Category: 699-12-7

Nikoorazm, Mohsen; Erfani, Zahra published the artcile< Fe3O4@MCM-41@Zn-Arg: as a novel, magnetically recoverable and ecofriendly nanocatalyst for the synthesis of disulfides, sulfoxides and 2,3-dihydroquinazolin-4(1H)-ones>, COA of Formula: C8H10OS, the main research area is disulfide sulfoxide dihydroquinazolinone green preparation zinc arginine complex catalyst.

The direct supporting of Zn-arginine complex on magnetic core-shell nanostructures (Fe3O4@MCM-41@Zn-Arg) was reported as a novel, heterogeneous and excellent nanocatalyst, which was applied for the oxidation reaction of sulfides to sulfoxides, oxidative coupling of thiols to their corresponding disulfides and the synthesis of 2,3-dihydroquinazolin-4(1H)-one derivatives under mild conditions. The simple exptl. procedure, very good catalytic activity, low cost, and excellent recycling are the noteworthy features of the currently employed heterogeneous catalytic system.

Inorganic and Nano-Metal Chemistry published new progress about Aryl aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, COA of Formula: C8H10OS.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Rasouli, Mohsen; Zolfigol, Mohammad Ali; Moslemin, Mohammad Hossien; Mohebat, Razieh; Chehardoli, Gholamabbas published the artcile< H2O2 as a green and environmentally benign reagent for the oxidation of sulfides in the presence of {[K.18-Crown-6]X3}n (X=Br, I) compared with some other organic tribromides>, Category: alcohols-buliding-blocks, the main research area is sulfoxide preparation green chem; sulfide oxidation hydrogen peroxide crown ether trihalide.

In the presence of {[K.18-Crown-6]X3}n (X = Br, I)-as interesting trihalide reagents, organic sulfides were oxidized to their corresponding sulfoxides using H2O2 as a green reagent. {[K.18-Crown-6]X3}n activates H2O2 via in situ generation of HOX and variously substituted sulfides were selectively transformed into the corresponding sulfoxides. The obtained results of {[K.18-Crown-6]X3}n with some other organic tribromides have been compared. Unexpectedly, in most cases, the results were similar.

Eurasian Chemical Communications published new progress about Green chemistry. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Category: alcohols-buliding-blocks.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Firsin, I. D.; Chuchelkin, I. V.; Gavrilov, V. K.; Trunina, V. M.; Zimarev, V. S.; Zheglov, S. V.; Gavrilov, K. N.; Goulioukina, N. S. published the artcile< Chiral P*,S-bidentate diamidophosphites with 1,2-thioether alcohol-based exocyclic substituents in asymmetric Pd-catalyzed reactions>, COA of Formula: C8H10OS, the main research area is chiral bidentate diamidophosphite thioether alc exocyclic palladium catalyst.

Chiral P*,S-diamidophosphites with a 1,3,2-diazaphospholidine core and exocyclic 1,2-hydroxyl-thioether fragments were prepared These asym. inducers provided up to 86% ee in the Pd-catalyzed allylic substitution of (E)-1,3-diphenylallyl acetate with di-Me malonate and pyrrolidine, and up to 76% in the Pd-mediated allylic alkylation of cinnamyl acetate with Et 2-oxocyclohexane-1-carboxylate.

Phosphorus, Sulfur and Silicon and the Related Elements published new progress about Allylic alkylation catalysts, stereoselective. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, COA of Formula: C8H10OS.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Firsin, I. D.; Chuchelkin, I. V.; Gavrilov, V. K.; Trunina, V. M.; Zimarev, V. S.; Zheglov, S. V.; Gavrilov, K. N.; Goulioukina, N. S. published the artcile< Chiral P*,S-bidentate diamidophosphites with 1,2-thioether alcohol-based exocyclic substituents in asymmetric Pd-catalyzed reactions>, COA of Formula: C8H10OS, the main research area is chiral bidentate diamidophosphite thioether alc exocyclic palladium catalyst.

Chiral P*,S-diamidophosphites with a 1,3,2-diazaphospholidine core and exocyclic 1,2-hydroxyl-thioether fragments were prepared These asym. inducers provided up to 86% ee in the Pd-catalyzed allylic substitution of (E)-1,3-diphenylallyl acetate with di-Me malonate and pyrrolidine, and up to 76% in the Pd-mediated allylic alkylation of cinnamyl acetate with Et 2-oxocyclohexane-1-carboxylate.

Phosphorus, Sulfur and Silicon and the Related Elements published new progress about Allylic alkylation catalysts, stereoselective. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, COA of Formula: C8H10OS.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Ghadermazi, Mohammad; Molaei, Somayeh; Ghadermazi, Nahid published the artcile< Introduction of Fe into mesoporous MCM-41 for the synthesis of 5-substituted 1H-Tetrazoles from aryl nitriles in water>, Recommanded Product: 2-(Phenylthio)ethanol, the main research area is mesoporous supported iron silica catalyst preparation; tetrazole sulfoxide preparation green chem; aryl nitrile sulfide oxidation water.

In this exploration, new recyclable mesoporous-supported iron particles with the ligand and without ligand (MCM-41@ 3,4,5-tri hydroxyphenyl acetic acid @Fe and MCM-41@Fe) have been developed through post-functionalization modification of silica MCM-41. These catalysts were demonstrated to be novel, effective, and green for the synthesis of 5-substituted 1H-tetrazoles from aryl nitriles in water. In these systems, 5-substituted 1H-tetrazoles are produced as the only product. Fe3+ species were identified as active sites. The ordered mesoporous iron-silica catalyst with the ligand displayed better catalytic activity compared to iron-silica catalyst without the ligand, which was ascribed to the improvement of the inter-action of iron with the support. The catalysts can be easily separated using simple recovery and reused several times with consistent activity.

Microporous and Mesoporous Materials published new progress about Aromatic nitriles Role: RCT (Reactant), RACT (Reactant or Reagent). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Recommanded Product: 2-(Phenylthio)ethanol.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Jaradat, Nidal; Khasati, Ahmad; Hawi, Maram; Hawash, Mohammed; Shekfeh, Suhaib; Qneibi, Mohammad; Eid, Ahmad M.; Arar, Mohammad; Qaoud, Mohammed T. published the artcile< Antidiabetic, antioxidant, and anti-obesity effects of phenylthio-ethyl benzoate derivatives, and molecular docking study regarding α-amylase enzyme>, Safety of 2-(Phenylthio)ethanol, the main research area is phenylthio ethylbenzoate antidiabetic antioxidant antiobesity mol docking alpha amylase.

In addition to their wide therapeutic application, benzoates and benzoic acid derivatives are the most commonly utilized food preservatives. The purpose of this study was to estimate the antioxidant, anti-diabetic, and anti-obesity activities of four 2-(phenylthio)-Et benzoate derivatives utilizing standard biomedical assays. The results revealed that the 2a compound has potent antidiabetic activity through the inhibition of α-amylase and α-glycosidase with IC50 doses of 3.57 ± 1.08 and 10.09 ± 0.70 μg/mL, resp., compared with the pos. control acarbose (IC50 = 6.47 and 44.79 μg/mL), resp. In addition, by utilizing the β-carotene linoleic acid and DPPH methods, the 2a compound showed the highest antioxidant activity compared with pos. controls. Moreover, the 2a compound showed potential anti-lipase activity with an IC50 dose of 107.95 ± 1.88 μg/mL compared to orlistat (IC50 = 25.01 ± 0.78 μg/mL). A mol. docking study was used to understand the interactions between four derivatives of (2-(phenylthio)-Et benzoate with α-amylase binding pocket. The present study concludes that the 2a compound could be exploited for further antidiabetic, antioxidant, and anti-obesity preclin. and clin. tests and design suitable pharmaceutical forms to treat these global health problems.

Scientific Reports published new progress about Antidiabetic agents. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Safety of 2-(Phenylthio)ethanol.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Bayat, Yadollah; Shirini, Farhad; Goli-Jolodar, Omid published the artcile< Selective oxidation of sulfides to sulfoxides using novel nano Bronsted dicationic ionic liquid as effective reagent under grinding conditions>, SDS of cas: 699-12-7, the main research area is sulfoxide preparation green chem; sulfide selective oxidation nano bronsted dicationic ionic liquid.

In this work, 1,1′-(butane-1,4-diyl)bis(1,4-diazabicyclo[2.2.2]octane-1,4-diium) bis(hydrogen sulfate) dinitrate ([C4(DABCO-H)2]·[HSO4]2[NO3]2) as a novel Bronsted dicationic ionic liquid was prepared with available starting materials, and characterized by FT-IR, 1H NMR, 13C NMR, TGA, DSC, SEM and FESEM techniques. This nano-sized regent was efficiently employed in selective oxidation of sulfides to sulfoxides at room temperature, under grinding and solvent-free condition. A simple method, short reaction times, high yields, green and easy work-up of the products, use of com. cheap starting materials and excellent selectivity are attractive features of the present method.

Journal of Molecular Liquids published new progress about Green chemistry. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, SDS of cas: 699-12-7.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Ghorbani-Choghamarani, Arash; Moradi, Parisa; Tahmasbi, Bahman published the artcile< Nickel(II) immobilized on dithizone-boehmite nanoparticles: as a highly efficient and recyclable nanocatalyst for the synthesis of polyhydroquinolines and sulfoxidation reaction>, Related Products of 699-12-7, the main research area is polyhydroquinoline sulfoxidation reaction nickel dithizone boehmite nanoparticle.

In this work, in the first stage, boehmite nanoparticles were easily fabricated via addition of NaOH solution to a solution of Al(NO3)3.9H2O at room temperature in water. Then, nickel-dithizone catalyst was supported on boehmite nanoparticles (Ni-dithizone@boehmite). Ni-dithizone@boehmite is a low-cost, nontoxic, and recoverable catalyst, which provides an environment friendly reaction conditions. In the second stage, catalytic activity of this catalyst was studied in the synthesis of polyhydroquinoline derivatives and selective oxidation of sulfides to sulfoxides. The reactions not require very high temperatures or inert atm. The developed heterogeneous catalyst could be easily separated by centrifugation and recycled for several runs without leaching of Nickel from the surface of the catalyst or significant loss of its catalytic activity.

Journal of the Iranian Chemical Society published new progress about Nanocatalysts. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Related Products of 699-12-7.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Tamoradi, Taiebeh; Ghorbani-Choghamarani, Arash; Ghadermazi, Mohammad published the artcile< Immobilization of Pd(0) complex on the surface of SBA-15: A reusable catalyst for the synthesis of 5-substituted tetrazoles, sulfides and sulfoxides>, Product Details of C8H10OS, the main research area is tetrazole preparation sulfide sulfoxide preparation palladium complex catalyst.

A simple and efficient method for the synthesis of 5-substituted tetrazoles, sulfides and sulfoxides in the presence of Pd(0) complex immobilized on mesoporous SBA-15 as an efficient, recoverable and thermally stable mesostructure was reported. Also, the prepared mesostructure was characterized by Fourier transform IR spectroscopy, SEM, x-ray mapping, energy-dispersive x-ray spectroscopy, N2 adsorption and desorption, inductively coupled plasma optical emission spectroscopy and thermal gravimetric anal. Then, this mesostructured catalyst was applied in the synthesis of 5-substituted tetrazoles, sulfides and sulfoxides. The approach described here offers advantages such as short reaction times, high yield, purity yields, simple and eco- friendly, easy work-up. More importantly, this nanohybrid robust catalyst did not undergo metal leaching and applied several times without any decrease in catalytic activity.

Polyhedron published new progress about Aryl halides Role: RCT (Reactant), RACT (Reactant or Reagent). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Product Details of C8H10OS.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Ghanbari Kermanshahi, Mohammad; Bahrami, Kiumars published the artcile< Fe3O4@BNPs@SiO2-SO3H as a highly chemoselective heterogeneous magnetic nanocatalyst for the oxidation of sulfides to sulfoxides or sulfones>, COA of Formula: C8H10OS, the main research area is sulfoxide preparation green chem chemoselective; sulfone preparation green chem chemoselective; sulfide oxidation iron oxide nanocatalyst.

The preparation and characterization of magnetic acidic boehmite nanoparticles as a heterogeneous catalyst, which is called Fe3O4@BNPs@SiO2-SO3H were described. This catalyst works efficiently in the selective oxidation of sulfides RSR1 [R = Ph, 4-bromobenzyl, prop-2-en-1-yl, benzothiazol-2-yl, etc.; R1 = Me, benzyl, carboxymethyl, etc.; RR1 = -(CH2-)4] and 9H-thioxanthen-9-one to sulfoxides RS(O)R1 or sulfones RS(O)2R1 in the presence of H2O2 as a green oxidant. It can easily be separated from the reaction medium by using an external magnet and it was recycled 6 times without loss of magnetic catalytic properties.

RSC Advances published new progress about Chemoselectivity. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, COA of Formula: C8H10OS.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts