Category: 106-21-8

CO₂ + 3,7-dimethyl-1-octanol + 1-decanol: High pressure experimental phase equilibria data and thermodynamic modelling was written by van Niekerk Fourie, Frederick Christiaan;Schwarz, Cara Elsbeth;Knoetze, Johannes Hendrik. And the article was included in Journal of Supercritical Fluids in 2018.Quality Control of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

New VLE data are presented for CO₂ + 3,7-dimethyl-1-octanol (37DM1O) + 1-decanol (C₁₀OH) at 35, 55 and 75°C and pressures between 68 and 237 bar. Phase compositions were analyzed using a static analytic app with dual sampling and online chromatog. The mixture displays virtually no enhanced solubility, liq curves remain convex throughout, and coexisting detached two-phase regions were not detected. CO₂ can fractionate all measured 37DM1O:C₁₀OH ratios though with limited efficacy, as highlighted by relative solubilities ranging from 1.1 to 1.5. RK-ASPEN, SR-POLAR, PR-BM and PC-SAFT correlations failed at 35°C, the optimum fractionation temperature At 55 and 75°C, RK-ASPEN and SR-POLAR produced the smallest percentage av abs deviations in equil pressure of 4.0%, and RK-ASPEN was marginally superior at correlating vapor and liq phase curves. At 35°C and 187.5 bar, the 25:75 37DM1O:C₁₀OH mixt passed through a d inversion and interesting images thereof are presented. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Quality Control of 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Quality Control of 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Quantitative Structure-Activity Relationship Modeling and Docking of Monoterpenes with Insecticidal Activity Against Reticulitermes chinensis Snyder and Drosophila melanogaster was written by Soares Rodrigues, Gabriela Cristina;dos Santos Maia, Mayara;Muratov, Eugene N.;Scotti, Luciana;Scotti, Marcus Tullius. And the article was included in Journal of Agricultural and Food Chemistry in 2020.Reference of 106-21-8 The following contents are mentioned in the article:

The goal of this study was to perform in silico identification of bioinsecticidal potential of 42 monoterpenes against Drosophila melanogaster and Reticulitermes chinensis Snyder. Quant. structure-activity relationship (QSAR) modeling was performed for both organisms, while docking and mol. dynamics were used only for Drosophila melanogaster. Neryl acetate has the lowest interaction energy (-87 kcal/mol) against active site of acetylcholinesterase, which is comparable to the ones of methiocarb and pirimicarb (-90 kcal/mol) and reported PDB binder 9-(3-iodobenzylamino)-1,2,3,4-tetrahydroacridine (-112.67 kcal/mol). Interaction stability was verified by mol. dynamics simulations and showed that the stability of ACHE active site complexes with three selected terpenes is comparable to the one of the pirimicarb and methiocarb. Overall, our results suggest that pulegone, citronellal, carvacrol, linalyl acetate, neryl acetate, citronellyl acetate, and geranyl acetate may be considered as a potential pesticide candidates. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Reference of 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Reference of 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

New chemical agents based on adamantane-monoterpene conjugates against orthopoxvirus infections was written by Suslov, Evgenii V.;Mozhaytsev, Evgenii S.;Korchagina, Dina V.;Bormotov, Nikolay I.;Yarovaya, Olga I.;Volcho, Konstantin P.;Serova, Olga A.;Agafonov, Alexander P.;Maksyutov, Rinat A.;Shishkina, Larisa N.;Salakhutdinov, Nariman F.. And the article was included in RSC Medicinal Chemistry in 2020.Quality Control of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

Currently, the spectrum of agents against orthopoxviruses, in particular smallpox, is very narrow. Despite the fact that smallpox is well controlled, there is, for many reasons, a real threat of epidemics associated with this or a similar virus. In order to search for new low mol. weight orthopoxvirus inhibitors, a series of amides combining adamantane and monoterpene moieties were synthesized using 1- and 2-adamantanecarboxylic acids as well as myrtenic, citronellic and camphorsulfonic acids as acid components. The produced compounds exhibited high activity against the vaccinia virus (an enveloped virus belonging to the poxvirus family), which was combined with low cytotoxicity. Some compounds had a selectivity index higher than that of the reference drug cidofovir; the highest SI = 1123 was exhibited by 1-adamantanecarboxylic acid amide containing the (-)-10-amino-2-pinene moiety. The produced compounds demonstrated inhibitory activity against other orthopoxviruses: cowpox virus (SI = 30-406) and ectromelia virus (mousepox virus, SI = 39-707). This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Quality Control of 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Quality Control of 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

CO₂ + n-dodecane + 3,7-dimethyl-1-octanol: High pressure experimental phase equilibria data and thermodynamic modelling was written by van Niekerk Fourie, Frederick Christiaan;Schwarz, Cara Elsbeth;Knoetze, Johannes Hendrik. And the article was included in Journal of Supercritical Fluids in 2017.Product Details of 106-21-8 The following contents are mentioned in the article:

New high pressure VLE data for the ternary mixture CO₂ + n-dodecane (nC₁₂) + 3,7-dimethyl-1-octanol (37DM1O) are presented. A static apparatus with online anal. was used to measure phase compositions at 35, 55 and 75°C, and pressures between 68 and 157 bar. In the high-nC₁₂ region the mixture displayed enhanced solubility, presenting as a pinched two phase band and s-shaped liquid phase curves. Relative solubility, an indicator of fractionation sharpness, increased with 37DM1O content and the 75:25 nC₁₂:37DM1O mixture cannot be separated using CO₂. RK-ASPEN, SR-POLAR, PR-BM and PC-SAFT models were evaluated for their ability to correlate these data. RK-ASPEN and PC-SAFT models provided the best and worst correlation of equilibrium pressures with resp. percentage average absolute deviations of 3.1% and 8.5%. RK-ASPEN model was impressive in its ability to capture the co-solubility pinch seen for the 75:25 nC₁₂:37DM1O mixture and the resultant s-shaped liquid phase complexity. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Product Details of 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Product Details of 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Effects of terpene alcohol dopant on the morphology and electro-optical properties of polymer-dispersed liquid-crystal composite films was written by Huang, Junyi;Hu, Wei;Yu, Meina;Ren, Yunxiao;Zhang, Lanying;Yang, Huai. And the article was included in Polymers for Advanced Technologies in 2021.Application of 106-21-8 The following contents are mentioned in the article:

Terpenes are a large class of hydrocarbon compounds derived from isoprene, which can be produced by plants or emitted by insects. Terpene alcs. contain double bonds that may affect the addition polymerization, and hydroxyl groups that can promote the network crosslinking d. during the formation of polymer-dispersed liquid-crystal (PDLC) composite films. In this work, effects of different terpene alc. dopant on the morphol. and electro-optical properties of PDLC films are systematically investigated. It is found that the appropriate dopant amount of geraniol (GOL) has the superior effect to improve the electro-optical performance. The optimum addition amount is at 3 wt%, where the transmittance vs. voltage curve gets steeper, the driving voltage of PDLC film reduces from 74 to 32 V and meanwhile the contrast ratio maintains at a relatively high level (123). Thus, this work not only broadens the application scope of the natural spices but also provides a new strategy to reduce the driving voltage of PDLC films for practical applications. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application of 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Application of 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Bioinspired Enzymatic Synthesis of Terpenoid-Based (Meth)acrylic Monomers: A Solvent-, Metal-, Amino-, and Halogen-Free Approach was written by Castagnet, Thibault;Aguirre, Garbine;Asua, Jose M.;Billon, Laurent. And the article was included in ACS Sustainable Chemistry & Engineering in 2020.Formula: C10H22O The following contents are mentioned in the article:

In an attempt to pave the way toward the substitution of petroleum-based monomers for monomers from sustainable and renewable resources, this work investigates the synthesis of a portfolio of new (meth)acrylic monomers using terpenoids as raw materials that can be conveniently extracted from wood waste and citrus fruits. The synthetic process is based on the enzymic catalysis of the esterification of terpenoids and is solvent-, metal-, amino-, and halogen-free, overcoming the limitations of the common esterification techniques. The effect of employing microwaves in combination with the enzyme and the effect of the acyl donor choice [(meth)acrylic acids vs (meth)acrylic anhydrides] were studied. The process yielded complete conversion and then high-purity monomers with a variety of structures that would allow them to substitute many of the most commonly used petrochem. (meth)acrylic monomers. Paving the way toward the substitution of petroleum-based (meth)acrylics monomers from renewable resources and sustainable chem. combining microwaves and enzymic catalysis. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Formula: C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Formula: C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Effect of the fluorination degree of partially fluorinated octyl-phosphocholine surfactants on their interfacial properties and interactions with purple membrane as a membrane protein model was written by Baba, Teruhiko;Takagi, Toshiyuki;Sumaru, Kimio;Kanamori, Toshiyuki. And the article was included in Chemistry and Physics of Lipids in 2020.Category: alcohols-buliding-blocks The following contents are mentioned in the article:

Interfacial properties and membrane protein solubilization activity of a series of partially fluorinated octyl-phosphocholine (PC) surfactants were investigated from the viewpoint of the fluorination degree of the hydrophobic chain. The critical micelle concentration (CMC), surface tension lowering activity, mol. occupied area at the CMC and free energy changes of micellization as well as adsorption to the air-water interface for each PC surfactant were estimated from surface tension measurements at 25 °C. The PCs with higher degree of fluorination exhibited low CMC and high surface activity, while the single trifluoromethyl group at the end of the chain appeared to enhance the hydrophilicity of the surfactant mol. Under conditions where conventional short-chain surfactants, n-octyl-β-D-glucoside, Triton X-100 and dioctanoylphosphatidylcholine significantly solubilize purple membranes (PM), none of the fluorinated-PCs solubilized PM. This suggests that fluorinated-PCs are low-invasive enough to maintain the structure of lipids/protein assemblies like PM. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Category: alcohols-buliding-blocks).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Chemical composition, antimicrobial, and antioxidant activities of medicinal plants nutsedge and fenugreek was written by Ceylan, ule;Camadan, Yasemin;Saral, Ozlem;Batur, Ozge Ozuleen. And the article was included in BioResources in 2022.Electric Literature of C10H22O The following contents are mentioned in the article:

Purple nutsedge roots (Cyperus rotundus L.) and fenugreek seeds (Trigonella foenum-graecum L.) have been traditionally used as food and to treat common ailments. After extraction by solid-phase microextraction (SPME), the chem. structure of the revealed volatile fractions was researched with gas chromatog. with mass spectrometry (GC-MS). The determined substances of the C. rotundus were pentadecanolide (72.0%), palmitic acid (8.2%), 16-hydroxy-6-hexadecenoic acid omega lactone (4.4%), and (Z)-anethol (3.9%). Most of the identified compounds of the T. foenum-graecum were pentadecanolide (61.3%) and (Z)-anethol (16.5%). The C. rotundus showed good antifungal activity against the yeast strands of Candida albicans and Candida krusei. Min. inhibitory concentration (MIC) numbers were 250 and 125 μg/mL, resp. However, the T. foenum-graecum seeds did not show any effect against the test microorganisms. The C. rotundus roots in particular exhibited good 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activity with an IC₅₀ number of 0.91 mg/mL. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Electric Literature of C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Electric Literature of C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Anti-biofilm activities of essential oils rich in carvacrol and thymol against Salmonella Enteritidis was written by Cabarkapa, Ivana;Colovic, Radmilo;Djuragic, Olivera;Popovic, Sanja;Kokic, Bojana;Milanov, Dubravka;Pezo, Lato. And the article was included in Biofouling in 2019.Application of 106-21-8 The following contents are mentioned in the article:

The aim of the present study was to determine the bioactive compounds in four essential oils (EO’s) from Origanum heracleoticum, Origanum vulgare, Thymus vulgaris and Thymus serpyllum and to assess their antimicrobial and anti-biofilm activity against Salmonella Enteritidis. Strains were previously characterized depending on the expression of the extracellular matrix components cellulose and curli fimbriae as rdar (red, dry and rough) and bdar morphotype (brown, dry and rough). This study revealed that the EO’s and EOC’s (carvacrol and thymol) investigated showed inhibition of biofilm formation at sub-min. inhibitory concentration Comparing the efficacy of EO’s and EOC’s in the inhibition of biofilm formation between the strains with different morphotype (rdar and bdar) did not show a statistically significant difference. Results related to the effectiveness of EO’s and EOC’s (the essential oil components, carvacrol and thymol) on eradication of preformed 48 h old biofilms indicated that biofilm reduction occurred in a dose-dependent manner over time. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application of 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Application of 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Catalytic Access to Functionalized Allylic gem-Difluorides via Fluorinative Meyer-Schuster-Like Rearrangement was written by Liao, Lihao;An, Rui;Li, Huimin;Xu, Yang;Wu, Jin-Ji;Zhao, Xiaodan. And the article was included in Angewandte Chemie, International Edition in 2020.Quality Control of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

An unprecedented approach for efficient synthesis of functionalized allylic gem-difluorides via catalytic fluorinative Meyer-Schuster-like rearrangement is disclosed. This transformation proceeded with readily accessible propargylic fluorides, and low-cost B-F reagents and electrophilic reagents by sulfide catalysis [e.g., I → II (88%) in presence of PhSPh as Lewis basic catalyst, tetrafluoroboric acid di-Et ether complex and NIS]. A series of iodinated, brominated, and trifluoromethylthiolated allylic gem-difluorides that were difficult to access by other methods were facilely produced with a wide range of functional groups. Importantly, the obtained iodinated products could be incorporated into different drugs and natural products, and could be expediently converted into many other valuable gem-difluoroalkyl mols. as well. Mechanistic studies revealed that this reaction went through a regioselective fluorination of alkynes followed by a formal 1,3-fluorine migration under the assistance of the B-F reagents to give the desired products. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Quality Control of 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Quality Control of 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts