Category: 821-41-0

The author of 《Ligand-Promoted Iron(III)-Catalyzed Hydrofluorination of Alkenes》 were Xie, Yongtao; Sun, Peng-Wei; Li, Yuxin; Wang, Siwei; Ye, Mengchun; Li, Zhengming. And the article was published in Angewandte Chemie, International Edition in 2019. Category: alcohols-buliding-blocks The author mentioned the following in the article:

An iron-catalyzed hydrofluorination of unactivated alkenes has been developed. The use of a multidentate ligand and the fluorination reagent N-fluorobenzenesulfonimide (NFSI) proved to be critical for this reaction, which afforded various fluorinated compounds in up to 94 % yield. In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Category: alcohols-buliding-blocks)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Application In Synthesis of 5-Hexen-1-olIn 2019 ,《Aryl Boronic Acid Catalysed Dehydrative Substitution of Benzylic Alcohols for C-O Bond Formation》 was published in Chemistry – A European Journal. The article was written by Estopina-Duran, Susana; Donnelly, Liam J.; McLean, Euan B.; Hockin, Bryony M.; Slawin, Alexandra M. Z.; Taylor, James E.. The article contains the following contents:

A combination of pentafluorophenylboronic acid and oxalic acid catalyzed the dehydrative substitution of benzylic alcs. with a second alc. to form new C-O bonds. This method had been applied to the intermol. substitution of benzylic alcs. to form sym. ethers I [R = H, Ph; Ar = Ph, 2-ClC6H4, 4-BrC6H4, etc.], intramol. cyclizations of diols to form aryl-substituted THF and tetrahydropyran derivatives II [Q = (CH2)n, n = 1,2; Ar = 4-MeOC6H4, 4-F3CC6H4], and intermol. crossed-etherification reactions between two different alcs. to give unsym. ethers III [R1 = Et, sec-Bu, 5-hexen-1-yl, etc.; R2 = Me, i-Pr, t-Bu, ethynyl, Ph; Ar = 3-BrC6H4, 2-MeOC6H4]. Mechanistic control experiments had identified a potential catalytic intermediate formed between the aryl boronic acid and oxalic acid. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0Application In Synthesis of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Application In Synthesis of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

The author of 《Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway》 were Zhou, Xiao-Le; Yang, Fan; Sun, Han-Li; Yin, Yun-Nian; Ye, Wei-Ting; Zhu, Rong. And the article was published in Journal of the American Chemical Society in 2019. Category: alcohols-buliding-blocks The author mentioned the following in the article:

A functional group tolerant cobalt-catalyzed method for the intermol. hydrofunctionalization of alkenes with oxygen- and nitrogen-based nucleophiles is reported. This protocol features a strategic use of hypervalent iodine(III) reagents that enables a mechanistic shift from conventional cobalt-hydride catalysis. Key evidence was found supporting a unique bimetallic-mediated rate-limiting step involving two distinct cobalt(III) species, from which a new carbon-heteroatom bond is formed. The results came from multiple reactions, including the reaction of 5-Hexen-1-ol(cas: 821-41-0Category: alcohols-buliding-blocks)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

SDS of cas: 821-41-0In 2021 ,《Segmented Polyurethane Elastomers with Mechanochromic and Self-Strengthening Functions》 was published in Angewandte Chemie, International Edition. The article was written by Seshimo, Kota; Sakai, Hio; Watabe, Takuma; Aoki, Daisuke; Sugita, Hajime; Mikami, Koichiro; Mao, Yuchen; Ishigami, Akira; Nishitsuji, Shotaro; Kurose, Takashi; Ito, Hiroshi; Otsuka, Hideyuki. The article contains the following contents:

Mechanochromic elastomers that exhibit force-induced crosslinking reactions in the bulk state are introduced. The synthesis of segmented polyurethanes (SPUs) that contain difluorenylsuccinonitrile (DFSN) moieties in the main chain and methacryloyl groups in the side chains was carried out. DFSN was selected as the mechanophore because it dissociates under mech. stimuli to form pink cyanofluorene (CF) radicals, which can also initiate the radical polymerization of methacrylate monomers. The obtained elastomers generated CF radicals and changed color by compression or extension; they also became insoluble due to the mech. induced crosslinking reactions. Addnl., an SPU containing diphenylmethane units also exhibited highly sensitive mechanofluorescence. To the best of our knowledge, this is the first report to demonstrate damage detection ability and changes in the mech. properties of bulk elastomers induced by simple compression or extension.5-Hexen-1-ol(cas: 821-41-0SDS of cas: 821-41-0) was used in this study.

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.SDS of cas: 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2022,Cleveland, Jacob W.; Choi, Ji Il; Sekiya, Ryoh-Suke; Cho, Jinwon; Moon, Hyun June; Jang, Seung Soon; Jones, Christopher W. published an article in ACS Applied Materials & Interfaces. The title of the article was 《Cooperativity in the Aldol Condensation Using Bifunctional Mesoporous Silica-Poly(styrene) MCM-41 Organic/Inorganic Hybrid Catalysts》.Synthetic Route of C6H12O The author mentioned the following in the article:

This work explores the efficacy of silica/organic hybrid catalysts, where the organic component is built from linear aminopolymers appended to the silica support within the support mesopores. Specifically, the role of mol. weight and polymer chain composition in amine-bearing atom transfer radical polymerization-synthesized poly(styrene-co-2-(4-vinylbenzyl)isoindoline-1,3-dione) copolymers is probed in the aldol condensation of 4-nitrobenzaldehyde and acetone. Controlled polymerization produces protected amine-containing poly(styrene) chains of controlled mol. weight and dispersity, and a grafting-to thiol-ene coupling approach followed by a phthalimide deprotection step are used to covalently tether and activate the polymer hybrid catalysts prior to the catalytic reactions. Site-normalized batch kinetics are used to assess the role of polymer mol. weight and chain composition in the cooperative catalysis. Lower-mol.-weight copolymers are demonstrated to be more active than catalysts built from only mol. organic components or from higher-mol.-weight chains. Mol. dynamics simulations are used to probe the role of polymer flexibility and morphol., whereby it is determined that higher-mol.-weight hybrid structures result in congested pores that inhibit active site cooperativity and the diffusivity of reagents, thus resulting in lower rates during the reaction.5-Hexen-1-ol(cas: 821-41-0Synthetic Route of C6H12O) was used in this study.

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Synthetic Route of C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Davies, Jacob; Janssen-Muller, Daniel; Zimin, Dmitry P.; Day, Craig S.; Yanagi, Tomoyuki; Elfert, Jonas; Martin, Ruben published their research in Journal of the American Chemical Society in 2021. The article was titled 《Ni-Catalyzed carboxylation of aziridines en route to β-amino acids》.Electric Literature of C6H12O The article contains the following contents:

A Ni-catalyzed reductive carboxylation of N-substituted aziridines with CO2 at atm. pressure is disclosed. The protocol is characterized by its mild conditions, exptl. ease, and exquisite chemo- and regioselectivity pattern, thus unlocking a new catalytic blueprint to access β-amino acids, important building blocks with considerable potential as peptidomimetics. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0Electric Literature of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Electric Literature of C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

The author of 《Mechanistic Insights into FLP-Catalyzed Iodoperfluoroalkylations》 were Spittler, Michael; Helmecke, Lucas; Czekelius, Constantin. And the article was published in European Journal of Organic Chemistry in 2019. Synthetic Route of C6H12O The author mentioned the following in the article:

The frustrated Lewis pair-catalyzed iodoperfluoroalkylation of olefins, its substrate activation mode, and catalyst degradation pathways are mechanistically investigated by kinetic measurements. The transformation most likely proceeds via coordination of the phosphane to the perfluoroalkyl iodide and involves radical intermediates. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0Synthetic Route of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Synthetic Route of C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Reference of 5-Hexen-1-olIn 2020 ,《First total synthesis of 5(S)-hydroxyrecifeiolide》 appeared in Synthetic Communications. The author of the article were Kalyankar, Kondbarao Balasaheb; Das, Saibal. The article conveys some information:

The first total synthesis of recently isolated 5(S)-hydroxyrecifeiolide (I) has been described in ten straight forward linear steps with 14% of overall yield. The key reaction involves Jacobsen’s hydrolytic kinetic resolution, Copper catalyzed Grignard reaction, Steglich esterification and ring closing metathesis reaction using Grubbs 2nd generation catalyst making the synthesis very elegant and simple. The stereogenic center at C5 was generated via Jacobsen’s HKR which was confirmed by the Mandelate ester strategy as well as HPLC purity. In addition to this study using 5-Hexen-1-ol, there are many other studies that have used 5-Hexen-1-ol(cas: 821-41-0Reference of 5-Hexen-1-ol) was used in this study.

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Reference of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Giofre, Sabrina; Molteni, Letizia; Nava, Donatella; Lo Presti, Leonardo; Beccalli, Egle Maria published an article in 2021. The article was titled 《Enantio- and Regioselective Palladium(II)-Catalyzed Dioxygenation of (Aza-)Alkenols》, and you may find the article in Angewandte Chemie, International Edition.Category: alcohols-buliding-blocks The information in the text is summarized as follows:

An oxidative Pd-catalyzed intra-intermol. dioxygenation of (aza-)alkenols were reported, with total regioselectivity. To study the stereoselectivity, different chiral ligands as well as different hypervalent-iodine compounds was compared. In particular, by using a C-6 modified pyridinyl-oxazoline (Pyox) ligand and hypervalent iodine bearing an aromatic ring, an excellent enantio- and diastereoselectivity was achieved. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0Category: alcohols-buliding-blocks)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Journal of the American Chemical Society included an article by Sun, Shang-Zheng; Romano, Ciro; Martin, Ruben. Quality Control of 5-Hexen-1-ol. The article was titled 《Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins》. The information in the text is summarized as follows:

A catalytic deaminative alkylation of unactivated olefins is described. The protocol was characterized by its mild conditions, wide scope, including the use of ethylene as substrate, and exquisite site-selectivity pattern for both α-olefins and internal olefins, thus unlocking a new catalytic platform to forge sp3-sp3 linkages, even in the context of late-stage functionalization. In the part of experimental materials, we found many familiar compounds, such as 5-Hexen-1-ol(cas: 821-41-0Quality Control of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Quality Control of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts