Category: 105-13-5

I found the field of Chemistry very interesting. Saw the article Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis published in 2021. Name: (4-Methoxyphenyl)methanol, Reprint Addresses Shu, XZ (corresponding author), Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Catalytic transformation of alcohols via metal-catalyzed cross-coupling reactions is very important, but it typically relies on a multistep procedure. We here report a dynamic kinetic cross-coupling approach for the direct functionalization of alcohols. The feasibility of this strategy is demonstrated by a nickel-catalyzed cross-electrophile arylation reaction of benzyl alcohols with (hetero)aryl electrophiles. The reaction proceeds with a broad substrate scope of both coupling partners. The electron-rich, electron-poor, and ortho-/meta-/para-substituted (hetero)aryl electrophiles (e.g., Ar-OTf, Ar-I, Ar-Br, and inert Ar-Cl) all coupled well. Most of the functionalities, including aldehyde, ketone, amide, ester, nitrile, sulfone, furan, thiophene, benzothiophene, pyridine, quinolone, Ar-SiMe3, Ar-Bpin, and Ar-SnBu3, were tolerated. The dynamic nature of this method enables the direct arylation of benzylic alcohol in the presence of various nucleophilic groups, including nonactivated primary/secondary/tertiary alcohols, phenols, and free indoles. It thus offers a robust alternative to existing methods for the precise construction of diarylmethanes. The synthetic utility of the method was demonstrated by a concise synthesis of biologically active molecules and by its application to peptide modification and conjugation. Preliminary mechanistic studies revealed that the reaction of in situ formed benzyl oxalates with nickel, possibly via a radical process, is an initial step in the reaction with aryl electrophiles.

Name: (4-Methoxyphenyl)methanol. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Category: alcohols-buliding-blocks. Authors Epifanov, M; Mo, JY; Dubois, R; Yu, H; Sammis, GM in AMER CHEMICAL SOC published article about in [Epifanov, Maxim; Mo, Jia Yi; Dubois, Rudy; Yu, Hao; Sammis, Glenn M.] Univ British Columbia, Dept Chem, Columbia, BC V6T 1Z1, Canada in 2021, Cited 48. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Sulfuryl fluoride is a valuable reagent for the one-pot activation and derivatization of aliphatic alcohols, but the highly reactive alkyl fluorosulfate intermediates limit both the types of reactions that can be accessed as well as the scope. Herein, we report the SO2F2-mediated alcohol substitution and deoxygenation method that relies on the conversion of fluorosulfates to alkyl halide intermediates. This strategy allows the expansion of SO2F2-mediated one-pot processes to include radical reactions, where the alkyl halides can also be exploited in the one-pot deoxygenation of primary alcohols under mild conditions (52-95% yield). This strategy can also enhance the scope of substitutions to nucleophiles that are previously incompatible with one-pot SO2F2-mediated alcohol activation and enables substitution of primary and secondary alcohols in 54-95% yield. Chiral secondary alcohols undergo a highly stereospecific (90-98% ee) double nucleophilic displacement with an overall retention of configuration.

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An article Palladium (II)-catalyzed homogeneous alcohol oxidations: Disclosing the crucial contribution of palladium nanoparticles in catalysis WOS:000590610700001 published article about NONREDOX METAL-IONS; SELECTIVE OXIDATION; AEROBIC OXIDATION; DIOXYGEN ACTIVATION; PD NANOPARTICLES; OXYGEN; HECK; COMPLEXES; FRONTIER; LIGAND in [Zeng, Miao; Lou, Chenlin; Xue, Jing-Wen; Jiang, Hongwu; Li, Kaiwen; Chen, Zhuqi; Fu, Shitao; Yin, Guochuan] Huazhong Univ Sci & Technol, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Mat Chem Energy Convers & Storage, Sch Chem & Chem Engn,Minist Educ, Wuhan 430074, Peoples R China in 2021, Cited 35. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. COA of Formula: C8H10O2

Versatile redox catalysts play the significant roles in alcohol oxidations, in which the mechanisms for homogeneous and heterogeneous alcohol oxidations are generally different. This work introduced a Lewis acid (LA) promoted homogeneous alcohol oxidation with Pd (OAc)(2) catalyst by using oxygen balloon as the oxidant source. It was found that adding Lewis acid such as Sc (OTf)(3) significantly accelerated Pd (II)-catalyzed alcohol oxidations; notably, the time courses of oxidations monitored by GC and H-1 NMR disclosed that there existed two processes including the initial sluggish oxidation followed by a rapid oxidation. The promotional effect of Lewis acid was attributed to the formation of heterobimetallic Pd (II)/LA species, which improved the oxidizing power of the palladium (II) species, thus accelerating alcohol oxidation in the induction period. Correlating the sizes of in situ generated palladium nanoparticles with the time course of alcohol oxidation further disclosed that the loosely, spherically large nanoparticles, which were composed of many tiny nanoparticles having the size less than 10 nm, were responsible for the rapid oxidation, whereas those highly dispersed, tiny nanoparticles having the size less than 10 nm were not responsible for the rapid oxidation.

Welcome to talk about 105-13-5, If you have any questions, you can contact Zeng, M; Lou, CL; Xue, JW; Jiang, HW; Li, KW; Chen, ZQ; Fu, ST; Yin, GC or send Email.. COA of Formula: C8H10O2

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Quality Control of (4-Methoxyphenyl)methanol. Authors Xiao, WL; Mo, YH; Guo, J; Su, ZS; Dong, SX; Feng, XM in ROYAL SOC CHEMISTRY published article about in [Xiao, Wanlong; Mo, Yuhao; Guo, Jing; Su, Zhishan; Dong, Shunxi; Feng, Xiaoming] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China in 2021, Cited 64. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

New types of C-2-symmetric chiral macrodiolides are readily obtained via chiral N,N ‘-dioxide-scandium(iii) complex-promoted asymmetric tandem Friedel-Crafts alkylation/intermolecular macrolactonization of ortho-quinone methides with C3-substituted indoles. This protocol provides an array of enantioenriched macrodiolides with 16, 18 or 20-membered rings in moderate to good yields with high diastereoselectivities and excellent enantioselectivities through adjusting the length of the tether at the C3 position of indoles. Density functional theory calculations indicate that the formation of macrocycles is more favorable than that of 9-membered-ring lactones in terms of kinetics and thermodynamics. The potential utility of these intriguing chiral macrodiolide molecules is demonstrated in the enantiomeric recognition of aminols and chemical recognition of metal ions.

Welcome to talk about 105-13-5, If you have any questions, you can contact Xiao, WL; Mo, YH; Guo, J; Su, ZS; Dong, SX; Feng, XM or send Email.. Quality Control of (4-Methoxyphenyl)methanol

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Computed Properties of C8H10O2. I found the field of Chemistry very interesting. Saw the article Magnetically recyclable CuFe2O4 catalyst for efficient synthesis of bis (indolyl)methanes using indoles and alcohols under mild condition published in 2021, Reprint Addresses Hung, TQ; Vu, XH (corresponding author), Vietnam Acad Sci & Technol, Inst Chem, 18 Hoang Quoc Viet, Hanoi, Vietnam.; Dang, TT (corresponding author), VNU Hanoi Univ Sci, Dept Chem, 19 Le Thanh Tong, Hanoi, Vietnam.; Vu, XH (corresponding author), Vietnam Petr Inst, 167 Trung Kinh Str, Hanoi, Vietnam.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol.

Bis(3-indolyl)methanes (BIM) are highly valuable and appear in the core structure of many natural products and pharmacologically active compounds (anticancer, anti-inflammatory, antiobesity, antimetastatic, antimicrobial, etc.). Herein, we have disclosed an air stable and highly efficient CuFe2O4 heterogeneous catalyst for alkylation of indoles with alcohols to give bis(3-indolyl)methanes in very good yields. The CuFe2O4 catalyst has been found to be magnetically recycled at least five times without losing significant catalytic activity.

Computed Properties of C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Authors Yao, HY; Wang, YS; Razi, MK in ROYAL SOC CHEMISTRY published article about in [Yao, Hongyan] Hebi Polytech, Deans Off, Hebi 458030, Peoples R China; [Wang, Yongsheng] Henan Polytech Univ, Sch Phys Sci Educ, Jiaozuo 454003, Henan, Peoples R China; [Razi, Maryam Kargar] Islamic Azad Univ, North Branch Tehran, Fac Chem, Tehran, Iran in 2021, Cited 82. SDS of cas: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

In this study, a magnetic asymmetric Salamo-based Zn complex (H2L = salen type di-Schiff bases)-supported on the surface of modified Fe3O4 (Fe3O4@H2L-Zn) as a new catalyst was designed and characterized via numerous analytical techniques such as FT-IR spectroscopy, XRD, EDS, ICP-AES, SEM, TEM, TGA and VSM. An efficient and sustainable synthetic protocol has been presented for the synthesis of silyl ether substructures via the silyl protection of alcohols under mild conditions. The synthetic protocol involves a two-component solvent-free reaction between various hydroxyl-bearing substrates and hexamethyldisilazane (HMDS) as an inexpensive silylating agent using Fe3O4@H2L-Zn MNPs as a magnetically separable, recyclable and reusable heterogeneous catalyst. Fe3O4@H2L-Zn MNPs were also applied for the removal of silyl protecting groups from hydroxyl functions using water in CH2Cl2 under green conditions. The catalyst demonstrated good to excellent catalytic yield efficiency for both the reactions compared to the commercial metal-based catalysts under green conditions for a wide range of substrates.

Welcome to talk about 105-13-5, If you have any questions, you can contact Yao, HY; Wang, YS; Razi, MK or send Email.. SDS of cas: 105-13-5

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I found the field of Cardiovascular System & Cardiology very interesting. Saw the article Comparison between sedation room and operating room in central venous catheter positioning in children published in 2021. Name: (4-Methoxyphenyl)methanol, Reprint Addresses Gatto, A (corresponding author), Fdn Policlin Univ Agostino, Gemelli IRCCS, Inst Pediat, Largo Agostino Gemelli 8, I-00168 Rome, Italy.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Background: Placement of central venous access devices is a clinical procedure associated with some risk of adverse events and with a relevant cost. Careful choice of the device, appropriate insertion technique, and proper management of the device are well-known strategies commonly adopted to achieve an optimal clinical result. However, the environment where the procedure takes place may have an impact on the overall outcome in terms of safety and cost-effectiveness. Methods: We carried out a retrospective analysis on pediatric patients scheduled for a major neurosurgical operation, who required a central venous access device in the perioperative period. We divided the patients in two groups: in group A the central venous access device was inserted in the operating room, while in group B the central venous access device was inserted in the sedation room of our Pediatric Intensive Care Unit. We compared the two groups in terms of safety and cost-effectiveness. Results: We analyzed 47 central venous access devices in 42 children. There were no insertion-related complications. Only one catheter-related bloodstream infection was recorded, in group A. However, the costs related to central venous access device insertion were quite different: euro330-euro540 in group A versus euro105-euro135 in group B. Conclusion: In the pediatric patient candidate to a major neurosurgical operation, preoperative insertion of the central venous access device in the sedation room rather than in the operating room is less expensive and equally safe.

Welcome to talk about 105-13-5, If you have any questions, you can contact Chiaretti, A; Pittiruti, M; Sassudelli, G; Conti, G; Rossi, M; Pulitano, SM; Mancino, A; Pusateri, A; Gatto, A; Tosi, F or send Email.. Name: (4-Methoxyphenyl)methanol

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In 2021 APPL ORGANOMET CHEM published article about NONREDOX METAL-IONS; SELECTIVE OXIDATION; AEROBIC OXIDATION; DIOXYGEN ACTIVATION; PD NANOPARTICLES; OXYGEN; HECK; COMPLEXES; FRONTIER; LIGAND in [Zeng, Miao; Lou, Chenlin; Xue, Jing-Wen; Jiang, Hongwu; Li, Kaiwen; Chen, Zhuqi; Fu, Shitao; Yin, Guochuan] Huazhong Univ Sci & Technol, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Mat Chem Energy Convers & Storage, Sch Chem & Chem Engn,Minist Educ, Wuhan 430074, Peoples R China in 2021, Cited 35. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Category: alcohols-buliding-blocks

Versatile redox catalysts play the significant roles in alcohol oxidations, in which the mechanisms for homogeneous and heterogeneous alcohol oxidations are generally different. This work introduced a Lewis acid (LA) promoted homogeneous alcohol oxidation with Pd (OAc)(2) catalyst by using oxygen balloon as the oxidant source. It was found that adding Lewis acid such as Sc (OTf)(3) significantly accelerated Pd (II)-catalyzed alcohol oxidations; notably, the time courses of oxidations monitored by GC and H-1 NMR disclosed that there existed two processes including the initial sluggish oxidation followed by a rapid oxidation. The promotional effect of Lewis acid was attributed to the formation of heterobimetallic Pd (II)/LA species, which improved the oxidizing power of the palladium (II) species, thus accelerating alcohol oxidation in the induction period. Correlating the sizes of in situ generated palladium nanoparticles with the time course of alcohol oxidation further disclosed that the loosely, spherically large nanoparticles, which were composed of many tiny nanoparticles having the size less than 10 nm, were responsible for the rapid oxidation, whereas those highly dispersed, tiny nanoparticles having the size less than 10 nm were not responsible for the rapid oxidation.

Category: alcohols-buliding-blocks. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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In 2021 CATAL LETT published article about METAL-ORGANIC FRAMEWORK; SELECTIVE OXIDATION; AROMATIC ALCOHOLS; HYDROGEN-PRODUCTION; REACTIVE DYE; NANOCOMPOSITE; EFFICIENT; MIL-101; NANOPARTICLES; PERFORMANCE in [Wang, Mingming; Ma, Yali; Lv, Bolin; Hua, Fenglin; Meng, Shuangyan; Lei, Xuedi; Wang, Qingtao; Su, Bitao; Lei, Ziqiang; Yang, Zhiwang] Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Polymer Mat Gansu Prov, Key Lab Ecofunct Polymer Mat,Minist Educ, Lanzhou 730070, Peoples R China in 2021, Cited 44. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Name: (4-Methoxyphenyl)methanol

A novel photoactive porous material of GR/FeMIL-101 based on FeMIL-101 metal organic frameworks (MOFs) was successfully synthesized via a simple hydrothermal method. The structural and photoelectric properties of the GR/FeMIL-101 was analyzed by XRD, SEM, TEM, TGA, XPS, UV-vis DRS, FT-IR, PL and EIS methods. The photocatalytic performance for the selective oxidation of benzyl alcohol with GR/FeMIL-101 as catalysts was evaluated under visible light irradiation. The results showed that the GR/FeMIL-101 nanohybrid had better photocatalytic performance than both of FeMIL-101 and the pristine MIL-101. It was further found that the incorporation of Fe and MIL-101 caused valence fluctuations of Fe3+/Fe2+ which improved the absorption of visible-light and increased the separation efficiency of photogenerated charges. In addition, the combination of FeMIL-101 and GR could further promote the transfer rate of the photoelectrons. The mechanism of the reaction revealed that center dot O-2(-) was the dominating active specie in this reaction through active species trapping experiments. [GRAPHICS] .

Welcome to talk about 105-13-5, If you have any questions, you can contact Wang, MM; Ma, YL; Lv, BL; Hua, FL; Meng, SY; Lei, XD; Wang, QT; Su, BT; Lei, ZQ; Yang, ZW or send Email.. Name: (4-Methoxyphenyl)methanol

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Recommanded Product: 105-13-5. In 2020 CATAL SCI TECHNOL published article about FACILE SYNTHESIS; REACTANTS ACTIVATION; NO ADSORPTION; DOPED G-C3N4; EFFICIENT; NANOSHEETS; ZIRCONIA; REACTIVITY; VACANCIES; MECHANISM in [Wang, Jiadong; Chen, Ruimin; Yuan, Chaowei; Dong, Fan; Sun, Yanjuan] Chongqing Technol & Business Univ, Coll Environm & Resources, Chongqing Key Lab Catalysis & New Environm Mat, Chongqing 400067, Peoples R China; [Wang, Jiadong; Cui, Wen; He, Ye; Yuan, Chaowei; Sheng, Jianping; Li, Jieyuan; Dong, Fan; Sun, Yanjuan] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Res Ctr Environm Sci & Technol, Chengdu 611731, Peoples R China; [Cui, Wen] Southwest Petr Univ, Sch Mat Sci & Engn, Ctr New Energy Mat & Thchnol, Chengdu 610500, Peoples R China; [Zhan, Yuxin] Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China in 2020, Cited 60. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Graphitic carbon nitride (g-C3N4, CN for short) is a compelling visible-light responsive photocatalyst. However, its photocatalytic efficiency is low due to the random carrier transfer in planes and insufficient redox potential. Herein, we build oxygen functional group modified sodium-doped carbon nitride (OH/Na co-functionalized carbon nitride) to promote directional transfer of charge carriers for acceleration of separation and enhance redox potential for efficient oxidation of NO in air. Specifically, the function of sodium atoms could control the directional transfer of random carriers from the intralayer to the oxygen functional group-modified surface for the purpose of effectively reducing photogenerated electron-hole recombination. Meanwhile, the modification by oxygen-containing functional groups could adjust the band structure of CN, thereby increasing the oxidation-reduction potential of NO in the photocatalyst. The transformation pathways and reaction mechanism of photocatalytic NO oxidation on CN and OH/Na co-functionalized carbon nitride have also been explicated by ESR spectroscopy and in situ DRIFTS and compared. This work provides a new method for simultaneously controlling the random transfer of carriers and adjusting the energy band structure of CN to optimize its photocatalytic efficiency. It is also possible to extend this strategy to improve the performance of other 2D layered catalysts for photocatalytic oxidation.

Recommanded Product: 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Wang, JD; Cui, W; Chen, RM; He, Y; Yuan, CW; Sheng, JP; Li, JY; Zhan, YX; Dong, F; Sun, YJ or send Email.

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