Category: 143-10-2

Lin, Yi-Jyun; Wu, Yao-Peng; Thul, Mayur; Hung, Ming-Wei; Chou, Shih-Huan; Chen, Wen-Tin; Lin, Wesley; Lin, Michelle; Reddy, Daggula Mallikarjuna; Wu, Hsin-Ru; Ho, Wen-Yueh; Luo, Shun-Yuan published an article in 2020, the title of the article was Tunable aryl imidazolium recyclable ionic liquid with dual Bronsted-Lewis acid as green catalyst for Friedel-Crafts acylation and thioesterification.Synthetic Route of 143-10-2 And the article contains the following content:

Unique tunable aryl imidazolium ionic liquids I (R = H, MeO, Me, NO2) successfully catalyzed Friedel-Crafts acylation and thioesterification in sealed tubes. These reactions can form a C-C bond and a C-S bond with high atom economy. Ionic liquids exhibited high activity and catalyzed essential reactions with good to excellent yields while retaining their catalytic activities for recycling. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Synthetic Route of 143-10-2

The Article related to aryl imidazolium recyclable green catalyst friedel crafts acylation thioesterification, friedel–crafts acylation, ionic liquids, recyclable, thioesterification, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ketones and Derivatives, Including Quinones and Sulfur Analogs and other aspects.Synthetic Route of 143-10-2

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On May 27, 2020, Han, Bin; Li, Yao; Ji, Xuan; Song, Xianneng; Ding, Shuaishuai; Li, Baili; Khalid, Hira; Zhang, Yaogang; Xu, Xiaona; Tian, Lixian; Dong, Huanli; Yu, Xi; Hu, Wenping published an article.Name: 1-Decanethiol The title of the article was Systematic Modulation of Charge Transport in Molecular Devices through Facile Control of Molecule-Electrode Coupling Using a Double Self-Assembled Monolayer Nanowire Junction. And the article contained the following:

We report a novel solid-state mol. device structure based on double self-assembled monolayers (D-SAM) incorporated into the suspended nanowire architecture to form a “Au|SAM-1||SAM-2|Au” junction. Using com. available thiol mols. that are devoid of synthetic difficulty, we constructed a “Au|S-(CH2)6-ferrocene||SAM-2|Au” junction with various lengths and chem. structures of SAM-2 to tune the coupling between the ferrocene conductive MO and electrode of the junction. Combining low noise and a wide temperature range measurement, we demonstrated systematically modulated conduction depending on the length and chem. nature of SAM-2. Meanwhile, the transport mechanism transition from tunneling to hopping and the intermediate state accompanied by the current fluctuation due to the coexistence of the hopping and tunneling transport channels were observed Considering the versatility of this solid-state D-SAM in modulating the electrode-mol. interface and electroactive groups, this strategy thus provides a novel facile strategy for tailorable nanoscale charge transport studies and functional mol. devices. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Name: 1-Decanethiol

The Article related to self assembly monolayer nanowire gold thiol electron transfer, Electric Phenomena: Conduction and Conductivity, Semiconductivity, Resistance, Current Carriers, Galvanomagnetic and Acoustoelectric Effects and other aspects.Name: 1-Decanethiol

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Terashima, Kyu; Kawasaki-Takasuka, Tomoko; Yamazaki, Takashi published an article in 2021, the title of the article was Construction of fully substituted carbon centers containing a heteroatom and a CF3 group via in situ generated p-quinone methides.Formula: C10H22S And the article contains the following content:

1,6-Conjugate additions of δ-CF3-δ-substituted p-quinone methides, generated in-situ from silyl ethers I (R1 = Me, n-Pr, i-Pr, Ph, PhCC), have been achieved with a variety of heteronucleophiles under mild conditions, which led to facile and practical construction of the compounds II (X = PhCH2NH, PhNHNH, 1-pyrrolidinyl, 1-imidazolyl, F3CCH2O, PhO, i-PrS, PhS, etc.; R2 = H or TBS) with fully substituted carbon centers including a heteroatom and a CF3 group. In particular, it was revealed that some amines themselves worked for efficient cleavage of the TBS protective group, and addition of a catalytic amount of an appropriate Bronsted acid was found to sometimes improve the progress of the desired process. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Formula: C10H22S

The Article related to phenol trifluoromethyl aminoalkyl thioalkyl preparation, quinone methide generation conjugate addition amine thiol alc, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Formula: C10H22S

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Luo, Jinyun; Lin, Muze; Wu, Leifang; Cai, Zhihua; He, Lin; Du, Guangfen published an article in 2021, the title of the article was The organocatalytic synthesis of perfluorophenylsulfides via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates.Recommanded Product: 1-Decanethiol And the article contains the following content:

The organic superbase t-Bu-P4-catalyzed direct thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates was developed. Yields of perfluorophenylsulfides of up to 97% under catalysis of 5 mol% t-Bu-P4 were achieved. This method was shown to provide an efficient way to construct the perfluorophenyl-sulfur bond under mild metal-free reaction conditions. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Recommanded Product: 1-Decanethiol

The Article related to trimethyl perfluorophenyl silane thiosulfonate phosphazene catalyst thiolation green chem, perfluorophenylsulfide preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Recommanded Product: 1-Decanethiol

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On April 30, 2020, Rahman, Mahbubur Md.; Li, Guangchen; Szostak, Michal published an article.Safety of 1-Decanethiol The title of the article was Thioesterification and Selenoesterification of Amides via Selective N-C Cleavage at Room Temperature: N-C(O) to S/Se-C(O) Interconversion. And the article contained the following:

An exceedingly mild method for the direct thioesterification and selenoesterification of amides by selective N-C(O) bond cleavage in the absence of transition metals was reported. Acyclic amides underwent N-C(O) to S/Se-C(O) interconversion to give the corresponding thioesters and selenoesters in excellent yields at room temperature via a tetrahedral intermediate pathway (cf. an acyl metal). The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Safety of 1-Decanethiol

The Article related to amidobenzene thiol selective thioesterification, benzothioate preparation, selenol amidobenzene selective selenoesterification, benzoselenoate preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Safety of 1-Decanethiol

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On March 22, 2022, Elimelech, Orian; Aviv, Omer; Oded, Meirav; Peng, Xiaogang; Harries, Daniel; Banin, Uri published an article.Name: 1-Decanethiol The title of the article was Entropy of Branching Out: Linear versus Branched Alkylthiols Ligands on CdSe Nanocrystals. And the article contained the following:

Surface ligands of semiconductor nanocrystals (NCs) play key roles in determining their colloidal stability and physicochem. properties and are thus enablers also for the NCs flexible manipulation toward numerous applications. Attention is usually paid to the ligand binding group, while the impact of the ligand chain backbone structure is less discussed. Using isothermal titration calorimetry (ITC), we studied the effect of structural changes in the ligand chain on the thermodn. of the exchange reaction for oleate coated CdSe NCs, comparing linear and branched alkylthiols. The investigated alkylthiol ligands differed in their backbone length, branching position, and branching group length. Compared to linear ligands, lower exothermicity and entropy loss were observed for an exchange with branched ligands, due to steric hindrance in ligand packing, thereby justifying their previous classification as “entropic ligands”. Mean-field calculations for ligand binding demonstrate the contribution to the overall entropy originating from ligand conformational entropy, which is diminished upon binding mainly by packing of NC-bound ligands. Model calculations and the exptl. ITC data both point to an interplay between the branching position and the backbone length in determining the entropic nature of the branched ligand. Our findings suggest that the most entropic ligand should be a short, branched ligand with short branching group located toward the middle of the ligand chain. The insights provided by this work also contribute to a future smarter NC surface design, which is an essential tool for their implementation in diverse applications. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Name: 1-Decanethiol

The Article related to entropy linear branched alkylthiol ligand cdse nanocrystal, cdse nanocrystals, branched ligands, conformational entropy, isothermal titration calorimetry, ligand exchange and other aspects.Name: 1-Decanethiol

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On February 15, 2021, Yu, Tzu-Yu; Pang, Haobo; Cao, Yilin; Gallou, Fabrice; Lipshutz, Bruce H. published an article.HPLC of Formula: 143-10-2 The title of the article was Safe, Scalable, Inexpensive, and Mild Nickel-Catalyzed Migita-Like C-S Cross-Couplings in Recyclable Water. And the article contained the following:

A new approach to C-S couplings is reported that relies on nickel catalysis under mild conditions, enabled by micellar catalysis in recyclable water as the reaction medium. The protocol tolerates a wide range of heteroaromatic halides and thiols, including alkyl and heteroaryl thiols, leading to a variety of thioethers in good isolated yields. The method is scalable, results in low residual metal in the products, and is applicable to syntheses of targets in the pharmaceutical area. The procedure also features an associated low E Factor, suggesting a far more attractive entry than is otherwise currently available, especially those based on unsustainable loadings of Pd catalysts. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).HPLC of Formula: 143-10-2

The Article related to thiol aryl iodide nickel cross coupling catalyst, thioether aryl preparation, migita cross-couplings, aqueous micellar catalysis, axitinib, designer surfactants, nickel catalysis and other aspects.HPLC of Formula: 143-10-2

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On September 9, 2020, Elimelech, Orian; Aviv, Omer; Oded, Meirav; Banin, Uri published an article.Category: alcohols-buliding-blocks The title of the article was A Tale of Tails: Thermodynamics of CdSe Nanocrystal Surface Ligand Exchange. And the article contained the following:

The surface ligands of semiconductor nanocrystals (NCs) are central for determining their properties and for their flexible implementation in diverse applications. Thus far, the thermodn. characteristics of ligand exchange reactions were attained by indirect methods. Isothermal titration calorimetry is utilized to directly and independently measure both the equilibrium constant and the reaction enthalpy of a model ligand exchange reaction from oleate-capped CdSe NCs to a series of alkylthiols. Increased reaction exothermicity for longer chains, accompanied by a decrease in reaction entropy with an overall enthalpy-entropy compensation behavior is observed, explained by the length-dependent interchain interactions and the organization of the bound ligands on the NCs’ surface. An increase in the spontaneity of the reaction with decreasing NC size is also revealed, due to their enhanced surface reactivity. This work provides a fundamental understanding of the physicochem. properties of the NC surface with implications for NC surface ligand design. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Category: alcohols-buliding-blocks

The Article related to cadmium selenide nanocrystal ligand exchange thiol, cdse nanocrystals, enthalpy−entropy compensation, isothermal titration calorimetry, ligand exchange, nanocrystal surface analysis and other aspects.Category: alcohols-buliding-blocks

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On June 5, 2020, Tran, Cong Chi; Kawaguchi, Shin-ichi; Sato, Fumiya; Nomoto, Akihiro; Ogawa, Akiya published an article.Application In Synthesis of 1-Decanethiol The title of the article was Photoinduced Cyclizations of o-Diisocyanoarenes with Organic Diselenides and Thiols that Afford Chalcogenated Quinoxalines. And the article contained the following:

This study describes the syntheses of 2,3-bis(selanyl)quinoxalines via the photoinduced cyclizations of o-diisocyanoarenes with diaryl or dialkyl diselenides, in addition to providing a detailed discussion of the corresponding mechanism and revealing that the developed procedure can also be applied to prepare 2-thiolated quinoxaline derivatives from o-diisocyanoarenes and thiols. The developed technique does not need the use of additives or metal catalysts and features the advantages of a high conversion, a broad substrate scope, and mild reaction conditions, thereby rendering it a valuable addition to the quinoxaline synthesis toolbox. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Application In Synthesis of 1-Decanethiol

The Article related to diselenide diisocyanoarene photoinduced cyclization light, bisselanyl quinoxaline preparation, thiol diisocyanoarene photoinduced cyclization light, thiolated quinoxaline preparation and other aspects.Application In Synthesis of 1-Decanethiol

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On May 4, 2020, Zhou, Kejin; Johnson, Lindsay T.; Xiong, Hu; Barrios, Sergio; Minnig, Jonathan T.; Yan, Yunfeng; Abram, Bethanie; Yu, Xueliang; Siegwart, Daniel J. published an article.Related Products of 143-10-2 The title of the article was Hydrophobic Domain Structure of Linear-Dendritic Poly(ethylene glycol) Lipids Affects RNA Delivery of Lipid Nanoparticles. And the article contained the following:

In this work, a series of linear-dendritic poly(ethylene glycol) (PEG) lipids (PEG-GnCm) were synthesized through a strategy using sequential aza- and sulfa-Michael addition reactions. The effect of modulating the hydrophobic domain of linear-dendritic PEG lipids was systematically investigated for in vitro and in vivo small RNA delivery as the surface-stabilizing component of 5A2-SC8 dendrimer lipid-based nanoparticles (DLNPs). The lipid alkyl lengths (C8, C12, and C16) and dendrimer generations (G1, G2, and G3) were altered to create PEG-GnCm with different phys. properties and anchoring potential. The tail chem. structure of PEG-GnCm did not affect the formulation of 5A2-SC8 DLNPs, including the nanoparticle size, RNA encapsulation, and stability. However, the tail chem. structure did dramatically affect the RNA delivery efficacy of the formed 5A2-SC8 DLNPs with different PEG-GnCm. First-generation PEG lipids (PEG-G1C8, PEG-G1C12, and PEG-G1C16) and a second-generation PEG lipid (PEG-G2C8) formed 5A2-SC8 DLNPs that could deliver siRNAs effectively in vitro and in vivo. 5A2-SC8 DLNPs formulated with second-generation PEG lipids (PEG-G2C12 and PEG-G2C16) and all three third-generation PEG lipids (PEG-G3C8, PEG-G3C12, and PEG-G3C16) lost the ability to deliver siRNA effectively in vitro and in vivo. Overall, we determined that the hydrophobic domain chem. structure of linear-dendritic poly(ethylene glycol) lipids affected the RNA delivery of DLNPs by impacting the escape of 5A2-SC8 DLNPs from endosomes at early cell incubation times, thereby indicating how PEG lipid anchoring and chem. structure can modulate in vitro and in vivo siRNA delivery efficacies. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Related Products of 143-10-2

The Article related to hydrophobic linear dendritic polyethylene glycol lipid rna carrier nanoparticle, rna delivery, linear-dendritic pegylated lipids, linear-dendritic block copolymers, lipid nanoparticles and other aspects.Related Products of 143-10-2

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