Category: 105-13-5

Authors Xia, YY; Lv, QY; Yuan, H; Wang, JY in SPRINGER INTERNATIONAL PUBLISHING AG published article about in [Xia, Yu-Yan; Lv, Qing-Yang; Yuan, Hua; Wang, Jia-Yi] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430073, Peoples R China in 2021, Cited 46. Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

An efficient method for catalyzing the ammoxidation of aromatic alcohols to aromatic nitriles was developed, in which a new heterogeneous catalyst based on transition metal elements was employed, the new catalyst was named Co-[Bmim]Br/C-700 and then characterized by X-ray photo-electronic spectroscopy, transmission electron microscope and X-ray diffraction. The reaction was carried out by two consecutive dehydrogenations under the catalysis of Co-[Bmim]Br/C-700, which catalytically oxidized the alcohol to the aldehyde, and then the aldehyde was subjected to ammoxidation to the nitrile. The catalyst system was suitable for a wide range of substrates and nitriles obtained in high yields, especially, the conversion rate of benzyl alcohol, 4-methoxybenzyl alcohol, 4-chlorobenzyl alcohol and 4-nitrobenzyl alcohol reached 100%. The substitution of ammonia and oxygen for toxic cyanide to participate in the reaction accords with the theory of green chemistry.

Welcome to talk about 105-13-5, If you have any questions, you can contact Xia, YY; Lv, QY; Yuan, H; Wang, JY or send Email.. Formula: C8H10O2

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In 2021 CHEMSUSCHEM published article about DEPENDENT AMINE OXIDASES; AEROBIC OXIDATION; CATALYTIC MECHANISM; ALCOHOL OXIDATION; TOPA QUINONE; ACTIVE-SITE; COPPER; HYDROGEN; MODEL; PYRIMIDINES in [K. Bains, Amreen; Adhikari, Debashis] Indian Inst Sci Educ & Res IISER Mohali, Dept Chem Sci, Sas Nagar 140306, Punjab, India; [Ankit, Yadav] Indian Inst Sci Educ & Res IISER Mohali, Dept Earth & Environm Sci, Sas Nagar 140306, Punjab, India in 2021, Cited 42. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Category: alcohols-buliding-blocks

A redox-active iminoquinone motif connected with pi-delocalized pyrene core has been reported that can perform efficient two-electron oxidation of a class of substrates. The design of the molecule was inspired by the organic redox cofactor topaquinone (TPQ), which executes amine oxidation in the enzyme, copper amine oxidase. Easy oxidation of both primary and secondary alcohols happened in the presence of catalytic KOtBu, which could reduce the ligand backbone to its iminosemiquinonate form under photoinduced conditions. Moreover, this easy oxidation of alcohols under aerobic condition could be elegantly extended to multi-component, one-pot coupling for the synthesis of quinoline and pyrimidine. This organocatalytic approach is very mild (70 degrees C, 8 h) compared to a multitude of transition-metal catalysts that have been used to prepare these heterocycles. A detailed mechanistic study proves the intermediacy of the iminosemiquinonate-type radical and a critical hydrogen atom transfer step to be involved in the dehydrogenation reaction.

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Authors Kobayashi, F; Fujita, M; Ide, T; Ito, Y; Yamashita, K; Egami, H; Hamashima, Y in AMER CHEMICAL SOC published article about PHOTOREDOX CATALYSIS; BOND FUNCTIONALIZATION; ACTIVATION; STRATEGY; TETRAHYDROISOQUINOLINES; ORGANOCATALYSIS; ALKYLATION; PHOTOLYSIS; CYANATION; RADICALS in [Kobayashi, Fumihisa; Fujita, Masashi; Ide, Takafumi; Ito, Yuta; Yamashita, Kenji; Egami, Hiromichi; Hamashima, Yoshitaka] Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, Shizuoka 4228526, Japan in 2021, Cited 70. HPLC of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Thiobenzoic acid (TBA) can serve as a single-electron reducing agent under photoirradiation from a blue light-emitting diode, in the presence of appropriate electron acceptors, and the resulting sulfur-centered radical species undergoes hydrogen atom abstraction. This dual-role catalysis by TBA enables regioselectivie C alpha-H arylation of benzylamines, benzyl alcohols, and ethers, as well as dihydroimidazoles, with cyano(hetero)arenes in good yield, without the need for a transition-metal photocatalyst and/or synthetically elaborated organic dyes.

HPLC of Formula: C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Kobayashi, F; Fujita, M; Ide, T; Ito, Y; Yamashita, K; Egami, H; Hamashima, Y or send Email.

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Authors Reddy, PS; Reddy, NG; Serjun, VZ; Mohanty, B; Das, SK; Reddy, KR; Rao, BH in SPRINGER published article about PARTICLE-SHAPE; BAYER-PROCESS; PHYSICAL-PROPERTIES; CARBON-DIOXIDE; WASTE; NEUTRALIZATION; ADSORBENT; LIME; STABILIZATION; STRENGTH in [Reddy, Peddireddy Sreekanth; Mohanty, Bijayananda] NIT Mizoram, Dept Civil Engn, Aizawl 796012, Mizoram, India; [Reddy, Narala Gangadhara; Rao, Bendadi Hanumantha] ITT Bhubaneswar, Sch Infrastruct, Khorda 752050, Odisha, India; [Reddy, Narala Gangadhara] Shantou Univ, Dept Civil & Environm Engn, Shantou 515063, Guangdong, Peoples R China; [Serjun, Vesna Zalar] Slovenian Natl Bldg & Civil Engn Inst Slovenia, Dept Mat, Ljubljana 1000, Slovenia; [Das, Sarat Kumar] IIT ISM Dhanbad, Dept Civil Engn, Dhanbad 826004, Jharkhand, India; [Reddy, Krishna R.] Univ Illinois, Dept Civil & Mat Engn, Chicago, IL USA in 2021, Cited 205. HPLC of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

In order to conserve natural resources and prevent waste generation, effective utilization of industrial wastes and/or by-products for beneficial engineering applications becomes inevitable. In order to accomplish this, extensive research studies, exploring properties and new applications of waste materials in a sustainable and environmentally friendly manner, have been initiated worldwide. Red mud (RM, also known as bauxite residue) is one of the wastes generated by the aluminium industry and its disposal and utilization have been traditionally hindered due to the extreme alkalinity (pH about 10.5-13.5). To date, no comprehensive review on various properties of RM of different origin and associated challenges in using it as a beneficial engineering material has been performed. The objective of this study is first to critically appraise the current understanding of properties of RM through a comprehensive literature review and detailed laboratory investigations conducted on Indian RM by the authors, to assess and identify the potential engineering applications, and to finally discuss associated challenges in using it in practical applications. Physical, chemical, mineralogical and geotechnical properties of RMs of different origin and production processes are reviewed. Mechanisms behind the pozzolanic reaction of RM under different chemical and mineralogical compositional conditions are discussed. Environmental concerns associated with the use of RM are also raised. Studies relevant to leachability characteristics reveal that most of the measured chemical concentrations are within the permissible regulatory limits. Overall, the review shows that RM disposal and reuse is complicated by its extreme alkalinity, which is also noticed to be influencing multiple engineering properties. But with selected pH amendments, the treated RM is found to have significant potential to be used as an effective and sustainable geomaterial. The assessment is majorly based on the characteristics of Indian RMs; hence the adaptation of the findings to other RMs should be assessed on a case-by-case basis. Moreover, field studies demonstrating the performance of RM in various engineering applications are warranted. [GRAPHICS] .

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HPLC of Formula: C8H10O2. Authors Tabaru, K; Nakatsuji, M; Itoh, S; Suzuki, T; Obora, Y in ROYAL SOC CHEMISTRY published article about in [Tabaru, Kazuki; Nakatsuji, Masato; Itoh, Satoshi; Obora, Yasushi] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Suita, Osaka 5648680, Japan; [Suzuki, Takeyuki] Osaka Univ, Inst Sci & Ind Res ISIR, Comprehens Anal Ctr, 8-1 Mihogaoka, Osaka 5670057, Japan in 2021, Cited 16. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

We report N,N-dimethylformamide-stabilised Pd nanoparticle (Pd NP)-catalysed transfer vinylation of alcohols from vinyl ether. Pd NPs combined with bathophenanthroline exhibited high catalytic activity. This reaction proceeded with low catalyst loading and the catalyst remained effective even after many rounds of recycling. The observation of the catalyst using transmission electron microscopy and dynamic light scattering implied no deleterious aggregation of Pd NPs.

HPLC of Formula: C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Tabaru, K; Nakatsuji, M; Itoh, S; Suzuki, T; Obora, Y or send Email.

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I found the field of Chemistry very interesting. Saw the article Nickel-Copper bimetallic mesoporous nanoparticles: As an efficient heterogeneous catalyst for N-alkylation of amines with alcohols published in 2021. Application In Synthesis of (4-Methoxyphenyl)methanol, Reprint Addresses Kassaee, MZ (corresponding author), Tarbiat Modares Univ, Dept Chem, POB 14155-175, Tehran, Iran.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A bimetallic catalyst (Ni/Cu-MCM-41) is prepared via co-condensation method. The latter is characterized by Fourier transform infrared (FT-IR), X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), diffuse reflectance spectroscopy (DRS), and nitrogen adsorption-desorption analysis. Catalytic performance of Ni/Cu-MCM-41 is probed in N-alkylation of amines with alcohols through a hydrogen autotransfer process. Noteworthy, this catalytic system appears very efficient for synthesis of a range of secondary and tertiary amines in good to excellent isolated yields. Moreover, the catalyst is successfully recovered and reused four times without notable decrease in its activity.

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I found the field of Chemistry very interesting. Saw the article Synthesis of the C1-C16 fragment of bryostatin for incorporation into 20,20-fluorinated analogues published in 2021. Safety of (4-Methoxyphenyl)methanol, Reprint Addresses Thomas, EJ (corresponding author), Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

The stereoselective synthesis of a carboxylic acid ester corresponding to the C1 -C16 fragment of bryostatin, with 4-methoxybenzyl (PMB) protection for the 7-hydroxyl group, is reported. The key steps included a Horner-Wadsworth-Emmons reaction between (5R)-3-[ (E)-2-tri- isop ropyls ilyloxy ethylidene]-6-(4-methoxybenzyloxy)-5-triethylsilyloxyhexanal and dimethyl (4,5,6R,85)-10-hydroxy-6,8-di-O-isopropylidene 4 (4 methoxybenzyloxy)-3,3-dimethyl-2-oxodecan-1-yl phosphonate, that gave the corresponding (E)-alkene, followed by selective cleavage of the triethylsilyl ether and cyclisation to give the required 2,6-cis-disubstituted 4-[(Z)-tri-isopropylsilyloxyethylide]tetrahydropyran. Oxidation of the primary alcohol gave the corresponding carboxylic acid that was converted into the required allyl ester. (C) 2020 Elsevier Ltd. All rights reserved.

Welcome to talk about 105-13-5, If you have any questions, you can contact Mears, PR; Thomas, EJ or send Email.. Safety of (4-Methoxyphenyl)methanol

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An article Enantioselective Protonation of Cyclic Carbonyl Ylides by Chiral Lewis Acid Assisted Alcohols WOS:000658032300001 published article about 1,3-DIPOLAR CYCLOADDITION REACTIONS; ASYMMETRIC CYCLOADDITIONS; RHODIUM; CARBENOIDS; DIAZOESTERS; COMPLEXES; CATALYSTS in [Toda, Yasunori; Yoshida, Takayuki; Arisue, Kaoru; Kikuchi, Ayaka; Suga, Hiroyuki] Shinshu Univ, Fac Engn, Dept Mat Chem, 4-17-1 Wakasato, Nagano 3808553, Japan; [Fukushima, Kazuaki; Esaki, Hiroyoshi] Hyogo Coll Med, Dept Chem, 1-1 Mukogawa Cho, Nishinomiya, Hyogo 6638501, Japan in 2021, Cited 60. Safety of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Chiral Lewis acid-catalyzed asymmetric alcohol addition reactions to cyclic carbonyl ylides generated from N-(alpha-diazocarbonyl)-2-oxazolidinones featuring a dual catalytic system are reported. Construction of a chiral quaternary heteroatom-substituted carbon center was accomplished in which the unique heterobicycles were obtained in good yields with high stereoselection. The alcohol adducts were successfully converted to optically active oxazolidine-2,4-diones by hydrolysis. Mechanistic studies by DFT calculations revealed that alcohols could be activated by Lewis acids, enabling enantioselective protonation of the carbonyl ylides.

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I found the field of Chemistry very interesting. Saw the article alpha-Alkylation of arylacetonitriles with primary alcohols catalyzed by backbone modified N-heterocyclic carbene iridium(I) complexes published in 2021. COA of Formula: C8H10O2, Reprint Addresses Gulcemal, S (corresponding author), Ege Univ, Dept Chem, TR-35100 Izmir, Turkey.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A series of backbone-modified N-heterocyclic carbene (NHC) complexes of iridium(I) (1d-f) have been synthesized and characterized. The electronic properties of the NHC ligands have been assessed by comparison of the IR carbonyl stretching frequencies of the in situ prepared [IrCl(CO)(2)(NHC)] complexes in CH2Cl2. These new complexes (1d-f), together with previously prepared 1a-c, were applied as catalysts for the alpha-alkylation of arylacetonitriles with an equimolar amount of primary alcohols or 2-aminobenzyl alcohol. The catalytic activities of these complexes could be controlled by modifying the N-substituents and backbone of the NHC ligands. The NHC-Ir-I complex 1f bearing 4-methoxybenzyl substituents on the N-atoms and 4-methoxyphenyl groups at the 4,5-positions of imidazole exhibited the highest catalytic activity in the alpha-alkylation of arylacetonitriles with primary alcohols. Various alpha-alkylated nitriles and aminoquinolines were obtained in high yields through a borrowing hydrogen pathway by using 0.1 mol% 1f and a catalytic amount of KOH (5 mol%) under an air atmosphere within significantly short reaction times.

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An article Vanadium C-scorpionate supported on mesoporous aptes-functionalized SBA-15 as catalyst for the peroxidative oxidation of benzyl alcohol WOS:000652645700004 published article about CYCLOHEXANE OXIDATION; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; HIGHLY EFFICIENT; METAL-COMPLEXES; II COMPLEX; SOLVENT; SILICA; DESULFURIZATION in [Correia, Luis M. M.; Soliman, Mohamed M. A.; Alegria, Elisabete C. B. A.] Inst Politecn Lisboa, Inst Super Engn Lisboa, Dept Engn Quim, R Conselheiro Emidio Navarro 1, P-1959007 Lisbon, Portugal; [Correia, Luis M. M.; Soliman, Mohamed M. A.; Martins, Luisa M. D. R. S.; Pombeiro, Armando J. L.; Alegria, Elisabete C. B. A.] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, Av Rovisco Pais, P-1049001 Lisbon, Portugal; [Correia, Luis M. M.; Soliman, Mohamed M. A.; Martins, Luisa M. D. R. S.; Pombeiro, Armando J. L.; Alegria, Elisabete C. B. A.] Univ Lisbon, Inst Super Tecn, Dept Engn Quim, Av Rovisco Pais, P-1049001 Lisbon, Portugal; [Granadeiro, Carlos M.; Balula, Salete S.] Univ Porto, Dept Quim & Bioquim, LAQV REQUIMTE, Fac Ciencias, Rua Campo Alegre S-N, P-4169007 Porto, Portugal in 2021, Cited 62. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: 105-13-5

The neutral trichloro[hydrotris(1-pyrazolyl)methane]vanadium(III) [VCl3(Tpm)] (Tpm = HC(pz)(3); pz = pyrazolyl) C-scorpionate complex was immobilized on amine-functionalized mesoporous silica (aptesSBA-15) via an impregnation method forming the [VCl3(Tpm)]@aptesSBA-15 composite. The immobilization of the vanadium compound was confirmed by several characterization techniques, namely SEM/EDS, powder XRD, FT-IR/ATR, ICP and BET surface area analysis, revealing the successful incorporation of the complex, and confirming the structural and morphological preservation of the porous support and the vanadium complex. The vanadium composite was tested as heterogeneous catalyst for the peroxidative oxidation of benzyl alcohol under mild conditions and its catalytic performance was compared to that of the analogous homogeneous [VCl3(Tpm)] complex. The catalytic studies were extended to other substrates. The effect of various parameters, such as amount and type of oxidant, catalyst and additives, temperature and reaction time were investigated allowing to reach overall yields of ca. 60% and turnover numbers (TONs) up to ca. 7.6 x 10(3). The results obtained demonstrated the higher performance of the heterogeneous catalyst using much less [VCl3(Tpm)] complex under a solvent-free system. Furthermore, consecutive reaction cycles could be performed, showing its recycling capacity. Structural stability was also investigated, indicating the viability of the vanadium C-scorpionate composite as catalyst for other oxidative reactions with high industrial interest.

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