Category: 143-10-2

On September 27, 2022, Soh, Eugene Jia Hao; Astier, Hippolyte P. A. G.; Daniel, Dan; Isaiah Chua, Jia Qing; Miserez, Ali; Jia, Zian; Li, Ling; O’Shea, Sean J.; Bhaskaran, Harish; Tomczak, Nikodem; Nijhuis, Christian A. published an article.Recommanded Product: 1-Decanethiol The title of the article was AFM Manipulation of EGaIn Microdroplets to Generate Controlled, On-Demand Contacts on Molecular Self-Assembled Monolayers. And the article contained the following:

Liquid metal droplets, such as eutectic gallium-indium (EGaIn), are important in many research areas, such as soft electronics, catalysis, and energy storage. Droplet contact on solid surfaces is typically achieved without control over the applied force and without optimizing the wetting properties in different environments (e.g., in air or liquid), resulting in poorly defined contact areas. In this work, we demonstrate the direct manipulation of EGaIn microdroplets using an at. force microscope (AFM) to generate repeated, on-demand making and breaking of contact on self-assembled monolayers (SAMs) of alkanethiols. The nanoscale positional control and feedback loop in an AFM allow us to control the contact force at the nanonewton level and, consequently, tune the droplet contact areas at the micrometer length scale in both air and ethanol. When submerged in ethanol, the droplets are highly nonwetting, resulting in hysteresis-free contact forces and minimal adhesion; as a result, we are able to create reproducible geometric contact areas of 0.8-4.5μm2 with the alkanethiolate SAMs in ethanol. In contrast, there is a larger hysteresis in the contact forces and larger adhesion for the same EGaIn droplet in air, which reduced the control over the contact area (4-12μm2). We demonstrate the usefulness of the technique and of the gained insights in EGaIn contact mechanics by making well-defined mol. tunneling junctions based on alkanethiolate SAMs with small geometric contact areas of between 4 and 12μm2 in air, 1 to 2 orders of magnitude smaller than previously achieved. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Recommanded Product: 1-Decanethiol

The Article related to gallium indium eutectic microdroplet afm self assembly monolayer, egain, atomic force microscopy, liquid metal, micromanipulation, molecular electronics, Surface Chemistry and Colloids: Solid-Liquid Systems and other aspects.Recommanded Product: 1-Decanethiol

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Huangfu, Xinlei; Wang, Yueqiao; Lu, Guozhang; Cao, Yinwei; Tang, Guo; Zhao, Yufen published an article in 2020, the title of the article was Direct synthesis of phosphorotrithioites and phosphorotrithioates from white phosphorus and thiols.Synthetic Route of 143-10-2 And the article contains the following content:

White phosphorus (P4) is still the major com. P-atom source for the production of organophosphorus compounds Conventionally, C-S-P bonds were constructed from environmentally questionable P(O)X directly or indirectly. From the green chem. point of view, formation of C-S-P bonds from inorganic mol. P4 in an easy-to-operate and atom-economical way is essential because it will avoid the hazardous chlorination process. Only five methods for the formation of C-S-P bonds from P4 have been developed over the past 70 years. Here, the first general and high-yielding synthesis of P(SR)3 and P(O)(SR)3 involving P4 and thiols is presented. With the use of KOH or K2CO3 as a base and DMSO-toluene as a solvent, both arythiols and alkylthiols are tolerant in this transformation. The reaction is characterized by a complete conversion of white phosphorus. This operationally simple and environmentally sound reaction shows a broad scope of substrates and good functional group tolerance. Moreover, this method can be easily adapted to large-scale preparation The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Synthetic Route of 143-10-2

The Article related to phosphorotrithioate phosphorotrithioite green chem preparation occupational safety, green chem white phosphorus thiol reactivity occupational safety, Organometallic and Organometalloidal Compounds: Phosphorus Compounds and other aspects.Synthetic Route of 143-10-2

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On December 1, 2021, Vysochinskaya, Yulia; Anisimov, Anton; Krylov, Fedor; Buzin, Mikhail; Buzin, Alexander; Peregudov, Alexander; Shchegolikhina, Olga; Muzafarov, Aziz published an article.Product Details of 143-10-2 The title of the article was Synthesis of functional derivatives of stereoregular organocyclosilsesquioxanes by thiol-ene addition. And the article contained the following:

The paper presents a facile and convenient thiol-ene addition method for the modification of cis-tetravinylcyclotetrasiloxanes containing trimethylsiloxy or dimethyl(vinyl)siloxy units at the silicon atoms. As a result, amphiphilic derivatives with hydrophobic trimethylsilyl groups on one side of the cyclosiloxane ring and with polar hydrophilic groups on the other side were obtained, along with a totally hydrophilic eight-functional derivative and a fully hydrophobic one. All the compounds were obtained in almost quant. yields and were fully characterized by 1H, 13C, 29Si NMR, IR spectroscopy, and HRMS ESI. The thermal properties of the organocyclosilsesquioxanes obtained and their behavior at the water/air interface were studied. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Product Details of 143-10-2

The Article related to stereoregular organocyclosilsesquioxanes thiol ene addition thermal thiolation, Plastics Manufacture and Processing: Preparation Of Resins and other aspects.Product Details of 143-10-2

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On January 15, 2021, Duran-Acevedo, Cristhian Manuel; Caceres-Tarazona, Juan Martin published an article.Quality Control of 1-Decanethiol The title of the article was Low-cost desorption unit coupled with a gold nanoparticles gas sensors array for the analysis of volatile organic compounds emitted from the exhaled breath (gastric cancer and control samples). And the article contained the following:

This paper describes the development and validation of a low-cost desorption unit (DU) equipment for the desorption of pre-concentrated volatile compounds in adsorption tubes ORBO-420 Tenax. The system initially heats the tubes to a temperature of 250C degrees, releasing the trapped VOCs and then drags them by compressed nitrogen flow to a gold nanoparticles gas sensor array. In each of the exptl. tests, the equipment was able to ensure the same desorption conditions in the set of measurements carried out, preventing the sample from being contaminated by external agents or from being diluted during extraction On the other hand, good repetitiveness and selectivity were observed in the sensors responses. To validate the functioning of the equipment, a set of previously acquired samples of exhaled breath from patients confirmed with gastric cancer and control patients (i.e, with gastritis and ulcer) were analyzed. The results were compared with a previous study and it was shown that the desorption unit was able to extract the volatile compounds emitted from exhaled breath and improving the classification. The samples were analyzed through data processing techniques such as: Principal Component Anal. (PCA), Discriminant Function Anal. (DFA), Probabilistic Neural Network (PNN) and Supporting Vector Machines (SVM), for the anal. and the classification of the data obtained, where 98.31% of the total variance was reached through the PCA anal. and 100% success rate was obtained in the classification by using SVM. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Quality Control of 1-Decanethiol

The Article related to gold nanoparticle gas sensor du volatile organic compound breath, Biochemical Methods: Other (Not Covered At Other Subsections) and other aspects.Quality Control of 1-Decanethiol

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Pan, Ting-Tiao; Guo, Mei-Ting; Guo, Wang; Lu, Ping; Hu, De-Yu published an article in 2021, the title of the article was A Sensitive SERS Method for Determination of Pymetrozine in Apple and Cabbage Based on an Easily Prepared Substrate.Name: 1-Decanethiol And the article contains the following content:

Residual pesticides are one of the major food safety concerns around the world. There is a demand for simple and reliable methods to monitor pesticide residues in foods. In this study, a sensitive method for determination of pymetrozine in apple and cabbage samples using surface-enhanced Raman spectroscopy (SERS) based on decanethiol functionalized silver nanoparticles was established. The proposed method performed satisfactorily with the linear detection range of 0.01-1.00 mg/L and limit of detection (LOD) of 0.01 mg/L in methanol. In addition, it was successfully used to detect pymetrozine in apple and cabbage samples, the LOD was 0.02 and 0.03 mg/L, resp., and the recoveries of spiked cabbage and apple ranged 70.40-104.00%, with relative standard deviations below 12.18% and 10.33% for intra-day and inter-day tests. Moreover, the results of the correlation test with real cabbage samples of liquid chromatog.-tandem mass spectrometry showed that they were highly correlated (slope = 0.9895, R2 = 0.9953). This study provides a sensitive approach for detection of pymetrozine in apple and cabbage, which has great potential for determination of pymetrozine residues in food products. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Name: 1-Decanethiol

The Article related to apple cabbage pymetrozine surface enhanced raman spectroscopy, food, insecticide, pymetrozine, residual detection, surface-enhanced raman spectroscopy, Food and Feed Chemistry: Fruits, Vegetables, Legumes, and Nuts and other aspects.Name: 1-Decanethiol

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Anisimov, Anton A.; Temnikov, Maxim N.; Krizhanovskiy, Ilya; Timoshina, Ekaterina I.; Milenin, Sergey A.; Peregudov, Alexander S.; Dolgushin, Fedor M.; Muzafarov, Aziz M. published an article in 2021, the title of the article was A thiol-ene click reaction with preservation of the Si-H bond: a new approach for the synthesis of functional organosilicon compounds.COA of Formula: C10H22S And the article contains the following content:

This work presents an approach for the preparation of functional hydrosilanes. The essence of the method is a thiol-ene click reaction on vinyl or allylsilanes. In this case, the Si-H bond in the substrate mol. is not affected. The reaction proceeds with radical (AIBN) or UV initiation with yields close to quant. This makes it possible to obtain aliphatic, aromatic, carboxyl and alkoxysilyl derivatives of the corresponding silanes. Crystalline tris(3-(phenylthio)propyl) silane was obtained and characterized for the first time. In the case when the thiol-ene reaction leads to the formation of a three-dimensional network, it was possible to obtain Si-H-containing materials – a transparent monolith and an aerogel with a d. of 0.26 g ml-1. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).COA of Formula: C10H22S

The Article related to crystal structure mol hydrosilane preparation, thiolene click reaction vinyl allyl silane silicon hydrogen bond, Organometallic and Organometalloidal Compounds: Silicon Compounds and other aspects.COA of Formula: C10H22S

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On January 31, 2022, Sharma, Preeti; Madan, Jaya; Pandey, Rahul; Sharma, Rajnish published an article.Related Products of 143-10-2 The title of the article was Reliability analysis of cost-efficient CH3NH3PbI3 based dopingless tunnel FET. And the article contained the following:

Electrostatically-doped TFETs (ED-TFETs) are amongst the most widely used cost-efficient steeper devices due to the use of charge-plasma technique and tunneling mechanism. However, the reliability anal. of ED-TFETs is considered an important concern for the research community. Most studies have only focused on improving the performance of ED-TFETs such as dopingless (DL)-TFET in terms of on-current (ION), subthreshold swing (SS) and threshold voltage (Vth), rather than investigating the reliability issues. In this context, the aim of our work is to investigate the reliability anal. of our previously reported methyl-ammonium lead tri-iodide materials based DL-TFET (MAPbI3-DL-TFET). The influence of interface trap charges, shallow and deep defects on the elec. and analog performance of MAPbI3-DL-TFET has been analyzed using the Silvaco ATLAS tool at room temperature Extensive results produced show that deep-level (Gaussian) defects impact the performance of the device prominently while the tail defects affect the device performance insignificantly. The present findings showed that the donor/acceptor trap charges impact the device in the subthreshold region considerably, while in the superthreshold region the impact of trap charges is marginal. In our view, these results emphasize the reliability anal. of MAPbI3-DL-TFET for the very first time. We hope that our research will be useful and valuable for DL-TFET manufacturers. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Related Products of 143-10-2

The Article related to methylammonium lead halide dopingless tunnel field effect transistor, Electric Phenomena: Capacitors, Dielectrics, Insulators, Electrets and other aspects.Related Products of 143-10-2

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Huangfu, Xinlei; Wang, Yueqiao; Lu, Guozhang; Cao, Yinwei; Tang, Guo; Zhao, Yufen published an article in 2020, the title of the article was Direct synthesis of phosphorotrithioites and phosphorotrithioates from white phosphorus and thiols.Synthetic Route of 143-10-2 And the article contains the following content:

White phosphorus (P4) is still the major com. P-atom source for the production of organophosphorus compounds Conventionally, C-S-P bonds were constructed from environmentally questionable P(O)X directly or indirectly. From the green chem. point of view, formation of C-S-P bonds from inorganic mol. P4 in an easy-to-operate and atom-economical way is essential because it will avoid the hazardous chlorination process. Only five methods for the formation of C-S-P bonds from P4 have been developed over the past 70 years. Here, the first general and high-yielding synthesis of P(SR)3 and P(O)(SR)3 involving P4 and thiols is presented. With the use of KOH or K2CO3 as a base and DMSO-toluene as a solvent, both arythiols and alkylthiols are tolerant in this transformation. The reaction is characterized by a complete conversion of white phosphorus. This operationally simple and environmentally sound reaction shows a broad scope of substrates and good functional group tolerance. Moreover, this method can be easily adapted to large-scale preparation The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Synthetic Route of 143-10-2

The Article related to phosphorotrithioate phosphorotrithioite green chem preparation occupational safety, green chem white phosphorus thiol reactivity occupational safety, Organometallic and Organometalloidal Compounds: Phosphorus Compounds and other aspects.Synthetic Route of 143-10-2

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On April 7, 2020, Joven-Sancho, Daniel; Baya, Miguel; Martin, Antonio; Orduna, Jesus; Menjon, Babil published an article.SDS of cas: 143-10-2 The title of the article was The First Organosilver(III) Fluoride, [PPh4][(CF3)3AgF]. And the article contained the following:

Organosilver(III) fluoride complexes have been assigned a key role in different fluorination processes. To the best of our knowledge, however, none of them seem to have been isolated or even detected thus far. Here we report on the successful synthesis of the trifluoromethyl derivative [PPh4][(CF3)3AgF], which has been isolated in high yield. The thermodn. stability of the Ag-F bond is shown by calculation and demonstrated by multistage mass spectrometry (MSn) under collision-induced dissociation (CID) conditions. Nevertheless, the substantial elongation found in the Ag-F bond (X-ray) is correlated with a marked nucleophilic character of the terminal F ligand. This Ag-F bond is, in fact, quite reactive: it suffers hydrolysis and is also solvolyzed by thiols. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).SDS of cas: 143-10-2

The Article related to crystal structure mol optimized organosilver fluoride preparation hydrolysis solvolysis, fluorides, high oxidation state, organosilver(iii), thiols, trifluoromethylation, Organometallic and Organometalloidal Compounds: Groups Ib, Iib – Cu, Ag, Au, Zn, Cd, Hg and other aspects.SDS of cas: 143-10-2

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Patra, Alakananda; Swamynathan, K.; Kumar, Sandeep published an article in 2021, the title of the article was Synthesis of novel regioisomeric phenanthro[a]phenazine derivatives through the SNAr strategy and their self-assembly into columnar phases.Name: 1-Decanethiol And the article contains the following content:

The cyclocondensation reaction of triphenylene-1,2-diquinone with 1,2-diamino-4-nitrobenzene results in two regioisomers, and is succeeded by a nucleophilic substitution reaction with alkyl mercaptans. The synthesis of unsym. substituted phenazines, separation and characterization of their regioisomers are rare in discotic liquid crystal chem. Here, for the first time the synthesis of two regioisomers of phenanthro[a]phenazine via a simple SNAr substitution reaction was reported. Separation of these regioisomers was achieved successfully via column chromatog. and they were well characterized by spectroscopic anal. Both the regioisomers were found to be mesomorphic. This study throws a lot of light on the SNAr strategy for functionalizing diverse π-conjugated systems for various applications. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Name: 1-Decanethiol

The Article related to phenanthrophenazine preparation columnar phase self assembly, Heterocyclic Compounds (More Than One Hetero Atom): Other 6-Membered Rings, Two Hetero Atoms and other aspects.Name: 1-Decanethiol

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