Category: 105-13-5

Product Details of 105-13-5. Authors Huang, M; Li, YW; Lan, XB; Liu, JH; Zhao, CY; Liu, Y; Ke, ZF in ROYAL SOC CHEMISTRY published article about in [Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Affiliated Hosp 1, Clin Pharm, Guangzhou 510006, Peoples R China; [Huang, Ming; Li, Yinwu; Lan, Xiao-Bing; Liu, Jiahao; Zhao, Cunyuan; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Chem, PCFM Lab, Sch Mat Sci & Engn, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Metal hydride complexes are key intermediates for N-alkylation of amines with alcohols by the borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols and the hydrogenation of imines. Herein we report ruthenium(s) complexes with hetero-bidentate N-heterocyclic carbene (NHC)-phosphine ligands, which realize smart pathway selection in the N-alkylated reaction via reactivity tuning of IRu-H) species by hetero-bidentate ligands. In particular, complex 6cb with a phenyl wingtip group and BArr counter anion, is shown to be one of the most efficient pre-catalysts for this transformation (temperature is as low as 70 degrees C, neat conditions and catalyst loading is as low as 0.25 mol%). A large variety of (hetero)aromatic amines and primary alcohols were efficiently converted into mono-N-alkylated amines in good to excellent isolated yields. Notably, aliphatic amines, challenging methanol and diamines could also be transformed into the desired products. Detailed control experiments and density functional theory (DFT) calculations provide insights to understand the mechanism and the smart pathway selection via [Ru-H] species in this process.

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Authors Pandey, VK; Tiwari, CS; Rit, A in AMER CHEMICAL SOC published article about in [Pandey, Vipin K.; Tiwari, Chandra Shekhar; Rit, Arnab] Indian Inst Technol Madras, Dept Chem, Chennai 600036, Tamil Nadu, India in 2021, Cited 56. Recommanded Product: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

AgSbF6 was developed as an effective catalyst for the hydroboration of various unsaturated functionalities (nitriles, alkenes, and aldehydes). This atom-economic chemoselective protocol works effectively under low catalyst loading, base- and solvent-free moderate conditions. Importantly, this process shows excellent functional group tolerance and compatibility with structurally and electronically diverse substrates (>50 examples). Mechanistic investigations revealed that the reaction proceeds via a radical pathway. Further, the obtained N,N-diborylamines were showcased to be useful precursors for amide synthesis.

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I found the field of Chemistry very interesting. Saw the article Nickel-Copper bimetallic mesoporous nanoparticles: As an efficient heterogeneous catalyst for N-alkylation of amines with alcohols published in 2021. Recommanded Product: 105-13-5, Reprint Addresses Kassaee, MZ (corresponding author), Tarbiat Modares Univ, Dept Chem, POB 14155-175, Tehran, Iran.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A bimetallic catalyst (Ni/Cu-MCM-41) is prepared via co-condensation method. The latter is characterized by Fourier transform infrared (FT-IR), X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), diffuse reflectance spectroscopy (DRS), and nitrogen adsorption-desorption analysis. Catalytic performance of Ni/Cu-MCM-41 is probed in N-alkylation of amines with alcohols through a hydrogen autotransfer process. Noteworthy, this catalytic system appears very efficient for synthesis of a range of secondary and tertiary amines in good to excellent isolated yields. Moreover, the catalyst is successfully recovered and reused four times without notable decrease in its activity.

Recommanded Product: 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Nasresfahani, Z; Kassaee, MZ or send Email.

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Safety of (4-Methoxyphenyl)methanol. Authors Feng, XY; Pi, YH; Song, Y; Xu, ZW; Li, Z; Lin, WB in AMER CHEMICAL SOC published article about in [Feng, Xuanyu; Pi, Yunhong; Song, Yang; Xu, Ziwan; Lin, Wenbin] Univ Chicago, Dept Chem, Chicago, IL 60637 USA; [Pi, Yunhong; Li, Zhong] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

We report here the construction of two metal-organic frameworks (MOFs), Zr-6-Cu/Fe-1 and Zr-6–Cu/Fe-2, by integrating earth-abundant cuprous photosensitizers (Cu-PSs) and Fe catalysts for photocatalytic aerobic oxidation. Site isolation and pore confinement stabilize both Cu-PSs and Fe catalysts, while the proximity between active centers facilitates electron and mass transfer. Upon visible light irradiation and using O-2 as the only oxidant, Zr-6-Cu/Fe-1 and Zr-6-Cu/ Fe-2 efficiently oxidize alcohols and benzylic compounds to afford corresponding carbonyl products with broad substrate scopes, high turnover numbers of up to 500 with a 9.4-fold enhancement over homogeneous analogues, and excellent recyclability in four consecutive runs. Control experiments, spectroscopic evidence, and computational studies revealed the photooxidation mechanism: oxidative quenching of [Cu-PS]* by O-2 affords [Cu-II-PS], which efficiently oxidizes Fe-III-OH to generate a hydroxyl radical for substrate oxidation. This work highlights the potential of MOFs in promoting earth-abundant metal-based photocatalysis.

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Authors Sung, K; Lee, MH; Cheong, YJ; Kim, YK; Yu, S; Jang, HY in WILEY-V C H VERLAG GMBH published article about in [Sung, Kihyuk; Lee, Mi-hyun; Cheong, Yeon-Joo; Kim, Yu Kwon; Yu, Sungju; Jang, Hye-Young] Ajou Univ, Dept Energy Syst Res, Suwon 16499, South Korea in 2021, Cited 56. Quality Control of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Multi N-heterocyclic carbene(NHC)-modified iridium catalysts were employed in the beta-alkylation of alcohols; dimerization of primary alcohols (Guerbet reaction), cross-coupling of secondary and primary alcohols, and intramolecular cyclization of alcohols. Mechanistic studies of Guerbet reaction, including kinetic experiments, mass analysis, and density functional theory (DFT) calculation, were employed to explain the fast reaction promoted by bimetallic catalysts, and the dramatic reactivity increase of monometallic catalysts at the late stage of the reaction.

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An article Synthesis, characterization, crystal structures, Hirshfeld surface analysis, DFT computational studies and catalytic activity of novel oxovanadium and dioxomolybdenum complexes with ONO tridentate Schiff base ligand WOS:000652846800002 published article about AEROBIC OXIDATION; BENZYLIC ALCOHOLS; C-H; COPPER; ALDEHYDES; MILD in [Kargar, Hadi] Ardakan Univ, Dept Chem Engn, Fac Engn, POB 184, Ardakan, Iran; [Bazrafshan, Maryam; Fallah-Mehrjardi, Mehdi; Behjatmanesh-Ardakani, Reza] Payame Noor Univ, Dept Chem, Tehran 193953697, Iran; [Rudbari, Hadi Amiri] Univ Isfahan, Dept Chem, Esfahan 8174673441, Iran; [Munawar, Khurram Shahzad] Univ Sargodha, Dept Chem, Punjab, Pakistan; [Munawar, Khurram Shahzad] Univ Mianwali, Dept Chem, Mianwali, Pakistan; [Ashfaq, Muhammad; Tahir, Muhammad Nawaz] Univ Sargodha, Dept Phys, Punjab, Pakistan in 2021, Cited 56. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. HPLC of Formula: C8H10O2

For the first time, two new oxovanadium and dioxomolybdenum Schiff base complexes, VOL(OMe) and MoO2L, were synthesized through the reaction of a ONO tridentate Schiff base ligand (H2L) derived from the condensation of 5-bromosalicylaldehyde and nicotinic hydrazide with oxo and dioxo acetylacetonate salts of vanadium and molybdenum, [VO(acac)(2) and MoO2(acac)2], respectively. The synthesized ligand and complexes were characterized by various spectroscopic techniques like FT-IR, H-1 NMR, C-13 NMR, elemental analysis (CHN) and the most authentic single crystal X-ray diffraction analysis (SC-XRD). The geometry around the central metal ion in MoO2L was distorted octahedral as revealed by the data collected from diffraction studies. Non-covalent interactions that are responsible for crystal packing are explored by Hirshfeld surface analysis. Theoretical calculations of the synthesized compounds, carried out by DFT at B3LYP/Def2-TZVP level of theory, indicated that the calculated results are in agreement with the experimental findings. Moreover, the catalytic activities of both complexes were investigated for the selective oxidation of benzylic alcohols using urea hydrogen peroxide (UHP) in acetonitrile. (C) 2021 Elsevier Ltd. All rights reserved.

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An article Simple preparation of nitrogen-doped TiO2 and its performance in selective oxidation of benzyl alcohol and benzylamine under visible light WOS:000605553500002 published article about PHOTOCATALYTIC ACTIVITY; AEROBIC OXIDATION; TITANIUM-DIOXIDE; FACILE SYNTHESIS; ANATASE TIO2; BENZALDEHYDE; ENHANCEMENT; HETEROSTRUCTURE; NANOCOMPOSITES; NANOPARTICLES in [Japa, Mattawan; Phasayavan, Witchaya] Chiang Mai Univ, Grad Sch, Chiang Mai 50200, Thailand; [Japa, Mattawan; Phasayavan, Witchaya; Inceesungvorn, Burapat] Chiang Mai Univ, Fac Sci, Ctr Excellence Innovat Chem PERCH CIC, Ctr Excellence Mat Sci & Technol,Dept Chem, Chiang Mai 50200, Thailand; [Japa, Mattawan; Nattestad, Andrew; Chen, Jun] Univ Wollongong, ARC Ctr Excellent Electromat Sci, Intelligent Polymer Res Inst, Australian Inst Innovat Mat, Wollongong, NSW 2522, Australia; [Tantraviwat, Doldet] Chiang Mai Univ, Fac Engn, Dept Elect Engn, Chiang Mai 50200, Thailand in 2021, Cited 52. Application In Synthesis of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

N-doped TiO2, denoted as T_400, was prepared simply by the facile thermal hydrolysis of TiOSO4 using NH4OH as both a precipitating agent and a nitrogen source. Compared to TiO2 without nitrogen doping, T_400 provides superior photocatalytic activity toward the selective oxidation of benzyl alcohol and benzylamine under visible light irradiation, with > 85 % conversion and > 95 % selectivity to benzaldehyde and N-benzylidenebenzylamine products, respectively. The increased photoactivity of T_400 is ascribed to enhanced visible-light absorption and efficient photogenerated charge transfer and separation as supported by UV-vis DRS, photoelectrochemical and VB-XPS results. The catalyst can tolerate the presence of substituent groups in benzyl alcohol and benzelamine molecules as > 80 % conversion and > 95 % selectivity are still achieved, which expands the scope of substrates and catalyst utilization. Band energy level of N-doped TiO2 compared to that of undoped TiO2 is determined using Mott-Schottky and UV-vis DRS measurements. Possible mechanisms for the formation of benzaldehyde and N-benzylidenebenzylamine over N-doped TiO2 are proposed. This work presents a simple synthesis of N-doped TiO2, using a low-cost and easily handled inorganic titanium salt instead of air/moisture-sensitive alkoxide precursors and reveals its potential application toward photocatalytic synthesis of organic fine chemicals under visible light.

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Product Details of 105-13-5. Authors Yao, HY; Wang, YS; Razi, MK in ROYAL SOC CHEMISTRY published article about in [Yao, Hongyan] Hebi Polytech, Deans Off, Hebi 458030, Peoples R China; [Wang, Yongsheng] Henan Polytech Univ, Sch Phys Sci Educ, Jiaozuo 454003, Henan, Peoples R China; [Razi, Maryam Kargar] Islamic Azad Univ, North Branch Tehran, Fac Chem, Tehran, Iran in 2021, Cited 82. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

In this study, a magnetic asymmetric Salamo-based Zn complex (H2L = salen type di-Schiff bases)-supported on the surface of modified Fe3O4 (Fe3O4@H2L-Zn) as a new catalyst was designed and characterized via numerous analytical techniques such as FT-IR spectroscopy, XRD, EDS, ICP-AES, SEM, TEM, TGA and VSM. An efficient and sustainable synthetic protocol has been presented for the synthesis of silyl ether substructures via the silyl protection of alcohols under mild conditions. The synthetic protocol involves a two-component solvent-free reaction between various hydroxyl-bearing substrates and hexamethyldisilazane (HMDS) as an inexpensive silylating agent using Fe3O4@H2L-Zn MNPs as a magnetically separable, recyclable and reusable heterogeneous catalyst. Fe3O4@H2L-Zn MNPs were also applied for the removal of silyl protecting groups from hydroxyl functions using water in CH2Cl2 under green conditions. The catalyst demonstrated good to excellent catalytic yield efficiency for both the reactions compared to the commercial metal-based catalysts under green conditions for a wide range of substrates.

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Recently I am researching about NITROGEN-HETEROCYCLES; ELECTRONIC-STRUCTURES; COMPLEXES; OXIDATION; HYDROGENATION; REACTIVITY, Saw an article supported by the DST, Govt. of IndiaDepartment of Science & Technology (India) [CRG/2019/001737]; Department of Science & Technology and Biotechnology, Govt. of West Bengal [ST/P/ST/15G-13/2019]; UGCUniversity Grants Commission, India; CSIRCouncil of Scientific & Industrial Research (CSIR) – India; DSTDepartment of Science & Technology (India); IIESTS. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Das, S; Mondal, R; Chakraborty, G; Guin, AK; Das, A; Paul, ND. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. SDS of cas: 105-13-5

Herein we report an exclusively ligand-centered redox controlled approach for the dehydrogenation of a variety of N-heterocycles using a Zn(II)-stabilized azo-anion radical complex as the catalyst. A simple, easy-to-prepare, and bench-stable Zn(II)-complex (1b) featuring the tridentate arylazo pincer, 2-((4-chlorophenyl)diazenyl)-1,10-phenanthroline, in the presence of zinc-dust, undergoes reduction to form the azo-anion radical species [1b]which efficiently dehydrogenates various saturated N-heterocycles such as 1,2,3,4-tetrahydro-2-methylquinoline, 1,2,3,4-tetrahydro-isoquinoline, indoline, 2-phenyl-2,3-dihydro-1H-benzoimidazole, 2,3-dihydro-2-phenylquinazolin-4(1H)-one, and 1,2,3,4-tetrahydro-2-phenylquinazolines, among others, under air. The catalyst has further been found to be compatible with the cascade synthesis of these N-heterocycles via dehydrogenative coupling of alcohols with other suitable coupling partners under air. Mechanistic investigation reveals that the dehydrogenation reactions proceed via a one-electron hydrogen atom transfer (HAT) pathway where the zinc-stabilized azo-anion radical ligand abstracts the hydrogen atom from the organic substrate(s), and the whole catalytic cycle proceeds via the exclusive involvement of the ligand-centered redox events where the zinc acts only as the template.

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HPLC of Formula: C8H10O2. In 2021 TETRAHEDRON published article about ASYMMETRIC TRANSFER HYDROGENATION; ENANTIOSELECTIVE TRANSFER HYDROGENATION; MEDIATED 2+2+1 CYCLOADDITIONS; TRIMETHYLAMINE N-OXIDE; METAL-DIENE COMPLEXES; REDUCTIVE AMINATION; SELECTIVE HYDROGENATION; HIGHLY EFFICIENT; ORGANIC-SYNTHESIS; CARBON-MONOXIDE in [Coufourier, Sebastien; Ndiaye, Daouda; Gaillard, Quentin Gaignard; Bettoni, Leo; Joly, Nicolas; Mbaye, Mbaye Diagne; Gaillard, Sylvain; Renaud, Jean-Luc] Normandie Univ, CNRS, UNICAEN, LCMT,ENSICAEN, 6 Blvd Marechal Juin, F-14050 Caen, France; [Ndiaye, Daouda; Mbaye, Mbaye Diagne] Univ Assane Seck Ziguinchor, BP 523, Ziguinchor, Senegal; [Joly, Nicolas; Poater, Albert] Univ Girona, Inst Quim Computac & Catalisi IQCC, Dept Quim, C M Aurelia Capmany 69, Girona 17003, Catalonia, Spain in 2021, Cited 109. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A Diaminocyclopentadienone iron tricarbonyl complex has been applied in chemoselective hydrogen transfer reductions. This bifunctional iron complex demonstrated a broad applicability in mild conditions in various reactions, such as reduction of aldehydes over ketones, reductive alkylation of various functionalized amines with functionalized aldehydes and reduction of alpha,beta-unsaturated ketones into the corresponding saturated ketones. A broad range of functionalized substrates has been isolated in excellent yields with this practical procedure. (C) 2021 Elsevier Ltd. All rights reserved.

HPLC of Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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