In 2019,Chemical Communications (Cambridge, United Kingdom) included an article by Harinath, Adimulam; Bhattacharjee, Jayeeta; Panda, Tarun K.. Formula: C7H7BrO. The article was titled 《Facile reduction of carboxylic acids to primary alcohols under catalyst-free and solvent-free conditions》. The information in the text is summarized as follows:
A facile protocol for the deoxygenative hydroboration of aliphatic and aryl carboxylic acids afforded corresponding primary alcs. under solvent-free and catalyst-free conditions was reported. The reaction proceeded under ambient temperature exhibited good tolerance towards various functional groups and generates quant. yields. The plausible mechanism involved the formation of Lewis acid-base adducts as well as the liberation of hydrogen gas. The results came from multiple reactions, including the reaction of (4-Bromophenyl)methanol(cas: 873-75-6Formula: C7H7BrO)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Formula: C7H7BrO It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts