Category: 111-87-5

Saric, Ankica published the artcileSolvothermal synthesis of zinc oxide nanoparticles: A combined experimental and theoretical study, Safety of n-Octanol, the main research area is zinc oxide nanoparticle solvothermal synthesis.

Zinc oxide particles were synthesized from zinc acetylacetonate in the presence of triethanolamine (TEA) and various alc. solvent, ethanol or octanol, at 170°. The structural, optical, and morphol. characteristics of ZnO particles were monitored using X-ray powder diffraction (XRD), UV-Vis and FT-IR spectroscopies, and field emission SEM (FE-SEM). The exptl. findings were confirmed by means of DFT calculations which were obtained in nonpolar alc. 1-octanol, as a follow up to our previous study in polar ethanol. The nucleation and formation mechanism of ZnO nanoparticles is proposed considering the results obtained from a computational study of Gibbs free energies of ZnO-TEA mol. interactions (ΔG*INT) in various solvent system. The calculations revealed different binding affinities which initiated the nucleation processes of ZnO nanoparticles in the presence of alcs. of different size and polarity. The high chelating efficiency of TEA towards zinc with tetrahedral geometry is observed The results of X-ray diffraction size-strain anal. indicate the presence of size anisotropy as well as a reduction in the ZnO crystallite size with the change of solvent from ethanol to 1-octanol (<10 nm). Journal of Molecular Structure published new progress about Bond length. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Safety of n-Octanol.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Sa’adiyah, Devy Setiorini published the artcileSpatial Evolution of CO2-Contaminated Water Bubble Flows in a Vertical Pipe, COA of Formula: C8H18O, the main research area is carbon dioxide contaminated water bubble flow vertical pipe.

Experiments on CO2-water bubble flows in a vertical pipe were carried out for clean water, an aqueous NaCl solution, and an aqueous NaCl solution with 1-octanol to obtain databases of spatial evolutions of the flows with the impurities. Mass transfer correlations for bubbles in these liquids were implemented into a one-way bubble tracking method. Numerical predictions of the spatial evolution, e.g., transition from a bubbly to a slug flow, depending on the impurities agreed well with the experiments

Chemie Ingenieur Technik published new progress about Bubble flow. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, COA of Formula: C8H18O.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Andrade, Brenda published the artcileNonionic Surfactant Properties of Amphiphilic Hyperbranched Polyglycerols, Category: alcohols-buliding-blocks, the main research area is nonionic surfactant amphiphilic hyperbranched polyglycerol.

The surfactant properties of amphiphilic hyperbranched polyglycerols (HPGs) were investigated. The HPGs were prepared by ring-opening multibranching polymerization of glycidol using hydrophobic initiators of varying size and structure. The cloud points for all HPG surfactants were found to be >80 °C in deionized water with >1 wt % NaCl. The HPG surfactants with hydrophilic-lipophilic balance values between 16 and 18 were found to form stable octanol/water (o/w) emulsions within a 24 h period. Several surface properties, including critical micelle concentration (CMC), efficiency of surface tension reduction (pC20), effectiveness of surface tension reduction (γCMC), surface excess concentration at the CMC (Γmax), min. area/mol. at the interface (Amin), and the CMC/C20 ratio of the HPG surfactants were measured in deionized water at 22.6 °C. In general, increasing HPG size was marked by an increase in min. surface area per mol. (Amin) at the aqueous liquid/air interface. This increase in size also led to lower CMC and greater pC20 values of HPG surfactants prepared with Tergitol 15-S-7 initiator (HPG 5a-5d), a com. available ethylene glycol oligomer with a branched hydrophobic tail.

Langmuir published new progress about Cloud point. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Category: alcohols-buliding-blocks.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Sibirtsev, Stephan published the artcileAutomation of a Procedure for the Experimental Investigation of Liquid-Liquid Phase Separation, Formula: C8H18O, the main research area is octanol water liquid phase separation automation process.

Optimal design of a liquid-liquid settler requires exptl. investigation on phase separation behavior of the used material system under the same operating conditions as in the tech. application. Performing these experiments and evaluating the obtained data is highly time-consuming. To reduce manual effort, the procedure was largely automated. In this work, the exptl. setup, the automated procedure, and its validation results at various operating temperatures are presented. The results show the suitability of the automated procedure and the influence of temperature on phase separation behavior of the liquid-liquid system 1-octanol/water.

Chemie Ingenieur Technik published new progress about Coalescence. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Formula: C8H18O.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Sidhu, Harmanpreet published the artcileRetention-release of ciprofloxacin and azithromycin in biosolids and biosolids-amended soils, Application In Synthesis of 111-87-5, the main research area is ciprofloxacin azithromycin biosolid amendment soil; Antibiotics; Batch equilibration; Bioaccessibility; Biosolids; DGT.

Ciprofloxacin (CIP) and azithromycin (AZ) are commonly prescribed antibiotics, often found at elevated concentrations in treated sewage sludge (biosolids), and could pose human and ecol. risks when land applied. Limited retention-release data preclude assessing potential risks from the target antibiotics in biosolids and biosolids-amended soils. The present work assessed sorption-desorption of CIP and AZ in biosolids and biosolids-amended soils using the “”traditional”” batch equilibration method. The batch equilibration method also included un-amended soils for comparison. Release potentials of the biosolids-borne antibiotics were assessed via multiple desorption equilibrations in the presence of CaCl2, soils, PbCl2, or competing antibiotic (CIP vs. AZ) solutions Desorption kinetics of CIP from biosolids were also evaluated by the diffusive gradient in thin films technique (DGT), coupled with a diffusion transport-exchange model available in 2D-DIFs. Sorption of both antibiotics followed linear models with partitioning coefficient (Kd) values for CIP ranging between 40 and 334 L kg-1 in soils and 357 L kg-1 in biosolids, and values for AZ ranging between 11 and 202 L kg-1 in soils and 428 L kg-1 in biosolids. Antibiotic desorption from the biosolids was highly hysteretic (hysteresis coefficients < 0.003) and desorption of the biosolids-borne chems. was extremely small (<3%) using any of the various desorption equilibration approaches. Desorption was hysteric in soils too; where desorption percentages were 4, 5, and 26% for CIP and 6, 32, and 50% for AZ in the silt loam soil, manured sand, and sand, resp. CIP release from biosolids determined by DGT was also small (<1%), ascribed to low dissolved and labile concentrations in the solid phase and a small effective diffusion coefficient Results obtained using equilibrium and dynamic approaches suggest that the target antibiotic bioaccessibilities from biosolids and finer-textured (typical agricultural) soils would be minimal and that biosolids (not soils) control desorption of the two biosolids-borne chems. Science of the Total Environment published new progress about Antibiotics. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Application In Synthesis of 111-87-5.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Wei, Jianping published the artcileChemical composition, sensorial properties, and aroma-active compounds of ciders fermented with Hanseniaspora osmophila and Torulaspora quercuum in co- and sequential fermentations, Name: n-Octanol, the main research area is aroma compound fermented cider Hanseniaspora Torulaspora; 3-Methyl-1-butanol (PubChem CID: 31260); 3-Methylbutyl acetate (PubChem CID: 31276); Ethyl butanoate (PubChem CID: 7762); Ethyl hexanoate (PubChem CID: 31265); Ethyl octanoate (PubChem CID: 7799); Gas chromatography-olfactometry (GC-O); Glycerol (PubChem CID: 753); Hanseniaspora osmophila; Mixed fermentation; Partial least squares regression (PLSR); Phenylethyl alcohol (PubChem CID: 6054); Torulaspora quercuum; dl-malic acid (PubChem CID: 525); β-Damascenone (PubChem CID: 5366074); β-Phenethyl acetate (PubChem CID: 7654).

In this study, apple juice was fermented using Hanseniaspora osmophila X25-5 in pure culture as well as mixed culture with Torulaspora quercuum X24-4, which was inoculated simultaneously or sequentially. H. osmophila inhibited the growth of T. quercuum, while T. quercuum had little effect on the growth of H. osmophila. The simultaneous fermentation consumed relatively more sugar and resulted in the highest ethanol content. The production of organic acids varied depending on the yeast species employed and inoculation modality. Esters and alcs. were the main volatile families produced during fermentation, while Et esters and terpenes contributed most to the temperate fruity aroma. Gas chromatog.-olfactometry (GC-O) showed that 3-methyl-1-butanol, Et 2-methylbutanoate, phenylethyl alc., β-phenethyl acetate, and β-damascenone were the most potent odorants in all samples. This study suggested that simultaneous fermentation with H. osmophila and T. quercuum might represent a novel strategy for the future production of cider.

Food Chemistry published new progress about Apple juice. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Name: n-Octanol.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Shishov, Andrey published the artcileIn-syringe dispersive liquid-liquid microextraction using deep eutectic solvent as disperser: Determination of chromium (VI) in beverages, Application of n-Octanol, the main research area is syringe dispersive liquid microextraction deep eutectic solvent chromium beverage; Beverages; Chromium (VI); Deep eutectic solvent; Disperser solvent; Dispersive liquid-liquid microextraction; In-syringe flow system.

A novel approach for dispersive liquid-liquid microextraction based on the use of deep eutectic solvent as a disperser was presented for the first time. The procedure was automated based on an in-syringe flow system coupled with UV-Vis detection and demonstrated by the determination of chromium (VI) in beverages. This anal. task was used as a proof-of-concept example. The automated extraction procedure involved the aspiration of aqueous sample into a syringe pump with homogeneous mixture of extraction solvent (1-octanol) and deep eutectic solvent (tetrabutylammonium bromide – formic acid) containing color-forming reagent (1,5-diphenylcarbazide). This led to decomposition of deep eutectic solvent in aqueous phase resulting in dispersion of extraction solvent, oxidation of 1,5-diphenylcarbazide to 1,5- diphenylcarbazone in the presence of chromium (VI), and formation of colored chromium (III) complex with 1,5-diphenylcarbazone and its fast extraction In this case composition of deep eutectic solvent played a key role for analyte extraction Tetrabutylammonium bromide promoted mass transfer between aqueous phase and the extraction solvent droplets as a salting out agent, bromide ion acted as an ion-pare agent for analyte complex extraction, formic acid provided required pH value for analyte complex formation. Under the optimal conditions the limit of detection, calculated from a blank test based on 3s, was 0.2 μg L-1. The automated dispersive liquid-liquid microextraction using deep eutectic solvent as disperser can be considered as an available, efficient, rapid and environmentally friendly sample pretreatment approach.

Talanta published new progress about Apple juice. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Application of n-Octanol.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Vazquez-Tato, M. Pilar published the artcileHighly Hydrophilic and Lipophilic Derivatives of Bile Salts, Computed Properties of 111-87-5, the main research area is bile salt hydrophilicity lipophilicity heat capacity partition coefficient; bile acids and salts; demicellization thermodynamics; hydrophilic-lipophilic balance; isothermal titration calorimetry; lipophilicity; partition coefficient.

Lipophilicity of 15 derivatives of sodium cholate, defined by the octan-1-ol/water partition coefficient (log P), has been theor. determined by the Virtual log P method. These derivatives bear highly hydrophobic or highly hydrophilic substituents at the C3 position of the steroid nucleus, being linked to it through an amide bond. The difference between the maximum value of log P and the min. one is enlarged to 3.5. The partition coefficient and the critical micelle concentration (cmc) are tightly related by a double-logarithm relationship (VirtuallogP=-(1.00 ±0.09)log(cmcmM)+(2.79±0.09)), meaning that the Gibbs free energies for the transfer of a bile anion from water to either a micelle or to octan-1-ol differ by a constant The equation also means that cmc can be used as a measurement of lipophilicity. The demicellization of the aggregates formed by three derivatives of sodium cholate bearing bulky hydrophobic substituents has been studied by surface tension and isothermal titration calorimetry. Aggregation numbers, enthalpies, free energies, entropies, and heat capacities, δCP,demic, were obtained. δCP,demic, being pos., means that the interior of the aggregates is hydrophobic.

International Journal of Molecular Sciences published new progress about Aggregation. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Computed Properties of 111-87-5.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Iakovleva, Ekaterina A. published the artcileAggregates of Ethoxylated Surfactant with Added n-Octanol: Details of Corona Structure from a Molecular-Thermodynamic Model, Product Details of C8H18O, the main research area is octanol ethoxylated surfactant aggregate corona structure thermodn model.

Polar heads of many nonionic surfactants have complex chem. structure. In the micellar aggregates these heads are engaged in specific and nonspecific interactions with one another and with the hydration water. We present here a mol.-thermodn. aggregation model that takes into account explicitly the hydrogen bonding and other specific interactions within the hydrated corona of a mixed nonionic aggregate. Apart from the aggregation characteristics that are usually obtained from the classical aggregation models – critical micelle concentration (CMC), the distribution of the aggregates over the size and shape and their composition – our model helps to establish a number of likely details of structure, including the corona thickness, hydration, and the partial penetration of the micelle components in the corona region. In this work the model is applied to describe the aggregation equilibrium in aqueous solutions of nonionic surfactants of the polyoxyethylene-p-(1,1,3,3-tetramethylbutyl)phenyl ether family that is closely related to Tritons, the com. surfactants of an extensive practical use. The model gives reasonable estimates of the CMCs and predicts correctly the trends in CMC and in the aggregation numbers vs the number of oxyethylene groups in the surfactant mol. The hydration numbers and the fraction of water engaged in hydrogen bonds are calculated For the hydration of the aggregate coronae, the predicted trend is in line with that found for other ethoxylated nonionic surfactants: poly(ethylene oxide) alkyl ethers and neonols. For surfactant solutions with added n-octanol, the model suggests that the tails of the octanol mols. are deeply buried in the cores of the mixed micelles with only one methylene group penetrating the coronae. We predict co-surfactant effect of added n-octanol: the depression of the CMCs is progressively stronger for more hydrophilic surfactants with larger EO heads.

Fluid Phase Equilibria published new progress about Aggregation. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Product Details of C8H18O.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Schreiber, Andreas published the artcilePrebiotic Protocell Model Based on Dynamic Protein Membranes Accommodating Anabolic Reactions, SDS of cas: 111-87-5, the main research area is prebiotic protocell model protein membrane anabolism evolution.

The nature of the first prebiotic compartments and their possible minimal mol. composition is of great importance in the origin of life scenarios. Current protocell model membranes are proposed to be lipid-based. This paradigm has several shortcomings such as limited membrane stability of monoacyl lipid-based membranes (e.g., fatty acids), missing pathways to synthesize protocell membrane components (e.g., phospholipids) under early earth conditions, and the requirement for different classes of mols. for the formation of compartments and the catalysis of reactions. Amino acids on the other hand are known to arise and persist with remarkable abundance under early earth conditions since the fundamental Miller-Urey experiments They were also postulated early to form protocellular structures, for example, proteinoid capsules. Here, we present a protocell model constituted by membranes assembled from amphiphilic proteins based on prebiotic amino acids. Self-assembled dynamic protein membrane-based compartments (PMBCs) are impressively stable and compatible with prevalent cellular membrane constituents forming protein-only or protein-lipid hybrid membranes. They can embed processes essential for extant living cells, such as enclosure of mols., membrane fusion, phase separation, and complex biosynthetic elements from modern cells demonstrating “”upward”” compatibility. Our findings suggest that prebiotic PMBCs represent a new type of protocell as a possible ancestor of current lipid-based cells. The presented prebiotic PMBC model can be used to design artificial cells, important for the study of structural, catalytic, and evolutionary pathways related to the emergence of life.

Langmuir published new progress about Amphiphiles. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, SDS of cas: 111-87-5.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts