Category: 143-10-2

On December 31, 2020, DeLeon, Michelle; Baldelli, Steve published an article.Electric Literature of 143-10-2 The title of the article was Electroreductive desorption of alkanethiols on gold and UPD copper/gold surfaces using in situ second harmonic generation. And the article contained the following:

The reductive desorption of three alkanethiols: 1-decanethiol (DT), 1-dodecanethiol (DDT), and 1-octadecanethiol (ODT) was studied. Real-time second harmonic generation (SHG) was used to monitor changes at the surface as the self-assembled monolayer was electrodesorbed from a gold and UPD Cu/Au electrode through cyclic voltammetry (CV). Before and after reductive desorption, samples are examined ex situ with sum frequency generation (SFG) spectroscopy, XPS, and contact angle (CA). These techniques confirmed the electrodesorption of short-chain alkanethiols, while long-chain alkanethiols were proven to remain near the surface of the electrode. However, a difference was observed for a DDT monolayer on the UPD Cu/Au electrode. While DDT was easily desorbed from a gold substrate, DDT on the UPD Cu/Au electrode behaved similarly to a long-chain alkanethiol on gold. Significantly, SHG was able to determine the relative alkanethiol coverage even while the desorption-features in the CV were obscured by the hydrogen evolution current. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Electric Literature of 143-10-2

The Article related to alkanethiols gold copper second harmonic generation electroreductive desorption, Optical, Electron, and Mass Spectroscopy and Other Related Properties: Optical Properties (Linear) and other aspects.Electric Literature of 143-10-2

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Chen, Pin-Ru; Lai, Kuo-Yang; Chen, Hsueh-Shih published an article in 2021, the title of the article was Roles of alcohols and existing metal ions in surface chemistry and photoluminescence of InP cores.Computed Properties of 143-10-2 And the article contains the following content:

Surface oxidation and chem. determine the optical properties of indium phosphide (InP) nanocrystals (NCs). In this study, existing metal ions from the reaction residuals and alcs. normally used in the washing process are investigated. It is found that existing metal ions and alcs. play key roles in the surface oxidation and potential surface reactions of aminophosphine-based InP NCs, which significantly affect their photoluminescence (PL), optical absorption and photo-stability. According to XPS anal., InP NCs after aging form InPOx oxide which could passivate the NC surface along with increased PL intensity and blue-shifted spectral peaks. Treating with the existing metal ions from reaction residuals and intentionally added alcs. (methanol or ethanol), InP NCs exhibit an enhanced PL quantum yield (QY) (~25 times, from 0.1% to 2.5%), unexpected red-shifted spectral peaks and improved photo-stability (~9 folds). The phenomenon is ascribed to the passivation effect of the ZnyIn1-yPOx layer formed from coupling of existing Zn2+ with the NC surface triggered by the alcs. The alcs. are found to facilitate the surface modification of amine-capped NCs and may be utilized as agents in NC surface modifications. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Computed Properties of 143-10-2

The Article related to indium phosphide nanocrystal alc surface oxidation photoluminescence optical property, Optical, Electron, and Mass Spectroscopy and Other Related Properties: Optical Properties (Linear) and other aspects.Computed Properties of 143-10-2

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

On July 2, 2020, Okuda, Yasuhiro; Imafuku, Kazuto; Tsuchida, Yoshiyuki; Seo, Tomoyo; Akashi, Haruo; Orita, Akihiro published an article.COA of Formula: C10H22S The title of the article was Process-Controlled Regiodivergent Copper-Catalyzed Azide-Alkyne Cycloadditions: Tailor-made Syntheses of 4- and 5-Bromotriazoles from Bromo(phosphoryl)ethyne. And the article contained the following:

We developed a regiodivergent syntheses of 4- and 5-bromo-substituted 1,2,3-triazoles in copper-catalyzed azide-alkyne cycloadditions (CuAACs) by taking advantage of bromo(phosphoryl)ethyne as a bromoethyne equivalent A one-shot dephosphorylative CuAAC afforded 4-bromotriazoles, which was transformed into a histone deacetylase 8 (HDAC8)-selective inhibitor, NCC-149. However, the direct CuAAC catalyzed by CuI/Cu(OAc)2 provided 5-bromo-4-phosphoryltriazoles. The consecutive nucleophilic substitution of the bromo group with thiols followed by MeOK-promoted dephosphorylation gave 5-thio-substituted triazoles. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).COA of Formula: C10H22S

The Article related to bromotriazole regiodivergent preparation copper catalyzed click cycloaddition bromophosphorylethyne, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.COA of Formula: C10H22S

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

On June 30, 2022, Son, Jong Yeog; Song, Hyunwook published an article.Application In Synthesis of 1-Decanethiol The title of the article was Investigation of intrinsic charge transport via alkyl thiol molecular electronic junctions with conductive probe atomic force microscopy. And the article contained the following:

Herein, we demonstrate characterization of intrinsic charge transport behavior of alkyl thiol mol. electronic junctions using a conductive probe at. force microscopy (CP-AFM). The stable contact between the component mols. and metallic electrodes were established by locating a conductive probe in a static position onto alkyl thiol monolayers, deposited on metal substrates. Then, we performed a combination of various measurement techniques so as to probe the intrinsic charge transport in the mol. junctions, which included temperature-, length-, and force-dependent current-voltage characterizations. Our findings can self-consistently fulfil a criterion in mol. electronics to accomplish a valid junction formation with CP-AFM. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Application In Synthesis of 1-Decanethiol

The Article related to alkyl thiol mol electronic junction intrinsic charge transport, Electric Phenomena: Dielectric and Electret Properties (Including Electric Moments, and Polarizability) and other aspects.Application In Synthesis of 1-Decanethiol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Xie, Zuoti; Baldea, Ioan; Nguyen, Quyen Van; Frisbie, C. Daniel published an article in 2021, the title of the article was Quantitative analysis of weak current rectification in molecular tunnel junctions subject to mechanical deformation reveals two different rectification mechanisms for oligophenylene thiols versus alkane thiols.HPLC of Formula: 143-10-2 And the article contains the following content:

Metal-mol.-metal junctions based on alkane thiol (CnT) and oligophenylene thiol (OPTn) self-assembled monolayers (SAMs) and Au electrodes are expected to exhibit similar elec. asymmetry, as both junctions have one chemisorbed Au-S contact and one physisorbed, van der Waals contact. Asymmetry is quantified by the current rectification ratio RR apparent in the current-voltage (I-V) characteristics. Here we show that RR < 1 for CnT and RR > 1 for OPTn junctions, in contrast to expectation, and further, that RR behaves very differently for CnT and OPTn junctions under mech. extension using the conducting probe at. force microscopy (CP-AFM) testbed. The anal. presented in this paper, which leverages results from the previously validated single level model and ab initio quantum chem. calculations, allows us to explain the puzzling exptl. findings for CnT and OPTn in terms of different current rectification mechanisms. Specifically, in CnT-based junctions the Stark effect creates the HOMO level shifting necessary for rectification, while for OPTn junctions the level shift arises from position-dependent coupling of the HOMO wavefunction with the junction electrostatic potential profile. On the basis of these mechanisms, our quantum chem. calculations allow quant. description of the impact of mech. deformation on the measured current rectification. Addnl., our anal., matched to experiment, facilitates direct estimation of the impact of intramol. electrostatic screening on the junction potential profile. Overall, our examination of current rectification in benchmark mol. tunnel junctions illuminates key phys. mechanisms at play in single step tunneling through mols., and demonstrates the quant. agreement that can be obtained between experiment and theory in these systems. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).HPLC of Formula: 143-10-2

The Article related to oligophenylene alkane thiol current rectification mol tunnel junction, Electric Phenomena: Dielectric and Electret Properties (Including Electric Moments, and Polarizability) and other aspects.HPLC of Formula: 143-10-2

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Zhang, Xiaolong; Kong, Hongtao; Zhang, Xuepeng; Jia, Hengmin; Ma, Xiuxia; Miao, Hui; Mu, Yan; Zhang, Guoqing published an article in 2021, the title of the article was Design and production of environmentally degradable quaternary ammonium salts.Computed Properties of 143-10-2 And the article contains the following content:

Quaternary ammonium compounds (QACs) are a class of cationic surfactants routinely used for the disinfection of industries, institutions and households, and have seen a sharp increase in use during the COVID-19 pandemic. However, current com. QACs consist of only stable chem. bonds such as C-N, C-C, and C-H, which makes their natural degradation rather difficult. Recent studies suggest that emerging neg. environmental impacts, such as systemic antibiotics resistance and toxicity to living organisms, are directly associated with prolonged exposure to QACs. Here we report a new class of QAC which contains relatively volatile chem. functional groups such as ester and thioether bonds. Degradation kinetics in aqueous solutions suggests that the stability of these QACs depends not only on their intrinsic hydrophobicity but also on external environmental factors such as pH, temperature and ion presence. The microbicidal effects of QACs containing carbon chains with various lengths were also tested, one of which, named “Ephemora”, is highly active against a broad spectrum of microbes including fungi, bacteria and viruses, for instance, methicillin-resistant Staphylococcus aureus (MRSA). The easy synthesis and purification of Ephemora starting from inexpensive com. available reagents, together with its excellent antimicrobial activity and ability to degrade in natural waters over time, make its large-scale com. production possible. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Computed Properties of 143-10-2

The Article related to environment degradable quaternary ammonium salt, Surface Active Agents and Detergents: Preparation, Analysis, and Properties Of Surfactants Other Than Soaps and other aspects.Computed Properties of 143-10-2

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

On May 5, 2020, Zhang, Wenguang; Xing, Lidan; Chen, Jiawei; Zhou, Hebin; Liang, Shimin; Huang, Weiyi; Li, Weishan published an article.COA of Formula: C10H22S The title of the article was Improving the cyclic stability of MoO2 anode for sodium ion batteries via film-forming electrolyte additive. And the article contained the following:

Application of film-forming electrolyte additive has been demonstrated to be an effective and economical approach to improve the performances of lithium ion batteries. However, investigations on the effect of electrolyte additives on the performances of sodium ion batteries is very limited. In this work, with vinylene carbonate (VC) as electrolyte additive, the cyclic stability of MoO2 anode for sodium ion batteries is greatly improved. After 1000 cycles at 300 mAg-1, the capacity retention of MoO2 electrode achieves 96.5% in comparison with that of 20.1% without additive. The poor long-term cyclic performance of MoO2 is mainly ascribed to the sever electrolyte reduction reaction during cycling, which results in significantly increase of electrode polarization. The VC-induced solid electrolyte interphase film effectively suppresses the decomposition of baseline electrolyte, and therefore, hinders the increase of interfacial reaction resistance and improves the interfacial stability of MoO2 electrode. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).COA of Formula: C10H22S

The Article related to molybdenum oxide anode sodium ion battery vinylene carbonate additive, vinylene carbonate additive electrolyte molybdenum oxide anode, Electrochemical, Radiational, and Thermal Energy Technology: Energy-Conversion Devices and Their Components and other aspects.COA of Formula: C10H22S

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

On September 7, 2021, Pan, Dandan; Xu, Shasha; Tian, Qingqiang; Li, Yahui published an article.Synthetic Route of 143-10-2 The title of the article was Pd-Catalyzed Intermolecular Transthiolation of Ar-OTf Using Methyl 3-(Methylthio) Propanoate as a Thiol Surrogate. And the article contained the following:

A method for the odorless synthesis of unsym. sulfides ArSR1 [Ar = naphth-1-yl, 3-NCC6H4, 4-F3CSC6H4, etc.; R1 = Me, Bn, CH2CH2Ph, etc.] via Csp2-O and Csp3-S bond activation was presented. Using Me 3-(methylthio) propanoate as a MeSH surrogate, a series of substituted aryl Me sulfides have been obtained in moderate to good yields. This catalytic protocol could also tolerated Me 3-(methylthio)propionate derivatives to afford the corresponding aryl sulfides. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Synthetic Route of 143-10-2

The Article related to aryl sulfide preparation, triflate aryl methyl methylthio propanoate intermol transthiolation palladium catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Synthetic Route of 143-10-2

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

On July 14, 2020, Diroll, Benjamin T. published an article.Reference of 1-Decanethiol The title of the article was Ligand-Dependent Tuning of Interband and Intersubband Transitions of Colloidal CdSe Nanoplatelets. And the article contained the following:

Although surface ligands of colloidal nanocrystals are known to adjust the absolute energy levels of valence and conduction bands of semiconductor nanocrystals, they typically have only minor influence on the band gap or effective masses. This changes in nanoplatelets. Ligand exchange of CdSe colloidal nanoplatelets induces large (up to 300 meV) bathochromic shifts of both interband and intersubband transitions. Here, three families of ligands-halides, thiolates, and phosphonates-are used to tune interband transitions, reflecting electron and hole confinement, across visible wavelengths and intersubband transitions, reflecting electron confinement, across the near-IR spectral window. Careful examination shows that delocalization from expansion of the nanoplatelet short axis, which was reported previously, cannot alone explain observed red shifts. Instead, comparison of intersubband, interband, and hole energy levels shows that ligand head group chem. confers specific, idiosyncratic adjustments of the contribution of conduction and valence bands to the observed bathochromic shifts. Phosphonate ligands show the largest band gap reductions but the smallest red shift of intersubband transition energies; halide-exchanged samples displayed smaller reductions in band gap but large red shifts of intersubband transitions; thiolates fall in between. A related specificity is observed in hole states, which implicates ligand-responsive valence band curvature as an addnl. contribution driving optical changes. For nanoplatelets, surface ligand chem. offers not only a tool to adjust the absolute energy level of conduction and valence bands but also an alternative route to preferential electron or hole band engineering that is normally achieved with inorganic shells. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Reference of 1-Decanethiol

The Article related to cadmium selenide ligand interband intersubband transition colloid nanoplatelet, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.Reference of 1-Decanethiol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Zhao, Yao; Rui, Jiacheng; Du, Qiang; Chen, Rizhi; Zhan, Ying; Zheng, Xintao; Wu, Xiaojin published an article in 2021, the title of the article was Catalytic base-controlled regiodivergent heteronucleophilic hydrofunctionalization of β,γ-unsaturated amides.Category: alcohols-buliding-blocks And the article contains the following content:

A general catalytic base-controlled regiodivergent nucleophilic hydrofunctionalization of both terminal and internal β,γ-unsaturated amides has been reported. The atom-economical addition of various S/P-based nucleophiles was also exclusively chemoselective. More than 60 branched or linear hetero-substituted aliphatic amides were synthesized from common starting materials under transition-metal-free conditions. Preliminary mechanistic studies are consistent with proposed divergent catalytic cycles. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Category: alcohols-buliding-blocks

The Article related to branched linear hetero aliphatic amide preparation regioselective chemoselective, unsaturated amide thol phosphine oxide hydrothiolation hydrophosphinylation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amides, Amidines, Imidic Esters, Hydrazides, and Hydrazonic Esters and other aspects.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts