Category: 821-41-0

In 2019,Nature Catalysis included an article by Maity, Soham; Potter, Tyler J.; Ellman, Jonathan A.. Related Products of 821-41-0. The article was titled 《Î?Branched amines by catalytic 1,1-addition of C-H bonds and aminating agents to terminal alkenesã€? The information in the text is summarized as follows:

The convergent synthesis of α-branched amines e.g., I was achieved from three readily accessible starting materials: aromatic C-H bond substrates, terminal alkenes and aminating agents. This reaction proceeded by an intermol. formation of C-C and C-N bonds at the sp3 carbon branch site through an uncommon 1,1-alkene addition pathway. Ethylene and propylene feedstock chems. were effective alkene inputs, with ethylene in particular provided one-step synthesis of α-Me branched amines, a motif prevalent in drug structures. The reaction was scalable and 1% loading of an air-stable dimeric rhodium precatalyst was effective for several different types of products. The use of chiral catalysts also enabled the asym. synthesis of α-branched amines. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Related Products of 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Related Products of 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Organic Letters included an article by Afeke, Cephas; Xie, Youwei; Floreancig, Paul E.. HPLC of Formula: 821-41-0. The article was titled 《Re2O7-Catalyzed Approach to Spirocyclic Ether Formation from Acyclic Precursors: Observation of Remote Stereoinductionã€? The information in the text is summarized as follows:

Ketones that are flanked by an allylic alc. and an alkene isomerize to spirocyclic ethers in the presence of Re2O7 through allylic alc. transposition, oxocarbenium ion formation, and Prins cyclization. These processes provide significant increases in mol. complexity, with multiple stereocenters being set relative to a stereocenter in the substrate. Stereoselectivity arises from the initial reversible steps being more rapid than the final step, thereby allowing for thermodynamically controlled stereochem. equilibration prior to product formation. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0HPLC of Formula: 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.HPLC of Formula: 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Trifluoromethylation of Unactivated Alkenes with Me3SiCF3 and N-Iodosuccinimideã€?was written by Yang, Xinkan; Tsui, Gavin Chit. Formula: C6H12OThis research focused ontrifluoromethylation unactivated alkene trifluoromethyltrimethylsilane iodosuccinimide visible light irradiation. The article conveys some information:

A novel approach to the trifluoromethylation of unactivated alkenes is presented. This reaction is promoted by N-iodosuccinimide (NIS) under visible light irradiation without the need for photocatalysts. The mild conditions allow the direct synthesis of useful trifluoromethylated (E)-alkenes from readily available alkene feedstocks with excellent functional group tolerability. In addition, using easy-to-handle and com. Me3SiCF3 instead of gaseous CF3I as the CF3 source is highly attractive for industrial-scale applications. After reading the article, we found that the author used 5-Hexen-1-ol(cas: 821-41-0Formula: C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Formula: C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Photoinduced Rapid Multicomponent Cascade Reaction Of Aryldiazonium Salts With Unactivated Alkenes And TMSN3ã€?was written by Shen, Jiabin; Xu, Jun; He, Lei; Ouyang, Yani; Huang, Lin; Li, Wanmei; Zhu, Qing; Zhang, Pengfei. SDS of cas: 821-41-0This research focused onunsym azo compound preparation; aryldiazonium salt alkene trimethylsilyl azide cascade three component photocatalyst. The article conveys some information:

A photoinduced rapid multicomponent cascade reaction of aryldiazonium salts with unactivated alkenes and trimethylsilyl azide (TMSN3) under oxidant-free conditions to afford unsym. azo compounds I [R1 = Me, nPr, Bn, etc.; R2 = H, Me; R3 = H, Me; Ar = Ph, 4-MeOC6H4, 2-FC6H4, etc.] was described. Compounds I were obtained in good to excellent yields under mild reaction conditions. In the part of experimental materials, we found many familiar compounds, such as 5-Hexen-1-ol(cas: 821-41-0SDS of cas: 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.SDS of cas: 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《E- and Z-, di- and tri-substituted alkenyl nitriles through catalytic cross-metathesisã€?was written by Mu, Yucheng; Nguyen, Thach T.; Koh, Ming Joo; Schrock, Richard R.; Hoveyda, Amir H.. COA of Formula: C6H12OThis research focused onunsaturated nitrile diastereoselective stereoretentive preparation; molybdenum catalyst stereoretentive cross metathesis alkene acrylonitrile maleonitrile fumaronitrile; pinacolborane isopropylphenylborane protecting group oleic alc acid cross metathesis. The article conveys some information:

Molybdenum alkylidene complexes (either molybdenum-based monoaryloxide pyrrolides or chlorides) were used as catalysts for the diastereoselective olefin metathesis reactions of alkenes with acrylonitrile, maleonitrile, or fumaronitrile to provide (E)- or (Z)-α,β-unsaturated nitriles and trisubstituted α,β-unsaturated nitriles. Oleyl alc. and oleic acid underwent stereoselective cross-metathesis with maleonitrile using pinacolborane or bis(triisopropylphenyl)borane as in-situ protecting group reagents. Intermediates toward the synthesis of natural products and pharmaceuticals were prepared using these methods. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0COA of Formula: C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.COA of Formula: C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Formula: C6H12OIn 2019 ,《Iron-catalyzed regioselective hydrogenation of terminal epoxides to alcohols under mild conditionsã€?appeared in Nature Catalysis. The author of the article were Liu, Weiping; Li, Wu; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias. The article conveys some information:

Here, a general methodol. was presented for the synthesis of primary alcs. CH(R1)(R2)CH2OH [R1 = n-Bu, Ph, 2-naphthyl, etc.; R2 = H, Me, Ph; R1R2 = (CH2)5, (CH2)7] in high yields, selectively under mild conditions via hydrogenation of terminal epoxides using Fe(BF4)2.6H2O/tetraphos catalyst system. The present protocol showed broad substrate scope and good functional group tolerance. The generality of this is showcased by transformation of various natural products, including steroids, terpenoids, sesquiterpenoids and drug derivatives, which gave the desired alcs. in moderate to excellent yields. Mechanistic studies confirmed the distinct feature of the catalyst system, which is active for Meinwald rearrangement of epoxides as well as for carbonyl hydrogenations. The experimental part of the paper was very detailed, including the reaction process of 5-Hexen-1-ol(cas: 821-41-0Formula: C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Formula: C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Application of 821-41-0In 2019 ,《Highly Performing Iodoperfluoroalkylation of Alkenes Triggered by the Photochemical Activity of Perylene Diimidesã€?was published in ChemPhotoChem. The article was written by Rosso, Cristian; Filippini, Giacomo; Cozzi, Pier Giorgio; Gualandi, Andrea; Prato, Maurizio. The article contains the following contents:

A novel efficient photochem. procedure for the direct iodoperfluoroalkylation of terminal olefins was developed. The process uses a simple and inexpensive perylenediimide (PDI) in an extremely low catalytic loading and occurs with visible light irradiation The methodol. was highly valuable from a synthetic point of view, since it proceeded under mild reaction conditions with a significant rate of production Preliminary mechanistic investigations were also reported. In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Application of 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Application of 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Organic Letters included an article by Tong, Chao-Lai; Xu, Xiu-Hua; Qing, Feng-Ling. Quality Control of 5-Hexen-1-ol. The article was titled 《Oxidative Hydro-, Bromo-, and Chloroheptafluoroisopropylation of Unactivated Alkenes with Heptafluoroisopropyl Silverã€? The information in the text is summarized as follows:

Oxidant-induced three-component hydro-, bromo-, and chloroheptafluoroisopropylation of unactivated alkenes are disclosed. In these reactions, the CF(CF3)2 radical was generated from the oxidation of AgCF(CF3)2. Then the addition of this perfluorinated radical to alkenes, followed by hydrogenation, bromination, or chlorination, gave the corresponding difunctionalized CF(CF3)2-containing products in high yields. In the experimental materials used by the author, we found 5-Hexen-1-ol(cas: 821-41-0Quality Control of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Quality Control of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Metal-Free Visible Light Hydroperfluoroalkylation of Unactivated Alkenes Using Perfluoroalkyl Bromidesã€?was written by Yajima, Tomoko; Shigenaga, Satsuki. Electric Literature of C6H12OThis research focused onunactivated alkene perfluoroalkyl bromide hydroperfluoroalkylation visible light organocatalyst; perfluoroalkyl alkane preparation; visible light hydroperfluoroalkylation promoter; organic dye hydroperfluoroalkylation organocatalyst. The article conveys some information:

Organic dye-catalyzed visible light induced hydroperfluoroalkylation of unactivated alkenes is described. Hydroperfluoroalkylation proceeds selectively and is applicable for various perfluoroalkyl bromide and alkenes including internal alkenes. The reaction mechanism is discussed, and it is shown that the hydrogen source varies with reaction conditions. In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Electric Literature of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Electric Literature of C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Synthetic Route of C6H12OIn 2019 ,《Randomly Functionalized Polyethylenes: In Quest of Avoiding Catalyst Deactivationã€?appeared in ACS Catalysis. The author of the article were Bouyahyi, Miloud; Turki, Younes; Tanwar, Akhilesh; Jasinska-Walc, Lidia; Duchateau, Rob. The article conveys some information:

Well-defined randomly functionalized polyolefins produced by catalysis form an interesting class of polymers with great potential for various applications. One of the major challenges for the production of these materials forms the incompatibility of the commonly used electrophilic group 4 metal based catalysts and the desired nucleophilic, especially protic functionalities like hydroxyl and carboxylic acid groups. Although pacification of the protic functionality remains necessary, it was found that lowering the oxidation state of a constrained geometry type of catalyst from Ti(IV) to Ti(III) turned the catalyst unexpectedly tolerant to a wide variety of aluminum alkyl pacified, hydroxyl-functionalized olefin comonomers. The catalyst’s tendency to undergo chain transfer to aluminum, which was found to be intensified by the presence of aluminum alkyl pacified, hydroxyl-functionalized comonomers, can be efficiently suppressed by the addition of a sterically hindered phenol such as 2,6-bis(1,1-dimethylethyl)-4-methylphenol (BHT). Surprisingly, the addition of BHT also increases the catalyst’s affinity to incorporate these functionalized comonomers. In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Synthetic Route of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Synthetic Route of C6H12O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts