Category: 821-41-0

《Deorphanization of an odorant receptor revealed new bioactive components for green mirid bug Apolygus lucorum (Hemiptera: Miridae)》 was written by Khashaveh, Adel; An, Xingkui; Shan, Shuang; Xiao, Yong; Wang, Qi; Wang, Shanning; Li, Zibo; Geng, Ting; Gu, Shaohua; Zhang, Yongjun. Application In Synthesis of 5-Hexen-1-ol And the article was included in Pest Management Science in 2020. The article conveys some information:

BACKGROUND : The Apolygus lucorum is one of the most destructive insect pests in China with a wide range of host plants. Interaction of A. lucorum with surrounding environment heavily relies on chem. communication. Deorphanization of receptors involved in odors detection elevates our understanding of the olfactory system of this pest and may help to develop a chem. ecol.-based control strategy. RESULTS : AlucOR80, an odorant receptor (OR) in A. lucorum was newly cloned. Gene expression anal. showed that this receptor was mainly expressed in the antennae and head of both sexes but with a male bias. The Xenopus oocytes heterologous expression system coupled with the two-electrode voltage-clamp (TEVC) recording revealed that AlucOR80 was tuned to 21 selected compounds Furthermore, electroantennogram (EAG) tests confirmed that all 21 ligands of AlucOR80 were electrophysiol. active in antennae of both sexes. Behavioral trials in a three-cage olfactometer indicated that 16 compounds were behaviorally active, amongst which, 12 components were attractants and four components were repellents for adults of both sexes. Bu butyrate and Di-Me disulfide (DMDS) were the strongest attractive and repellent compounds, resp. Importantly, we found the repellency of 1, 8-Cineole, S-(-)-cis-Verbenol and (1S)-(1)-beta-Pinene against adults of A. lucorum. CONCLUSION : Although AlucOR80 is a general OR, may play important role in the olfactory perception of A. lucorum. Screening of AlucOR80 ligands by behavioral assay provided valuable insights by which olfactory-based management approaches could be developed by utilizing the behaviorally active components as attractants or repellents. © 2019 Society of Chem. Industry The results came from multiple reactions, including the reaction of 5-Hexen-1-ol(cas: 821-41-0Application In Synthesis of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Application In Synthesis of 5-Hexen-1-ol

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The author of 《Grafting of Polymer Brushes from Xanthate-Functionalized Silica Particles》 were Ohno, Kohji; Yahata, Yoshikazu; Sakaue, Motokazu; Ladmiral, Vincent. And the article was published in Chemistry – A European Journal in 2019. COA of Formula: C6H12O The author mentioned the following in the article:

Monodisperse silica particles (SiPs) were surface-modified with a newly designed silane coupling agent comprising a triethoxysilane and an alkyl halide, namely, 6-(triethoxysilyl)hexyl 2-bromopropionate, which was further treated with potassium O-Et dithiocarbonate (PEX) to immobilize xanthate mols. on the particle surfaces. Surface-initiated macromol. design via interchange of xanthates (MADIX) polymerization of vinyl acetate (VAc) was conducted with the xanthate-functionalized SiPs. The polymerization was well controlled and produced SiPs coated with poly(vinyl acetate) (PVAc) with a well-defined target molar mass and a graft d. of about 0.2 chains nm-2. Dynamic light scattering and TEM measurements revealed that the hybrid particles were highly dispersible in good solvents without any aggregation. The PVAc brushes were hydrolyzed with hydrochloric acid to produce poly(vinyl alc.) brushes on the SiP surfaces. In addition, the number of xanthate mols. introduced on the SiP surfaces could be successfully controlled by adjusting the concentration of PEX. Thus, the SiPs have two functionalities: xanthates able to act as a MADIX chain-transfer agent and alkyl bromide initiation sites for atom transfer radical polymerization (ATRP). By using these unique bifunctional particles, mixed polymer brushes were constructed on the SiPs by MADIX of VAc followed by ATRP of styrene or Me methacrylate. After reading the article, we found that the author used 5-Hexen-1-ol(cas: 821-41-0COA of Formula: C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.COA of Formula: C6H12O

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Application of 821-41-0In 2019 ,《Surface Modification and Functionalization of Boron Nitride Nanotubes via Condensation with Saturated and Unsaturated Alcohols for High Performance Polymer Composites》 was published in ACS Applied Nano Materials. The article was written by Smith, Kamia K.; Redeker, Neil D.; Rios, Juan C.; Mecklenburg, Matthew H.; Marcischak, Jacob C.; Guenthner, Andrew J.; Ghiassi, Kamran B.. The article contains the following contents:

Over the past decade, boron nitride nanotubes (BNNTs) have been researched extensively due to their desirable phys., thermal, and mech. properties. However, a major challenge for BNNT utilization in applications is their poor processability and difficulty associated with their incorporation into materials and composites. The desire to incorporate BNNTs into relevant materials, specifically within the aerospace industry, calls for improving their processability. The successful grafting of reactive functionalities allows for improvements to the compatibility of BNNTs in polymer systems, allowing for the manufacturing of high performance BNNT-polymer composites. The research presented here addresses this concern, introducing a facile method for covalent surface functionalization of BNNTs with a diverse set of functional moieties allowing for homogeneous dispersibility in solvent. The grafted functionalities in this work are based on alkyl-, vinyl-, and propargyl-terminated alcs. covalently bound to BNNTs that were subjected to an oxidizing perchloric acid treatment. NMR spectroscopy, though not typically used for BNNT characterization, was successfully employed as a primary means to determine functionalization. Addnl. characterization methods including FTIR, SEM, TEM, and TGA also provide evidence of functionalization. Surface-functionalized materials were produced exhibiting up to 6 wt % functionality. Furthermore, visual anal. showed improved and stable dispersions lasting over 24 h, leading to potential benefits in processing for applications. The experimental part of the paper was very detailed, including the reaction process of 5-Hexen-1-ol(cas: 821-41-0Application of 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Application of 821-41-0

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The author of 《Metal-, Photocatalyst-, and Light-Free Minisci C-H Alkylation of N-Heteroarenes with Oxalates》 were Dong, Jianyang; Wang, Zhen; Wang, Xiaochen; Song, Hongjian; Liu, Yuxiu; Wang, Qingmin. And the article was published in Journal of Organic Chemistry in 2019. Quality Control of 5-Hexen-1-ol The author mentioned the following in the article:

Herein, the authors report a mild protocol for metal-, photocatalyst-, and light-free Minisci C-H alkylation reactions of N-heteroarenes with alkyl oxalates derived from primary, secondary, and tertiary alcs. The protocol uses environmentally benign persulfate as a stoichiometric oxidant and does not require high temperatures or large excesses of either of the substrates, making the procedure suitable for late-stage C-H alkylation of complex mols. Notably, several pharmaceuticals and natural products could be functionalized or prepared with this protocol, thus demonstrating its utility.5-Hexen-1-ol(cas: 821-41-0Quality Control of 5-Hexen-1-ol) was used in this study.

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Quality Control of 5-Hexen-1-ol

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Alcohol – Wikipedia,
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In 2019,Advanced Synthesis & Catalysis included an article by Oh, Hyunseok; Park, Areum; Jeong, Kyu-Sung; Han, Soo Bong; Lee, Hyuk. COA of Formula: C6H12O. The article was titled 《Copper-Catalyzed 1,2-Bistrifluoromethylation of Terminal Alkenes》. The information in the text is summarized as follows:

The catalytic 1,2-bistrifluoromethylations of alkenes catalyzed by Copper (Cu) have been reported. Two CF3 sources have been used, namely Umemoto’s reagent and (trifluoromethyl)trimethylsilane (TMSCF3). Each reagent plays a unique role during this transformation; Umemoto’s reagent generates CF3 radicals, while TMSCF3 is used to form CF3 anions. Copper (I) bromide (CuBr) exhibited the best catalytic activity for this reaction. CuBr oxidizes the alkyl radical, which is produced by the addition of CF3 radical to the alkenes R(CH2)nCH2=CH2 (Ar = 4-acetamidophenoxy, 3-methylphenoxy, phthalimido, (4-methylbenzene)sulfonamido, 4-formylphenoxy, etc.; n = 1, 2, 3, 4) to the corresponding alkyl cation, which then reacts with the CF3 anion from TMSCF3 to produce the desired products R(CH2)nCH(CF3)CH2CF3. This reaction tolerates a diverse set of substrates bearing functional groups such as amides, esters, ethers, ketones, protected amines, tertiary amines, and phthalimides, hence making this transformation to be widely applicable to a wide variety of substrates. After reading the article, we found that the author used 5-Hexen-1-ol(cas: 821-41-0COA of Formula: C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.COA of Formula: C6H12O

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Alcohol – Wikipedia,
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《Hypervalent Iodine(III)-Promoted Rapid Cascade Reaction of Quinoxalinones with Unactivated Alkenes and TMSN3》 was written by Shen, Jiabin; Xu, Jun; Huang, Lin; Zhu, Qing; Zhang, Pengfei. Product Details of 821-41-0 And the article was included in Advanced Synthesis & Catalysis in 2020. The article conveys some information:

The first example of rapidly three-component cascade reaction of quinoxalinones I (R1 = 6-OCH3, 6,7-(CH3)2, 7-Br, etc.; R2 = H, CH3, CH2C6H5, cyclohexylmethyl, etc.) with unactivated alkenes R3R4C=CHR5 (R3 = R4 = R5 = Me; R3 = n-Pr, R4 = R5 = H; R4 = H; R3R5 = -(CH2)4-, etc.) and TMSN3 under mild condition has been described. This approach provides a practical solution for the rapid modification of quinoxalinones and enables new planning strategies for the synthesis of bioactive organoazides II. A radical mechanism is responsible for this three-component transformation. In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Product Details of 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Product Details of 821-41-0

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《In Situ-Generated Halogen-Bonding Complex Enables Atom Transfer Radical Addition (ATRA) Reactions of Olefins》 was written by Matsuo, Kazuki; Yamaguchi, Eiji; Itoh, Akichika. Application of 821-41-0 And the article was included in Journal of Organic Chemistry in 2020. The article conveys some information:

Although organic-based photocatalysts provide an inexpensive, environmentally friendly alternative, many are incapable of absorption within the visible wavelength range; this ultimately influences their effectiveness. Photocatalytic reactions usually proceed via single electron transfer (SET) or energy transfer (ET) processes from the photoexcited mols. to the various substrates. In our study, the carbohalogenation of olefins was accomplished by combining CBr4 and 4-phenylpyridine under irradiation The atom transfer radical addition reaction of olefins was catalyzed by an in situ-formed photocatalyst via halogen bonding to afford a variety of products in moderate to good yields. Essential to the reaction is the formation of a CT complex with the haloalkane, which triggers charge separation processes and, ultimately, leads to the formation of the C-centered radical. While taking advantage of relatively inexpensive, readily available, and environmentally friendly reagents, the indirect activation of the substrate via the photoexcited catalyst paves the way for more efficient routes, especially for otherwise challenging chem. syntheses. In addition to this study using 5-Hexen-1-ol, there are many other studies that have used 5-Hexen-1-ol(cas: 821-41-0Application of 821-41-0) was used in this study.

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Application of 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Application In Synthesis of 5-Hexen-1-olIn 2020 ,《Electrochemical Difunctionalization of Olefines: Access to Selenomethyl-Substituted Cyclic Ethers or Lactones》 was published in Advanced Synthesis & Catalysis. The article was written by Meng, Xiu-Jin; Zhong, Ping-Fu; Wang, Yu-Mei; Wang, Heng-Shan; Tang, Hai-Tao; Pan, Ying-Ming. The article contains the following contents:

A metal- and oxidant-free electrochem. method for preparing selenomethyl-substituted cyclic ethers or lactones via difunctionalization of olefines is presented. A series of selenomethyl-substituted cyclic ethers, particularly 9- and 11- membered, selenomethyl-substituted lactones (4-6 membered), and selenomethyl-substituted phthalides can be obtained via this reaction. This method features convenient operation, an electron as oxidant, and ammonium iodide as electrolyte, thereby making it a green synthesis method. In addition to this study using 5-Hexen-1-ol, there are many other studies that have used 5-Hexen-1-ol(cas: 821-41-0Application In Synthesis of 5-Hexen-1-ol) was used in this study.

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Application In Synthesis of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Koley, Debasis; De, Sriman; Sivendran, Nardana; Goossen, Lukas J. published an article in 2021. The article was titled 《Isomerization of Functionalized Olefins by Using the Dinuclear Catalyst [PdI(μ-Br)(PtBu3)]2: A Mechanistic Study》, and you may find the article in Chemistry – A European Journal.Recommanded Product: 5-Hexen-1-ol The information in the text is summarized as follows:

In a combined exptl. and computational study, the isomerization activity of the dinuclear palladium(I) complex [PdI(μ-Br)(PtBu3)]2 towards allyl arenes, esters, amides, ethers, and alcs. has been investigated. The calculated energy profiles for catalyst activation for two alternative dinuclear and mononuclear catalytic cycles, and for catalyst deactivation are in good agreement with the exptl. results. Comparison of exptl. observed E/Z ratios at incomplete conversion with calculated kinetic selectivities revealed that a substantial amount of product must form via the dinuclear pathway, in which the isomerization is promoted cooperatively by two palladium centers. The dissociation barrier towards mononuclear Pd species is relatively high, and once the catalyst enters the energetically more favorable mononuclear pathway, only a low barrier has to be overcome towards irreversible deactivation. After reading the article, we found that the author used 5-Hexen-1-ol(cas: 821-41-0Recommanded Product: 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Recommanded Product: 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Hypervalent iodine(III)-promoted rapid cascade reaction for the synthesis of unsymmetric azo compounds》 was written by Shen, Jiabin; Xu, Jun; Zhu, Qing; Zhang, Pengfei. Product Details of 821-41-0This research focused onunsym diazene preparation hypervalent iodine promoter; aryldiazonium salt alkene trimethylsilyl azide three component tandem reaction. The article conveys some information:

A rapid three-component cascade reaction for the synthesis of unsym. azo compounds via a radical activation strategy has been reported. Various aryldiazonium salts and unactivated alkenes are well compatible, providing the corresponding products in good to excellent yields. This strategy gives an efficient and practical solution for the synthesis of unsym. azo compounds with two C-N bond formation. A free radical pathway mechanism is advised for this transformation. In addition to this study using 5-Hexen-1-ol, there are many other studies that have used 5-Hexen-1-ol(cas: 821-41-0Product Details of 821-41-0) was used in this study.

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Product Details of 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts