto Frias S-N, P-4200465 Porto, Portugal; [Boumeriame, Hanane] Univ Abdelmalek Essaadi, Fac Sci & Tech, Lab Chem Engn & Valorizat Resources LGCVR UAE L01, Tangier, Morocco; [Lopes, Tania; Andrade, Luisa; Mendes, Adelio] Univ Porto, Fac Engn, LEPABE Lab Proc Engn Environm Biotechnol & Energy, Rua Dr Roberto Frias, P-4200465 Porto, Portugal in 2021, Cited 70. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Citric acid-modified graphite-like carbon nitride materials (GCN-zCA) were synthetized by thermal copolymerization of dicyandiamide with different amounts of citric acid (z = between 5 and 25 mg). The resulting materials presented surface porosity, defective polymeric structure, and enhanced visible light absorption in the 450-700 nm range, attributed to the existence of mid-gap states and n-pi* electronic transitions. All the modified catalysts presented high selectivity (>99 %) towards the conversion of p-anisyl alcohol into p-anisaldehyde under visible-LED irradiation, the best performing photocatalyst (GCN-20CA) reaching 63 % yield (contrasting with 22 % obtained with bulk GCN) after 240 min reaction. GCN-20CA was also applied for hydrogen generation from water splitting. The modified material practically duplicated the hydrogen production when compared to bulk GCN (75 and 44 mu mol H-2 evolved in three hours, respectively), by using platinum nanoparticles as co-catalyst and EDTA as sacrificial electron donor. Moreover, p-anisyl alcohol was successfully used as sacrificial agent for water splitting, with simultaneous production of p-anisaldehyde and H-2. Reusability tests showed that GCN-20CA remained stable in a series of consecutive runs both for p-anisaldehyde synthesis and hydrogen production.

Product Details of 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Fernandes, RA; Sampaio, MJ; Da Silva, ES; Boumeriame, H; Lopes, T; Andrade, L; Mendes, A; Faria, JL; Silva, CG or send Email.

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Recommanded Product: (4-Methoxyphenyl)methanol. Authors Alam, MN; Dash, SR; Mukherjee, A; Pandole, S; Marelli, UK; Vanka, K; Maity, P in AMER CHEMICAL SOC published article about in [Alam, Md Nirshad; Mukherjee, Anirban; Pandole, Satish; Marelli, Udaya Kiran; Maity, Pradip] CSIR Natl Chem Lab, Organ Chem Div, Pune 411008, Maharashtra, India; [Alam, Md Nirshad; Dash, Soumya Ranjan; Marelli, Udaya Kiran; Vanka, Kumar] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India; [Dash, Soumya Ranjan; Vanka, Kumar] CSIR Natl Chem Lab, Phys & Mat Chem Div, Pune 411008, Maharashtra, India in 2021, Cited 55. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A thermal O-to-C [1,3]-rearrangement of alpha-hydroxy acid derived enol ethers was achieved under mild conditions. The 2-aminothiophenol protection of carboxylic acids facilitates formation of the [1,3] precursor and its thermal rearrangement via stabilization of a radical intermediate. Experimental and theoretical evidence for dissociative radical pair formation, its captodative stability via aminothiophenol, and a unique solvent effect are presented. The aminothiophenol was deprotected from rearrangement products as well as after derivatization to useful synthons.

Welcome to talk about 105-13-5, If you have any questions, you can contact Alam, MN; Dash, SR; Mukherjee, A; Pandole, S; Marelli, UK; Vanka, K; Maity, P or send Email.. Recommanded Product: (4-Methoxyphenyl)methanol

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In 2020 ADV SYNTH CATAL published article about SELECTIVE SYNTHESIS; COUPLING REACTIONS; ALPHA; TRICHLOROMETHYL; CLEAVAGE; REDUCTION; ALKYNES; ALPHA,ALPHA-DIBROMOACETOPHENONES; TRIPHENYLPHOSPHINE; HYDROXYLATION in [Liu, Yunyun; Xiong, Jin; Wei, Li; Wan, Jie-Ping] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China in 2020, Cited 77. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: (4-Methoxyphenyl)methanol

The novel free radical-based cleavage of the enaminone C=C double bond is realized by using N-halosuccinimides (NXS) in the presence of benzoyl peroxide (BPO) with mild heating, enabling the tunable synthesis of alpha,alpha-dihalomethyl ketones and alpha,alpha,alpha-trihalomethyl ketones under different reaction conditions. The formation of these divergent products involving featured C=C double bond cleavage requires no any metal reagent, and represents one more practical example on the synthesis of poly halogenated methyl ketones via the functionalization of carbon-carbon bond.

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HPLC of Formula: C8H10O2. Authors Wei, DY; Yang, P; Yu, CM; Zhao, FK; Wang, YL; Peng, ZH in AMER CHEMICAL SOC published article about in [Wei, Dongyue; Yang, Peng; Yu, Chuanman; Zhao, Fengkai; Wang, Yilei; Peng, Zhihua] China Univ Petr East China, Coll Sci, Dept Chem, Qingdao 266580, Shandong, Peoples R China in 2021, Cited 51. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A manganese-catalyzed N-alkylation reaction of amines with alcohols via hydrogen autotransfer strategy has been demonstrated. The developed practical catalytic system including an inexpensive, nontoxic, commercially available MnCl2 or MnBr(CO) s as the metal salt and triphenylphosphine as a ligand provides access to diverse aromatic, heteroaromatic, and aliphatic secondary amines in moderate-to-high yields. In addition, this operationally simple protocol is scalable to the gram level and suitable for synthesizing heterocycles such as indole and resveratrol-derived amines known to be active for Alzheimer’s disease.

HPLC of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wei, DY; Yang, P; Yu, CM; Zhao, FK; Wang, YL; Peng, ZH or concate me.

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In 2021 J ENVIRON CHEM ENG published article about ORGANIC-CHEMISTRY; AROMATIC ALCOHOLS; AQUEOUS GLUCOSE; BENZOIC-ACID; WATER; HYDROCARBONS; DEGRADATION in [Bellardita, Marianna; Loddo, Vittorio; Palmisano, Leonardo; Augugliaro, Vincenzo] Univ Palermo, Dipartimento Ingn, Schiavello Grillone Photocatalysis Grp, Viale Sci,Ed 6, I-90128 Palermo, Italy; [Yurdakal, Sedat; Tek, Bilge Sina] Afyon Kocatepe Univ, Fen Edebiyat Fak, Kimya Bolumu, Ahmet Necdet Sezer Kampusu, TR-03200 Afyon, Turkey; [Degirmenci, Caglar] Eskisehir Tekn Univ, Fen Fak, Kimya Bolumu, Yunus Emre Kampusu, TR-26470 Eskisehir, Turkey; [Palmisano, Giovanni] Khalifa Univ Sci & Technol, Dept Chem Engn, POB 127788, Abu Dhabi, U Arab Emirates; [Palmisano, Giovanni] Khalifa Univ Sci & Technol, Res & Innovat Ctr CO2 & H2, POB 127788, Abu Dhabi, U Arab Emirates; [Soria, Javier] CSIC, Inst Catalisis & Petroleoquim, C Marie Curie 2, Madrid 28049, Spain; [Sanz, Jesus] CSIC, Inst Ciencia Mat, Madrid 28049, Spain in 2021, Cited 38. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Safety of (4-Methoxyphenyl)methanol

The influence of pH on the photocatalytic partial oxidation of 4-methoxybenzyl alcohol (MBA) and vanillyl alcohol (VA) to their corresponding aldehydes in aqueous suspension under UVA irradiation was investigated by using poorly crystalline home-prepared and crystalline commercial TiO2 (BDH, Merck and Degussa P25) photocatalysts. The results clearly show as tuning pH can strongly impart selectivity and activity to photocatalytic processes which are often quite unselective in aqueous suspensions. It was found that pH effect on reaction rate and product selectivity strongly depended on TiO2 crystallinity and substrate type. In the case of MBA oxidation, photoreactivity and selectivity were very high at low pH values for all of TiO2 catalysts, and the crystalline samples showed to be more active than the poorly crystalline ones. At pH= 1 the photoactivity of Degussa P25 was the highest one, and 88% selectivity at 50% conversion was determined. At acidic pH values, selectivity and activity were higher in the presence of HCl than H2SO4 or H3PO4. For VA oxidation, high selectivity values were obtained at high pH’s for all of the samples, and the crystalline samples showed higher activity at the alkaline pH values with respect to that observed at the acidic ones. Experiments starting from the obtained products, that are p-anisaldehyde and vanillin, showed that the selectivity depends on the resistance of those compounds to be subjected to further oxidation under the experimental conditions used.

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Computed Properties of C8H10O2. Authors Duong, U; Ansari, TN; Parmar, S; Sharma, S; Kozlowski, PM; Jasinski, JB; Plummer, S; Gallou, F; Handa, S in AMER CHEMICAL SOC published article about in [Duong, Uyen; Ansari, Tharique N.; Parmar, Saurav; Sharma, Sudripet; Kozlowski, Pawel M.; Handa, Sachin] Univ Louisville, Dept Chem, Louisville, KY 40292 USA; [Jasinski, Jacek B.] Univ Louisville, Mat Characterizat, Conn Ctr Renewable Energy Res, Louisville, KY 40292 USA; [Plummer, Scott] Novartis Inst Biomed Res, Cambridge, MA 02139 USA; [Gallou, Fabrice] Novartis Pharma AG, CH-4056 Basel, Switzerland in 2021, Cited 34. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Upon visible-light irradiation, the heterogeneous polymer of PDI-Cu(I)-PDI (PDI = perylene diimide) generates charge transfer states that are subsequently quenched by molecular oxygen for their participation in redox activity. This insoluble polymeric Cu(I) is catalytically active for the oxidation of benzylic alcohols to corresponding aldehydes when suspended in dynamic micelles of PS-750-M. A broad substrate scope, excellent selectivity, and no over-oxidation reveal the catalyst robustness. The catalytic activity, control experiments, and time-dependent DFT calculations show the charge transfer states. The polymeric catalyst is entirely recyclable, as evidenced by the recycle studies using Scott’s recyclability test. The morphology, structure, copper’s oxidation state, and the catalyst’s thermal stability are determined by SEM, XPS, and TGA analysis.

Computed Properties of C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Duong, U; Ansari, TN; Parmar, S; Sharma, S; Kozlowski, PM; Jasinski, JB; Plummer, S; Gallou, F; Handa, S or concate me.

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Product Details of 105-13-5. Authors Kon, Y; Nakashima, T; Yada, A; Fujitani, T; Onozawa, SY; Kobayashi, S; Sato, K in ROYAL SOC CHEMISTRY published article about in [Kon, Yoshihiro; Nakashima, Takuya; Yada, Akira; Fujitani, Tadahiro; Onozawa, Shun-ya; Kobayashi, Shu; Sato, Kazuhiko] Natl Inst Adv Ind Sci & Technol, Interdisciplinary Res Ctr Catalyt Chem, Tsukuba, Ibaraki 3058565, Japan; [Kobayashi, Shu] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan in 2021, Cited 41. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The oxidation of alcohols to aldehydes is a powerful reaction pathway for obtaining valuable fine chemicals used in pharmaceuticals and biologically active compounds. Although many oxidants can oxidize alcohols, only a few hydrogen peroxide oxidations can be employed to continuously synthesize aldehydes in high yields using a liquid-liquid two-phase flow reactor, despite the possibility of the application toward a safe and rapid multi-step synthesis. We herein report the continuous flow synthesis of (E)-cinnamaldehyde from (E)-cinnamyl alcohol in 95%-98% yields with 99% selectivity for over 5 days by the selective oxidation of hydrogen peroxide using a catalyst column in which Pt is dispersed in SiO2. The active species for the developed selective oxidation is found to be zero-valent Pt(0) from the X-ray photoelectron spectroscopy measurements of the Pt surface before and after the oxidation. Using Pt black diluted with SiO2 as a catalyst to retain the Pt(0) species with the optimal substrate and H2O2 introduction rate not only enhances the catalytic activity but also maintains the activity during the flow reaction. Optimizing the contact time of the substrate with Pt and H2O2 using a flow reactor is important to proceed with the selective oxidation to prevent the catalytic H2O2 decomposition.

Product Details of 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Kon, Y; Nakashima, T; Yada, A; Fujitani, T; Onozawa, SY; Kobayashi, S; Sato, K or concate me.

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Authors Yamamoto, Y; Ota, M; Kodama, S; Michimoto, K; Nomoto, A; Ogawa, A; Furuya, M; Kawakami, K in AMER CHEMICAL SOC published article about in [Yamamoto, Yuki; Ota, Miyuto; Kodama, Shintaro; Michimoto, Kazuki; Nomoto, Akihiro; Ogawa, Akiya] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Sakai, Osaka 5998531, Japan; [Furuya, Mitsunori; Kawakami, Kiminori] Mitsubishi Chem Corp, Sci & Innovat Ctr, Yokohama, Kanagawa 2278502, Japan in 2021, Cited 67. Quality Control of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A green method for the oxidation of alcohols to carboxylic acids was developed using a novel co-catalytic system based on gold, silver, and copper catalysts. This reaction system was conducted under atmospheric oxygen in water and mild conditions to selectively oxidize 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid, as a building block for polyethylene furanoate, which is a 100% bio-based, future alternative to the petroleum-based polyethylene terephthalate. Furthermore, various primary alcohols were conveniently oxidized to their corresponding carboxylic acids in up to quantitative yields.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Yamamoto, Y; Ota, M; Kodama, S; Michimoto, K; Nomoto, A; Ogawa, A; Furuya, M; Kawakami, K or concate me.. Quality Control of (4-Methoxyphenyl)methanol

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Authors Aarsetoy, R; Ueland, T; Aukrust, P; Michelsen, AE; de la Fuente, RL; Ponitz, V; Brugger-Andersen, T; Grundt, H; Staines, H; Nilsen, DWT in WILEY published article about SOLUBLE RECEPTOR TIE-2; CARDIOVASCULAR MORTALITY; ANGPTL4; DISEASE; RISK; ANGIOGENESIS; BIOMARKER; EVENTS in [Aarsetoy, Reidun; Ponitz, Volker; Brugger-Andersen, Trygve; Nilsen, Dennis W. T.] Stavanger Univ Hosp, Dept Cardiol, POB 8100, N-4068 Stavanger, Norway; [Aarsetoy, Reidun; Grundt, Heidi; Nilsen, Dennis W. T.] Univ Bergen, Dept Clin Sci, Bergen, Norway; [Ueland, Thor; Aukrust, Pal; Michelsen, Annika E.] Oslo Univ Hosp, Res Inst Internal Med, Rikshosp, Oslo, Norway; [Aukrust, Pal] Oslo Univ Hosp, Sect Clin Immunol & Infect Dis, Rikshosp, Oslo, Norway; [de la Fuente, Ricardo Leon] Ctr Cardiovasc Salta, Salta, Argentina; [Grundt, Heidi] Stavanger Univ Hosp, Dept Resp Med, Stavanger, Norway; [Staines, Harry] Sigma Stat Serv, Balmullo, Scotland in , Cited 34. Recommanded Product: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Background Plasma levels of angiopoietin-2 (ANGPT2) and angiopoietin-like 4 protein (ANGPTL4) reflect different pathophysiological aspects of cardiovascular disease. We evaluated their association with outcome in a hospitalized Norwegian patient cohort (n = 871) with suspected acute coronary syndrome (ACS) and validated our results in a similar Argentinean cohort (n = 982). Methods A cox regression model, adjusting for traditional cardiovascular risk factors, was fitted for ANGPT2 and ANGPTL4, respectively, with all-cause mortality and cardiac death within 24 months and all-cause mortality within 60 months as the dependent variables. Results At 24 months follow-up, 138 (15.8%) of the Norwegian and 119 (12.1%) of the Argentinian cohort had died, of which 86 and 66 deaths, respectively, were classified as cardiac. At 60 months, a total of 259 (29.7%) and 173 (17.6%) patients, respectively, had died. ANGPT2 was independently associated with all-cause mortality in both cohorts at 24 months [hazard ratio (HR) 1.27 (95% confidence interval (CI), 1.08-1.50) for Norway, and HR 1.57 (95% CI, 1.27-1.95) for Argentina], with similar results at 60 months [HR 1.19 (95% CI, 1.05-1.35) (Norway), and HR 1.56 (95% CI, 1.30-1.88) (Argentina)], and was also significantly associated with cardiac death [HR 1.51 (95% CI, 1.14-2.00)], in the Argentinean population. ANGPTL4 was significantly associated with all-cause mortality in the Argentinean cohort at 24 months [HR 1.39 (95% CI, 1.15-1.68)] and at 60 months [HR 1.43 (95% CI, 1.23-1.67)], enforcing trends in the Norwegian population. Conclusions ANGPT2 and ANGPTL4 were significantly associated with outcome in similar ACS patient cohorts recruited on two continents. Clinical Trial Registration ClinicalTrials.gov Identifier: NCT00521976. ClinicalTrials.gov Identifier: NCT01377402.

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Formula: C8H10O2. Authors Li, WZ; Wang, ZX in ROYAL SOC CHEMISTRY published article about in [Li, Wei-Ze; Wang, Zhong-Xia] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China; [Li, Wei-Ze; Wang, Zhong-Xia] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China; [Wang, Zhong-Xia] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China in 2021, Cited 99. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

alpha-Alkylation of methyldiarylphosphine oxides with (hetero)arylmethyl alcohols was performed under nickel catalysis. Various arylmethyl and heteroarylmethyl alcohols can be used in this transformation. A series of methyldiarylphosphine oxides were alkylated with 30-90% yields. Functional groups on the aromatic rings of methyldiarylphosphine oxides or arylmethyl alcohols including OMe, NMe2, SMe, CF3, Cl, and F groups can be tolerated. The conditions are also suitable for the alpha-alkylation reaction of dialkyl methylphosphonates.

Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Li, WZ; Wang, ZX or concate me.

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