Category: 105-13-5

Recently I am researching about AEROBIC OXIDATION; BENZYLIC ALCOHOLS; C-H; COPPER; ALDEHYDES; MILD, Saw an article supported by the . Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Kargar, H; Bazrafshan, M; Fallah-Mehrjardi, M; Behjatmanesh-Ardakani, R; Rudbari, HA; Munawar, KS; Ashfaq, M; Tahir, MN. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. COA of Formula: C8H10O2

For the first time, two new oxovanadium and dioxomolybdenum Schiff base complexes, VOL(OMe) and MoO2L, were synthesized through the reaction of a ONO tridentate Schiff base ligand (H2L) derived from the condensation of 5-bromosalicylaldehyde and nicotinic hydrazide with oxo and dioxo acetylacetonate salts of vanadium and molybdenum, [VO(acac)(2) and MoO2(acac)2], respectively. The synthesized ligand and complexes were characterized by various spectroscopic techniques like FT-IR, H-1 NMR, C-13 NMR, elemental analysis (CHN) and the most authentic single crystal X-ray diffraction analysis (SC-XRD). The geometry around the central metal ion in MoO2L was distorted octahedral as revealed by the data collected from diffraction studies. Non-covalent interactions that are responsible for crystal packing are explored by Hirshfeld surface analysis. Theoretical calculations of the synthesized compounds, carried out by DFT at B3LYP/Def2-TZVP level of theory, indicated that the calculated results are in agreement with the experimental findings. Moreover, the catalytic activities of both complexes were investigated for the selective oxidation of benzylic alcohols using urea hydrogen peroxide (UHP) in acetonitrile. (C) 2021 Elsevier Ltd. All rights reserved.

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An article HFIP-catalyzed direct dehydroxydifluoroalkylation of benzylic and allylic alcohols with difluoroenoxysilanes WOS:000613461100020 published article about FLUORINATED ALCOHOLS; SOLVENTS; ACCESS; BENZYLATION; ALLYLATION; REAGENTS; ETHERS in [Li, Jinshan; Xi, Wenxue; Zhong, Rong; Yang, Jianguo; Wang, Lei; Wang, Zhiming] Taizhou Univ, Adv Res Inst, 1139 Shifu Ave, Taizhou 318000, Peoples R China; [Li, Jinshan; Xi, Wenxue; Zhong, Rong; Yang, Jianguo; Wang, Lei; Wang, Zhiming] Taizhou Univ, Dept Chem, 1139 Shifu Ave, Taizhou 318000, Peoples R China; [Ding, Hanfeng] Zhejiang Univ, Dept Chem, Hangzhou 310058, Peoples R China in 2021, Cited 49. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Category: alcohols-buliding-blocks

Hexafluoroisopropanol (HFIP)-catalyzed direct dehydroxydifluoro-alkylation of benzylic and allylic alcohols with difluoroenoxysilanes is developed. This procedure enables the synthesis of a broad range of alpha,alpha-difluoroketones, a class of highly valuable intermediates and building blocks in medicinal and organic chemistry. Here, we have demonstrated for the first time that HFIP could act as a powerful catalyst for fluorinated carbon-carbon bond formation. The application of this protocol in late-stage dehydroxydifluoroalkylation of potentially bioactive drugs and natural products has also been carried out.

Category: alcohols-buliding-blocks. Welcome to talk about 105-13-5, If you have any questions, you can contact Li, JS; Xi, WX; Zhong, R; Yang, JG; Wang, L; Ding, HF; Wang, ZM or send Email.

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Recently I am researching about CYCLOHEXANE OXIDATION; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; HIGHLY EFFICIENT; METAL-COMPLEXES; II COMPLEX; SOLVENT; SILICA; DESULFURIZATION, Saw an article supported by the Fundacao para a Ciencia e a Tecnologia (FCT), Portugal (Centro de Quimica Estrutural) [UIDB/00100/2020]; Fundacao para a Ciencia e a Tecnologia (FCT), PortugalPortuguese Foundation for Science and Technology [PTDC/QUI-QIN/29778/2017]; REQUIMTE-LAQV (FCT) [POCI-01-0145-FEDER-007265, UID/QUI/50006/2013]; FCT/MEC [GlyGold PTDC/CTM-CTM/31983/2017]; Fundo Europeu de Desenvolvimento Regional (FEDER) under the PT2020 Partnership Agreement; national funds (OE), through FCT-Fundacao para a Ciencia e a Tecnologia, I.P.. Published in ELSEVIER in AMSTERDAM ,Authors: Correia, LMM; Soliman, MMA; Granadeiro, CM; Balula, SS; Martins, LMDRS; Pombeiro, AJL; Alegria, ECBA. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. Computed Properties of C8H10O2

The neutral trichloro[hydrotris(1-pyrazolyl)methane]vanadium(III) [VCl3(Tpm)] (Tpm = HC(pz)(3); pz = pyrazolyl) C-scorpionate complex was immobilized on amine-functionalized mesoporous silica (aptesSBA-15) via an impregnation method forming the [VCl3(Tpm)]@aptesSBA-15 composite. The immobilization of the vanadium compound was confirmed by several characterization techniques, namely SEM/EDS, powder XRD, FT-IR/ATR, ICP and BET surface area analysis, revealing the successful incorporation of the complex, and confirming the structural and morphological preservation of the porous support and the vanadium complex. The vanadium composite was tested as heterogeneous catalyst for the peroxidative oxidation of benzyl alcohol under mild conditions and its catalytic performance was compared to that of the analogous homogeneous [VCl3(Tpm)] complex. The catalytic studies were extended to other substrates. The effect of various parameters, such as amount and type of oxidant, catalyst and additives, temperature and reaction time were investigated allowing to reach overall yields of ca. 60% and turnover numbers (TONs) up to ca. 7.6 x 10(3). The results obtained demonstrated the higher performance of the heterogeneous catalyst using much less [VCl3(Tpm)] complex under a solvent-free system. Furthermore, consecutive reaction cycles could be performed, showing its recycling capacity. Structural stability was also investigated, indicating the viability of the vanadium C-scorpionate composite as catalyst for other oxidative reactions with high industrial interest.

Computed Properties of C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Correia, LMM; Soliman, MMA; Granadeiro, CM; Balula, SS; Martins, LMDRS; Pombeiro, AJL; Alegria, ECBA or send Email.

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SDS of cas: 105-13-5. In 2021 CHEM COMMUN published article about CONJUGATED MICROPOROUS POLYMERS; AEROBIC OXIDATION; ORGANIC FRAMEWORKS; CATALYTIC-SYSTEM; SUPPORTED TEMPO; CORE-SHELL; SPHERES; DESIGN in [Shen, Yan-Ming; Xue, Yun; Yan, Mi; Mao, Hui-Ling; Cheng, Hu; Chen, Zhuo; Yu, Xiu-Jun; Zhuang, Jin-Liang] Guizhou Normal Univ, Key Lab Funct Mat Chem Guizhou Prov, Sch Chem & Mat Sci, 116 Baoshan Rd North, Guiyang 550001, Peoples R China; [Sui, Zhi-Wei] Natl Inst Metrol, Ctr Adv Measurement Sci, Beijing, Peoples R China; [Zhu, Shao-Bin; Zhuang, Jin-Liang] NanoFCM INC, Xiamen Pioneering Pk Overseas Chinese Scholars, Xiamen 361005, Peoples R China; [Yu, Xiu-Jun] Goethe Univ Frankfurt, Inst Inorgan & Analyt Chem, Max von Laue Str 7, D-60438 Frankfurt, Germany in 2021, Cited 34. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A bottom-up approach was developed to prepare TEMPO radical decorated hollow aromatic frameworks (HPAF-TEMPO) by using TEMPO radical functionalized monomers and SiO2 nanospheres as templates. The accessible inner layer, high density of TEMPO sites, and hybrid micro-/mesopores of the HPAF-TEMPO enable the aerobic oxidation of a broad range of alcohols with high efficiency and excellent selectivity.

SDS of cas: 105-13-5. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Authors Yang, SN; Liu, XY; Lu, SJ; Li, Z; Zhang, YM; Yu, SN; Song, J; Ding, CF; Yang, HY in WILEY-V C H VERLAG GMBH published article about in [Yang, Shouning; Yu, Shaoning; Yang, Huayan] Ningbo Univ, Sch Mat Sci & Chem Engn, Inst Mass Spectrometry, Zhejiang Prov Key Lab Adv Mass Spectrometry & Mol, Ningbo 315211, Zhejiang, Peoples R China; [Zhang, Yanmin; Song, Jian] Henan Normal Univ, Sch Phys, Xinxiang 453007, Henan, Peoples R China; [Yang, Shouning; Liu, Xiaoyang; Lu, Sijia; Li, Zhuo; Yang, Huayan] Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Key Lab Green Chem Media & React, Minist Educ,Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China in 2021, Cited 65. SDS of cas: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The development of eco-friendly and low cost catalysts is challenging. Here, heterostructures of Bi2S3 quantum dots (QDs) doped onto ultrathin BiOCl nanosheets were synthesized by a facile hydrothermal method to exploit efficient photosensitizers with appropriate electronic states to enhance the transfer of electrons. The obtained Bi2S3-BiOCl showed highly efficient photocatalytic ability for selective oxidation of aromatic alcohols to aldehydes. More oxygen vacancies are formed on the exposed 001 facet of the ultrathin BiOCl, which can effectively trap electrons and form O-.(2)- radicals. The cooperation between the BiOCl and the Bi2S3 QDs effectively separates photogenerated electron-hole pairs at the heterointerface and facilitates the cooperative actions of O-.(2)- radicals and holes, which brings about a desirable photocatalytic eciency for the selective oxidation of aromatic alcohols. This work highlights the synergistic effect of semiconductor QDs and two-dimensional materials on selective conversion processes and provides a new design paradigm using noble metal-free heteromaterials with high photocatalytic activity. This opens new possibilities for photocatalyst design using heteromaterials with high photocatalytic activity.

Welcome to talk about 105-13-5, If you have any questions, you can contact Yang, SN; Liu, XY; Lu, SJ; Li, Z; Zhang, YM; Yu, SN; Song, J; Ding, CF; Yang, HY or send Email.. SDS of cas: 105-13-5

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COA of Formula: C8H10O2. In 2021 AUST J CHEM published article about VITAMIN-E in [Shahnavaz, Zohreh; Zaharani, Lia; Khaligh, Nader Ghaffari; Johan, Mohd Rafie] Univ Malaya, Inst Postgrad Studies, Nanotechnol & Catalysis Res Ctr, 3rd Floor,Block A, Kuala Lumpur 50603, Malaysia; [Mihankhah, Taraneh] Iran Univ Sci & Technol, Sch Civil Engn, Dept Water & Environm Engn, Environm Res Lab, Tehran 16765163, Iran in 2021, Cited 35. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A new ionic liquid was synthesised, and its chemical structure was elucidated by FT-IR, 1D NMR, 2D NMR, and mass analyses. Some physical properties, thermal behaviour, and thermal stability of this ionic liquid were investigated. The formation of a two-protonic acid salt namely 4,4′-trimethylene-N,N’-dipiperidinium sulfate instead of 4,4′-trimethylene-N,N’-dipiperidinium hydrogensulfate was evidenced by NMR analyses. The catalytic activity of this ionic liquid was demonstrated in the esterification reaction of n-butanol and glacial acetic acid under different conditions. The desired acetate was obtained in 62-88% yield without using a Dean-Stark apparatus under optimal conditions of 10 mol-% of the ionic liquid, an alcohol to glacial acetic acid mole ratio of 1.3 : 1.0, a temperature of 75-100 degrees C, and a reaction time of 4 h. alpha-Tocopherol (alpha-TCP), a highly efficient form of vitamin E, was also treated with glacial acetic acid in the presence of the ionic liquid, and O-acetyl-alpha-tocopherol (Ac-TCP) was obtained in 88.4% yield. The separation of esters was conducted during workup without the utilisation of high-cost column chromatography. The residue and ionic liquid were used in subsequent runs after the extraction of desired products. The ionic liquid exhibited high catalytic activity even after five runs with no significant change in its chemical structure and catalytic efficiency.

COA of Formula: C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Shahnavaz, Z; Zaharani, L; Khaligh, NG; Mihankhah, T; Johan, MR or send Email.

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In 2021 EUR J ORG CHEM published article about CATALYZED AEROBIC DEHYDROGENATION; BIOLOGICAL EVALUATION; MOLECULAR-OXYGEN; HECK REACTION; 2′-AMINOCHALCONES; EFFICIENT; FLAVANONES; INHIBITORS; CHEMISTRY; QUINOLONE in [Kim, Young Min; Yoo, Hyung-Seok; Son, Seung Hwan; Kim, Ga Yeong; Jang, Hyu Jeong; Kim, Dong Hwan; Kim, Nam-Jung] Kyung Hee Univ, Coll Pharm, 26 Kyungheedae Ro, Seoul 02447, South Korea; [Kim, Soo Dong; Park, Boyoung Y.; Kim, Nam-Jung] Kyung Hee Univ, Dept Life & Nanopharmaceut Sci, 26 Kyungheedae Ro, Seoul 02447, South Korea in 2021, Cited 36. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. COA of Formula: C8H10O2

2-Aryl-2,3-dihydroquinolin-4(1H)-ones have recently been identified as important structures with potent biological activities such as antitumor and antidiabetic effect. Herein, a total of 25 novel N-Tf 2-aryl-2,3-dihydroquinolin-4(1H)-ones were expediently synthesized via the oxidative aza-Michael cyclization of N-Tf-2 ‘-aminodihydrochalcones by ligand-free palladium(II) catalysis. This study presents a new synthetic approach to yield N-Tf 2-aryl-2,3-dihydroquinolin-4(1H)-ones, which can be easily transformed into pharmacologically interesting aza-flavanones and other N-heterocycles, such as quinolines and tetrahydroquinolines, in yields up to 84 %. This methodology has various advantages, which includes short reaction times under mild conditions and suitable functional group tolerance. Furthermore, a plausible mechanism was proposed and demonstrated by kinetic analysis.

COA of Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Formula: C8H10O2. Authors Feng, XY; Pi, YH; Song, Y; Xu, ZW; Li, Z; Lin, WB in AMER CHEMICAL SOC published article about in [Feng, Xuanyu; Pi, Yunhong; Song, Yang; Xu, Ziwan; Lin, Wenbin] Univ Chicago, Dept Chem, Chicago, IL 60637 USA; [Pi, Yunhong; Li, Zhong] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

We report here the construction of two metal-organic frameworks (MOFs), Zr-6-Cu/Fe-1 and Zr-6–Cu/Fe-2, by integrating earth-abundant cuprous photosensitizers (Cu-PSs) and Fe catalysts for photocatalytic aerobic oxidation. Site isolation and pore confinement stabilize both Cu-PSs and Fe catalysts, while the proximity between active centers facilitates electron and mass transfer. Upon visible light irradiation and using O-2 as the only oxidant, Zr-6-Cu/Fe-1 and Zr-6-Cu/ Fe-2 efficiently oxidize alcohols and benzylic compounds to afford corresponding carbonyl products with broad substrate scopes, high turnover numbers of up to 500 with a 9.4-fold enhancement over homogeneous analogues, and excellent recyclability in four consecutive runs. Control experiments, spectroscopic evidence, and computational studies revealed the photooxidation mechanism: oxidative quenching of [Cu-PS]* by O-2 affords [Cu-II-PS], which efficiently oxidizes Fe-III-OH to generate a hydroxyl radical for substrate oxidation. This work highlights the potential of MOFs in promoting earth-abundant metal-based photocatalysis.

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Recommanded Product: (4-Methoxyphenyl)methanol. Authors Li, Y; Pan, CS; Wang, GL; Leng, Y; Jiang, PP; Dong, YM; Zhu, YF in ROYAL SOC CHEMISTRY published article about in [Li, Yan; Pan, Chengsi; Wang, Guangli; Leng, Yan; Jiang, Pingping; Dong, Yuming] Jiangnan Univ, Int Joint Res Ctr Photorespons Mol & Mat, Sch Chem & Mat Engn, Wuxi 214122, Jiangsu, Peoples R China; [Zhu, Yongfa] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Until now, the effective photocatalytic oxidation of benzyl alcohol to benzaldehyde with high selectivity is still a great challenge. It is reported that the carrier separation rate is the key factor affecting the photocatalytic activity, and the formation of heterojunction is an effective solution to hinder electron-hole recombination. SnS with a narrow band gap has excellent light absorption performance, which covers the whole visible light region. After compounding with g-C3N4, the light utilization of the SnS/g-C3N4 photocatalyst is effectively improved. In addition, a Z-scheme heterojunction is formed between SnS and g-C3N4 due to the matched energy levels, which accelerates the separation of electrons and holes and improves the conversion of benzyl alcohol effectively. In this paper, the charge separation is accelerated to promote the reaction by the in situ construction of Z-scheme heterojunctions; the preparation method, reaction mechanism and energy level structure of the photocatalyst can play a certain guiding role in the organic conversion reaction.

Welcome to talk about 105-13-5, If you have any questions, you can contact Li, Y; Pan, CS; Wang, GL; Leng, Y; Jiang, PP; Dong, YM; Zhu, YF or send Email.. Recommanded Product: (4-Methoxyphenyl)methanol

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In 2021 CHEM-EUR J published article about ENANTIOSELECTIVE AMINOLYSIS; PHARMACOLOGICAL-ACTIVITY; PYRROLIDINE DERIVATIVES; CYCLOPEPTIDE ALKALOIDS; 2,3-EPOXY ALCOHOLS; AEROBIC OXIDATION; ANTIFUNGAL AGENT; STEREOCHEMISTRY; ENTRY in [Kuriyama, Yuse; Sasano, Yusuke; Hoshino, Yoshihiko; Uesugi, Shun-ichiro; Yamaichi, Aoto; Iwabuchi, Yoshiharu] Tohoku Univ, Dept Organ Chem, Grad Sch Pharmaceut Sci, Aoba Ku, 6-3 Aoba, Sendai, Miyagi 9808578, Japan in 2021, Cited 38. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Product Details of 105-13-5

Highly regioselective intramolecular aminolysis of 3,4-epoxy amines has been achieved. Key features of this reaction are (1) chemoselective activation of epoxides in the presence of unprotected aliphatic amines in the same molecules by a La(OTf)(3) catalyst and (2) excellent regioselectivity for anti-Baldwin 5-endo-tet cyclization. This reaction affords 3-hydroxy-2-alkylpyrrolidines stereospecifically in high yields. DFT calculations revealed that the regioselectivity might be attributed to distortion energies of epoxy amine substrates. The use of this reaction was demonstrated by the first enantioselective synthesis of an antispasmodic agent prifinium bromide.

Product Details of 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Kuriyama, Y; Sasano, Y; Hoshino, Y; Uesugi, S; Yamaichi, A; Iwabuchi, Y or send Email.

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