Category: 821-41-0

Casnati, Alessandra; Lichosyt, Dawid; Lainer, Bruno; Veth, Lukas; Dydio, Pawel published their research in Organic Letters in 2021. The article was titled 《Multicatalytic Approach to One-Pot Stereoselective Synthesis of Secondary Benzylic Alcohols》.Reference of 5-Hexen-1-ol The article contains the following contents:

Here, one-pot, multicatalytic protocols that convert alkenes, unsaturated aliphatic alcs., and aryl boronic acids into secondary benzylic alcs. with high stereoselectivities (typically >95:5 er) under sequential catalysis that integrates alkene cross-metathesis, isomerization, and nucleophilic addn was reported. Prochiral allylic alcs. was converted to any stereoisomer of the product with high stereoselectivity (>98:2 er, >20:1 dr). The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Reference of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Reference of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Imidodiphosphorimidate (IDPi) as an efficient organocatalyst for controlled/living ring-opening polymerization of lactones》 was written by Zhang, Xun; Jiang, Yu; Ma, Qiang; Hu, Siping; Wang, Qinggang; Liao, Saihu. SDS of cas: 821-41-0 And the article was included in European Polymer Journal in 2020. The article conveys some information:

Imidodiphosphorimidate (IDPi) is demonsatreted as a novel and efficient acid/base bifunctional organocatalyst for controlled/living ring-opening polymerization of lactones, which delivered the metal-free poly(δ-valerolactone) and poly(ε-caprolactone) with excellent control over the mol. weight and narrow dispersity at a low catalyst loading under mild conditions. NMR and MALDI-TOF characterizations, kinetic study, and chain extension experiment suggest a well-controlled/living nature of the current ROP of lactones catalyzed by the IDPi catalyst. In addition to this study using 5-Hexen-1-ol, there are many other studies that have used 5-Hexen-1-ol(cas: 821-41-0SDS of cas: 821-41-0) was used in this study.

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.SDS of cas: 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Visible-Light-Promoted Iododifluoromethylation of Alkenes via (Phosphonio)difluoromethyl Radical Cation》 was published in Organic Letters in 2020. These research results belong to Trifonov, Alexey L.; Panferova, Liubov I.; Levin, Vitalij V.; Kokorekin, Vladimir A.; Dilman, Alexander D.. Computed Properties of C6H12O The article mentions the following:

A reaction of an iododifluoromethylphosphonium salt with unactivated alkenes mediated by peri-xanthenoxanthene under blue-light irradiation is described. The reaction proceeds via activation of the carbon-iodine bond to generate (phosphonio)difluoromethyl radical cation, which attacks the double bond with subsequent quenching by the iodine. The intermediate phosphonium salts are easily hydrolyzed, furnishing products of iododifluoromethylation of alkenes. In addition to this study using 5-Hexen-1-ol, there are many other studies that have used 5-Hexen-1-ol(cas: 821-41-0Computed Properties of C6H12O) was used in this study.

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Computed Properties of C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes》 was published in Nature Communications in 2020. These research results belong to Shen, Xuzhong; Chen, Xu; Chen, Jieping; Sun, Yufeng; Cheng, Zhaoyang; Lu, Zhan. Synthetic Route of C6H12O The article mentions the following:

Here, a ligand-promoted cobalt-catalyzed Markovnikov-type selective radical hydroamination of alkenes with diazo compounds was reported. This operationally simple protocol uses unsym. NNN-tridentate (UNT) ligand, readily available alkenes and hydrosilanes to construct hydrazones I (R = C6H5, 4-FC6H4, 3-pyridyl, etc.; R1 = Et, t-Bu, 4-MeOC6H4) with good functional group tolerance. The hydrazones can underwent nitrogen-nitrogen bond cleavage smoothly to deliver valuable amine derivatives Addnl., asym. intermol. hydroamination of unactivated aliphatic terminal alkenes using chiral N-imidazolinylphenyl 8-aminoquinoline (IPAQ) ligands has also been achieved to afford chiral amine derivatives II (R = Et, 4-FC6H4, C6H5CH2CH2, etc.; PG = Boc, Bz, (CH2)2CH(Ph)2, etc.) with good enantioselectivities. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0Synthetic Route of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Synthetic Route of C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Science China: Chemistry included an article by Li, Xiaonan; Chen, Pinhong; Liu, Guosheng. Formula: C6H12O. The article was titled 《Iodine(III) reagent (ABX-N3)-induced intermolecular anti-Markovnikov hydroazidation of unactivated alkenes》. The information in the text is summarized as follows:

Anti-Markovnikov hydroazidation of unactivated alkenes using ABX-N3 as an initiator has been developed at room temperature, wherein hydrogen azide (HN3) acts as both hydrogen source and azidation agent. Notably, the HN3 reagent was generated from azidotrimethylsilane (TMSN3) and acetic acid in situ. The reaction itself displays broad substrate scope, good yields, and excellent regioselectivities. In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Formula: C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Formula: C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Quality Control of 5-Hexen-1-olIn 2021 ,《Oxidative additions of alkynyl/vinyl iodides to gold and gold-catalyzed vinylation reactions triggered by the MeDalphos ligand》 was published in Chemical Science. The article was written by Rodriguez, Jessica; Tabey, Alexis; Mallet-Ladeira, Sonia; Bourissou, Didier. The article contains the following contents:

The hemilabile Ad2P(o-C6H4)NMe2 ligand promotes fast, quant. and irreversible oxidative addition of alkynyl and vinyl iodides to gold. The reaction is general. It works with a broad range of substrates of various electronic bias and steric demand, and proceeds with complete retention of stereochem. from Z and E vinyl iodides. Both alkynyl and vinyl iodides react faster than aryl iodides. The elementary step is amenable to catalysis. Oxidative addition of vinyl iodides to gold and π-activation of alkenols (and N-alkenyl amines) at gold have been combined to achieve hetero-vinylation reactions. A number of functionalized heterocycles, i.e. tetrahydrofurans, tetrahydropyrans, oxepanes and pyrrolidines were obtained thereby (24 examples, 87% average yield). Taking advantage of the chemoselectivity for vinyl iodides over aryl iodides, sequential transformations involving first a hetero-vinylation step and then a C-N coupling, a C-C coupling or an heteroarylation were achieved from a vinyl/aryl bis-iodide substrate. The results came from multiple reactions, including the reaction of 5-Hexen-1-ol(cas: 821-41-0Quality Control of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Quality Control of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

The author of 《Rheo-Optical Near-Infrared (NIR) Characterization of Hydroxyl-Functionalized Polypropylene (PPOH)-Mesoporous Silica Nanocomposites Using Two-Trace Two-Dimensional (2T2D) Correlation Analysis》 were Watanabe, Ryota; Hagihara, Hideaki; Sato, Hiroaki; Mizukado, Junji; Shinzawa, Hideyuki. And the article was published in Applied Spectroscopy in 2019. Synthetic Route of C6H12O The author mentioned the following in the article:

A rheo-optical characterization technique based on the combination of near-IR (NIR) spectroscopy and mech. anal. was applied to the nanocomposite consisting of hydroxyl-functionalized polypropylene (PPOH) and mesoporous silica (MPS) to probe the deformation behavior. Substantial levels of spectral changes of NIR spectral features were captured when the polymer samples underwent tensile deformation. Sets of spectra were subjected to projection treatment to remove the effect of baseline fluctuations and thickness change inevitably caused by the tensile deformation of the sample. Then, two-trace two-dimensional (2T2D) correlation spectroscopy was applied to the pretreated spectra to elucidate spectroscopic signature associated with the difference between the initial and deformed samples. An asynchronous correlation peak appears between the bands at 1720 and 1700 nm resp. reflecting the contributions of predominantly amorphous and crystalline component of the PPOH, indicating the predominant variation of amorphous structure followed by that of crystalline structure. In addition, the predominant spectral change related to the amorphous band becomes even more acute by including the MPS with large pores. It is hence likely that the larger pore size of the MPS confines the more amorphous structure, which, in turn, causes simultaneous reorientation of the polymer chains in the amorphous region during the elastic deformation. Consequently, the incorporation of the MPS selectively restricts the deformation of the amorphous structure which eventually provides the obvious increase in the mech. property of the PPOH polymer. In the part of experimental materials, we found many familiar compounds, such as 5-Hexen-1-ol(cas: 821-41-0Synthetic Route of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Synthetic Route of C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Mass spectrometry distinguishing C=C location and cis/trans isomers: A strategy initiated by water radical cations》 was written by Zhang, Xiaoping; Ren, Xiang; Chingin, Konstantin; Xu, Jiaquan; Yan, Xin; Chen, Huanwen. Computed Properties of C6H12O And the article was included in Analytica Chimica Acta in 2020. The article conveys some information:

We present an approach for the elucidation of C=C bond position and cis/trans isomers, which is achieved by the reaction of ambient water radical cations and double bonds, followed by the fragmentation of epoxide radical cations to generate diagnostic ions in tandem mass spectrometry. Hexenol double bond positional isomers and cis/trans isomers which exhibit different properties and biol. functions are characterized as a proof of concept. The merits of the approach include the simplicity of exptl. setup, rapid derivatization (within seconds), the obviation of organic solvents, as well as easy spectral interpretation. In the experimental materials used by the author, we found 5-Hexen-1-ol(cas: 821-41-0Computed Properties of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Computed Properties of C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,European Polymer Journal included an article by Liu, Jingjing; Zhang, Chan; Li, Zhenjiang; Zhang, Lei; Xu, Jiaxi; Wang, Haixin; Xu, Songquan; Guo, Tianfo; Yang, Kun; Guo, Kai. Related Products of 821-41-0. The article was titled 《Dibutyl phosphate catalyzed commercial relevant ring-opening polymerizations to bio-based polyesters》. The information in the text is summarized as follows:

Organocatalyzed ring-opening polymerization (ROP) of cyclic esters was developed into a stage that demanding translation of the academic success into com. viable production An industrial relevant development of the organocatalysis in ROPs required bulk polymerizations at high temperatures up to 180 °C. Organic phosphoric acid was one of the few organocatalysts workable under these conditions that devoid of otherwise commonly appeared transesterification, epimerization, and decarboxylation in the ROPs. A com. di-Bu phosphate (DBuP), which was inexpensive and available by hundreds of tons as antistatic agent, was firstly evaluated as a catalyst. Well-defined polyesters catalyzed by DBuP were obtained with narrow dispersities (Dm 1.08-1.31) and predicted mol. weights from 2.1 to 55 kg mol-1. Series of homopolymers, diblock copolymers and end-functionalized polymers of ε-caprolactone (CL), δ-valerolactone (VL), trimethylene carbonate (TMC), and L-lactide (LA) were synthesized. 1H NMR, 13C NMR, SEC, and MALDI-ToF MS analyses indicated that the obtained polyesters were exactly the designated ones. NMR titration experiments confirmed that the ROP proceeded a bifunctional activation mechanism. The cytotoxicity test using MTT assay showed biosafety of the polyesters. The exptl. results suggested that di-Bu phosphate is a com. organocatalyst widely useful in all major cyclic ester monomer toward com. relevant ring-opening polymerizations In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Related Products of 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Related Products of 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2022,Chen, Su; Van der Eycken, Erik V.; Sharma, Upendra K. published an article in Advanced Synthesis & Catalysis. The title of the article was 《Remote Alkenylation via Carbopalladation/1,4-Palladium Migration/Heck Reaction Sequence with Unactivated Alkenyl Alcohols》.Recommanded Product: 821-41-0 The author mentioned the following in the article:

Intramol. C-H bond activation via 1,4-palladium migration has become a synthetic tool to enable remote functionalization of C-H bonds. In this work, authors report a Pd-catalyzed remote alkenylation with unactivated alkenyl alcs. involving a 1,4-palladium migration step. This method provides a regioselective access to synthesize substituted unsaturated alcs. in a single operational step. The results came from multiple reactions, including the reaction of 5-Hexen-1-ol(cas: 821-41-0Recommanded Product: 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Recommanded Product: 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts