Category: 100-55-0

《Palladium-Catalyzed Electrophilic Functionalization of Pyridine Derivatives through Phosphonium Salts》 was written by Che, Yuan-Yuan; Yue, Yanni; Lin, Ling-Zhi; Pei, Bingbing; Deng, Xuezu; Feng, Chao. Application In Synthesis of 3-Pyridinemethanol And the article was included in Angewandte Chemie, International Edition in 2020. The article conveys some information:

Herein, we report a highly efficient and practical method for pyridine-derived heterobiaryl synthesis through palladium-catalyzed electrophilic functionalization of easily available pyridine-derived quaternary phosphonium salts. The nice generality of this reaction was goes beyond arylation, enabling facile incorporation of diverse carbon-based fragments, including alkenyl, alkynyl, and also allyl fragments, onto the pyridine core. Notably, the silver salt additive is revealed to be of vital importance for the success of this transformation and its pivotal role as transmetallation mediator, which guarantees a smooth transfer of pyridyl group to palladium intermediate, is also described. In the experiment, the researchers used 3-Pyridinemethanol(cas: 100-55-0Application In Synthesis of 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridines form stable salts with strong acids. Pyridine itself is often used to neutralize acid formed in a reaction and as a basic solvent. Application In Synthesis of 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Name: 3-PyridinemethanolIn 2019 ,《Uniform silver nanoparticles on tunable porous N-doped carbon nanospheres for aerobic oxidative synthesis of aryl nitriles from benzylic alcohols》 was published in Applied Organometallic Chemistry. The article was written by Hashemi, Alireza Nemati; Eshghi, Hossein; Lamei, Kamran. The article contains the following contents:

Tunable N-doped carbon nanospheres were prepared from sucrose as carbon source and tris(2-aminoethyl)amine (TAEA) as nitrogen source by a simple and easily reproducible method. It was demonstrated that the tunable N-doping of carbon spheres could be realized by altering the ratio of TAEA in the raw materials. The content of doped nitrogen, surface area, pore volume and pore size of carbon nanospheres were increased with the increasing of TAEA amount in the hydrothermal process. Prepared N-doped carbon nanospheres acted as solid ligand for anchoring of Ag NPs which was generated via chem. reduction of Ag ions. Benzylic alcs. and aldehydes were converted into the aryl nitriles R-CN [R = Ph, 3-pyridyl, 3-HOC6H4, etc.] by using Ag/N-CS-1 nanospheres as the catalyst and O2 as the oxidant, efficiently. This catalyst was stable and could use for 6 successful runs. The experimental process involved the reaction of 3-Pyridinemethanol(cas: 100-55-0Name: 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridines, quinolines, and isoquinolines have found a function in almost all aspects of organic chemistry. Pyridine has found use as a solvent, base, ligand, functional group, and molecular scaffold. As structural elements, these moieties are potent electron-deficient groups, metal-directing functionalities, fluorophores, and medicinally important pharmacophores. Name: 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

The author of 《Palladium oxide nanoparticles intercalated mesoporous silica for solvent free acceptorless dehydrogenation reactions of alcohols》 were Samanta, Partha Kumar; Ray, Shounak; Das, Trisha; Gage, Samuel H.; Nandi, Mahasweta; Richards, Ryan M.; Biswas, Papu. And the article was published in Microporous and Mesoporous Materials in 2019. Product Details of 100-55-0 The author mentioned the following in the article:

Aggregation-free well-dispersed palladium oxide nanoparticles intercalated into the walls of mesoporous silica (PdOMS) were prepared by using thioether groups during the sol-gel preparation of mesoporous silica. The PdOMS material was characterized by N2 adsorption-desorption, X-ray diffraction, SEM, transmission electron microscopy and UV-Vis spectroscopy. The material retains mesoporous structure with narrow pore size distribution with an average pore diameter of 6.8 nm and possesses high surface area of 683 m2g-1. The PdOMS catalyst was employed as an efficient heterogeneous catalyst in the acceptor- and oxidant-free dehydrogenation of neat alcs. to corresponding carbonyl compounds in very good to excellent yields (72-95%) at 80° under inert atm. The catalytic efficacy of PdOMS was evaluated for the acceptorless dehydrogenative coupling reactions of alcs. with o-diamino benzene and o-amino phenol to yield azole-based heterocycles. The stability of PdOMS was assessed by investigating its recyclability and reusability in the dehydrogenation of neat alc. for up to five cycles. After reading the article, we found that the author used 3-Pyridinemethanol(cas: 100-55-0Product Details of 100-55-0)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine derivatives lend themselves to many roles in the spirited field of supramolecular chemistry – whether as the ligand backbone of metal-organic polymers or presiding over the key electronic stations of nanodevices. In biochemistry, pyridine-containing cofactors are necessary nutrients on which our lives depend. Product Details of 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Theoretical Infrared Spectra: Quantitative Similarity Measures and Force Fields》 was written by Henschel, Henning; Andersson, Alfred T.; Jespers, Willem; Mehdi Ghahremanpour, Mohammad; van der Spoel, David. Computed Properties of C6H7NO And the article was included in Journal of Chemical Theory and Computation in 2020. The article conveys some information:

IR spectroscopy can provide significant insight into the structures and dynamics of mols. of all sizes. The information that is contained in the spectrum is, however, often not easily extracted without the aid of theor. calculations or simulations. We present here the calculation of the IR spectra of a database of 703 gas phase compounds with four different force fields (CGenFF, GAFF-BCC, GAFF-ESP, and OPLS) using normal-mode anal. Modern force fields increasingly use virtual sites to describe, e.g., lone-pair electrons or the σ-holes on halogen atoms. This requires some adaptation of code to perform normal-mode anal. of such compounds,the implementation of which into the GROMACS software is briefly described as well. For the quant. comparison of the obtained spectra with exptl. reference data, we discuss the application of two different statistical correlation coefficients, Pearson and Spearman. The advantages and drawbacks of the different methods of comparison are discussed, and we find that both methods of comparison give the same overall picture, showing that present force field methods cannot match the performance of quantum chem. methods for the calculation of IR spectra. In addition to this study using 3-Pyridinemethanol, there are many other studies that have used 3-Pyridinemethanol(cas: 100-55-0Computed Properties of C6H7NO) was used in this study.

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is a relatively complex molecule and exhibits a number of different bands in IR spectra. Among others, the bands characterizing the ν8a and ν19b modes have been found to be sensitive to the coordination or protonation of the molecule. Note that the band that is diagnostic for the PyH+ ion at about 1545 cm− 1 (ν19b mode) does not overlap with any of the other bands.Computed Properties of C6H7NO

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Chemical Communications (Cambridge, United Kingdom) included an article by Tang, Jun; Cao, Shixiong; Wang, Jianli. Recommanded Product: 100-55-0. The article was titled 《CO2-switchable Pickering emulsions: efficient and tunable interfacial catalysis for alcohol oxidation in biphasic systems》. The information in the text is summarized as follows:

CO2-responsive Pickering emulsions were fabricated on the basis of polymeric nanoaggregates with adjustable surface wettability. The static Pickering emulsion system provides an efficient and sustainable platform for in situ separation and reuse of catalysts in biphasic reactions. The experimental process involved the reaction of 3-Pyridinemethanol(cas: 100-55-0Recommanded Product: 100-55-0)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridines are often used as catalysts or reagents; particular notice has been paid recently to how pyridine coordinates to metal centers enabling a wide range of valuable reactions. Recommanded Product: 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

SDS of cas: 100-55-0In 2021 ,《Synthesis of bioactive quinoline acting as anticancer agents and their mode of action using in silico analysis towards Aurora kinase A inhibitors》 appeared in Chemical Data Collections. The author of the article were Narasimhamurthy, Kereyagalahally H.; Guruswamy, Dileep Kumar M.; Chandra; Kallesha, Nichhapurada; Basappa; Rangappa, Kanchugarakoppal S.. The article conveys some information:

In the present investigation, novel quinolines have been synthesized and analyzed for their invitro cytotoxic activity against human colon cancer and lung cancer cells. Among the newly synthesized quinoline derivatives, 2-(3-chlorophenyl)-6,7-dimethoxyquinoline (Q6) showed considerable cytotoxic activity against human colon cancer (HCT116) and lung cancer (A549) cell lines with IC50 values of 25.5 ± 2.7 and 32 ± 4.7 μM resp. Since these quinolines interacted with an Aurora kinase A, we carried out the mol. docking investigation and observed that this quinoline displayed inhibitory potentials. Overall, the compound Q6 was well suited to develop a newer quinolines-based anticancer medication, especially to block cell cycle arrest through Aurora kinase A inhibitors in human cancer.3-Pyridinemethanol(cas: 100-55-0SDS of cas: 100-55-0) was used in this study.

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine and pyridine-derived structures are privileged pharmacophores in medicinal chemistry and an essential functionality for organic chemists. As the prototypical π-deficient heterocycle, pyridine illustrates distinctive chemistry as both substrate and reagent. SDS of cas: 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Jana, Akash; Kumar, Amol; Maji, Biplab published their research in Chemical Communications (Cambridge, United Kingdom) in 2021. The article was titled 《Manganese catalyzed C-alkylation of methyl N-heteroarenes with primary alcohols》.Reference of 3-Pyridinemethanol The article contains the following contents:

C-Alkylations of nine different classes of methyl-substituted N-heteroarenes including quinolines, quinoxalines, benzimidazoles, benzoxazoles, pyrazines, pyrimidines, pyridazines, pyridines, and triazines were disclosed. A bench stable earth-abundant Mn(I)-complex catalyzed the chemoselective hydrogen-transfer reaction utilizing a diverse range of primary alcs. as the non-fossil fuel-derived carbon source. The diversified N-heteroarenes were isolated in high yields and selectivities. Water was produced as the sole byproduct, making the protocol environmentally benign. After reading the article, we found that the author used 3-Pyridinemethanol(cas: 100-55-0Reference of 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.Reference of 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Quality Control of 3-PyridinemethanolIn 2019 ,《Room temperature N-heterocyclic carbene manganese catalyzed selective N-alkylation of anilines with alcohols》 was published in Chemical Communications (Cambridge, United Kingdom). The article was written by Huang, Ming; Li, Yukui; Li, Yinwu; Liu, Jiahao; Shu, Siwei; Liu, Yan; Ke, Zhuofeng. The article contains the following contents:

The first example of room temperature non-noble metal homogeneous system catalyzed selective N-alkylation of anilines with alcs. by a bis-NHC manganese complex is presented. This system was applied to a large range of alcs. and anilines, including biol. relevant motifs and challenging methanol. Exptl. and computational studies suggest an outer-sphere mechanism for this NHC-Mn system. The experimental process involved the reaction of 3-Pyridinemethanol(cas: 100-55-0Quality Control of 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine and pyridine-derived structures are privileged pharmacophores in medicinal chemistry and an essential functionality for organic chemists. As the prototypical π-deficient heterocycle, pyridine illustrates distinctive chemistry as both substrate and reagent. Quality Control of 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Selective photocatalytic oxidation of glycerol and 3-pyridinemethanol by nanotube/nanowire-structured TiO2 powders obtained by breakdown anodization》 was written by Cetinkaya, Sidika; Khamidov, Gofur; Ozcan, Levent; Palmisano, Leonardo; Yurdakal, Sedat. Category: alcohols-buliding-blocksThis research focused ontitanium dioxide glycerol pyridinemethanol nanotube nanowire photocatalytic oxidation; 3-pyridinemethanol; glycerol; green synthesis; heterogeneous photocatalysis; nanotube structured TiO2; selective oxidation; vitamin B3. The article conveys some information:

Nanotube/nanowire-structured TiO2 was formed on the Ti surface by an anodic oxidation method performed at different potential values (50 or 60 V) and for different times (3 or 5 h). The TiO2 photocatalysts were taken in powder form using the ultrasonic treatment from the Ti electrodes, calcined at different temperatures, and characterized by XRD and SEM techniques, and BET surface area analyses. Both the crystallinity and the size of the primary TiO2 particles increased by increasing the heat treatment temperature While all the photocatalysts heat treated up to 500°C were only in the anatase phase, the particles heat-treated at 700°C consisted of both anatase and rutile phases. The BET sp. surface area of the samples decreased drastically after heat treatment of 700°C because of partial sinterization. SEM analyses indicated that the prepared materials were structured in both nanotubes and nanowires. They were tested as photocatalysts for the selective oxidation of glycerol and 3-pyridinemethanol under UVA irradiation in water at room temperature and ambient pressure. Glyceraldehyde, 1,3-dihydroxyacetone, and formic acid were determined as products in glycerol oxidation, while the products of 3-pyridinemethanol oxidation were 3-pyridinemethanal and vitamin B3. Non-nanotube/nanowire-structured com. (Degussa P25 and Merck TiO2) photocatalysts were used for the sake of comparison. Low selectivity values towards the products obtained by partial oxidation were determined for glycerol. On the contrary, higher selectivity values towards the products were obtained (total 3-pyridinemethanal and vitamin B3 selectivity up to ca. 90%) for the photocatalytic oxidation of 3-pyridinemethanol. TiO2 photocatalysts must be highly crystalline (calcined at 700°C) for effective oxidation of glycerol, while for the selective oxidation of 3-pyridinemethanol it was not necessary to obtain a high crystallinity, and the optimal heat treatment temperature was 250°C. Glycerol and its oxidation products could more easily desorb from highly crystalline and less hydroxylated surfaces, which would justifies their higher activity. The prepared photocatalysts showed lower activity than Degussa P25, but a greater selectivity towards the products found. In the part of experimental materials, we found many familiar compounds, such as 3-Pyridinemethanol(cas: 100-55-0Category: alcohols-buliding-blocks)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridines, quinolines, and isoquinolines have found a function in almost all aspects of organic chemistry. Pyridine has found use as a solvent, base, ligand, functional group, and molecular scaffold. As structural elements, these moieties are potent electron-deficient groups, metal-directing functionalities, fluorophores, and medicinally important pharmacophores. Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Intermaggio, Nicholas E.; Millet, Agustin; Davis, Dali L.; MacMillan, David W. C. published an article in 2022. The article was titled 《Deoxytrifluoromethylation of Alcohols》, and you may find the article in Journal of the American Chemical Society.Product Details of 100-55-0 The information in the text is summarized as follows:

Deoxy-functionalization of alcs. represents a class of reactions that has had profound impact on modern medicine. In particular, deoxyfluorination is commonly employed as a means to incorporate high-value fluorine atoms into drug-like mols. Recently, the trifluoromethyl (CF3) group has garnered attention from medicinal chemists due to its ability to markedly improve the pharmaceutical properties of small mol. drug candidates. To date, however, there remains no general means to accomplish the analogous deoxygenative trifluoromethylation of alcs. Herein, a copper metallaphotoredox-mediated direct deoxytrifluoromethylation is reported, wherein alc. substrates are activated in situ by benzoxazolium salts for C(sp3)-CF3 bond formation. The experimental part of the paper was very detailed, including the reaction process of 3-Pyridinemethanol(cas: 100-55-0Product Details of 100-55-0)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.Product Details of 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts