Category: 100-55-0

《A facile and highly efficient transfer hydrogenation of ketones and aldehydes catalyzed by palladium nanoparticles supported on mesoporous graphitic carbon nitride》 was published in Journal of Chemical Research in 2020. These research results belong to Nisanci, Bilal; Dagalan, Ziya. Application In Synthesis of 3-Pyridinemethanol The article mentions the following:

A novel transfer hydrogenation methodol. for the reduction of ketones (14 examples) and benzaldehyde derivatives (12 examples) to the corresponding alcs. using Pd nanoparticles supported on mesoporous graphitic carbon nitride (mpg-C3N4/Pd) as a reusable catalyst and ammonia borane as a safe hydrogen source in an aqueous solution MeOH/H2O (volume/volume = 1/1) was described. The catalytic hydrogenation reactions were conducted in a com. available high-pressure glass tube at room temperature and the corresponding alcs. were obtained in high yields in 2-5 min. Moreover, the presented transfer hydrogenation protocol showed partial halogen selectivity with bromo-, fluoro- and chloro-substituted carbonyl analogs. In addition, the present catalyst can be reused up to five times without losing its efficiency and scaling-up the reaction enabled α-methylbenzyl alc. to be produced in 90% isolated yield. In the experimental materials used by the author, we found 3-Pyridinemethanol(cas: 100-55-0Application In Synthesis of 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridines are often used as catalysts or reagents; particular notice has been paid recently to how pyridine coordinates to metal centers enabling a wide range of valuable reactions. Application In Synthesis of 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Zhao, Fengqian; Ai, Han-Jun; Wu, Xiao-Feng published an article in 2021. The article was titled 《Radical Carbonylation under Low CO Pressure: Synthesis of Esters from Activated Alkylamines at Transition Metal-Free Conditions》, and you may find the article in Chinese Journal of Chemistry.Product Details of 100-55-0 The information in the text is summarized as follows:

High CO pressure (> 40 bar) is usually needed in radical carbonylation reactions in the absence of metal catalyst. In this communication, a transition-metal-free radical carbonylation of activated alkylamines with phenols and alcs. under low CO pressure (1-6 bar) was developed. Various esters were obtained in moderate to excellent yields under simple reaction conditions with good functional group compatibility. After reading the article, we found that the author used 3-Pyridinemethanol(cas: 100-55-0Product Details of 100-55-0)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is very deactivated towards electrophilic substitution with respect to benzene. For this reason classical formylation, using methods such as the Gattermann or Vilsmeier reactions, are not generally successful. Product Details of 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Category: alcohols-buliding-blocksIn 2020 ,《Selective oxidation of alcohols by porphyrin-based porous polymer-supported manganese heterogeneous catalysts》 appeared in Applied Organometallic Chemistry. The author of the article were Chen, Jian; Zhang, Yan; Zhu, Dajian; Li, Tao. The article conveys some information:

A series of porphyrin-based porous polymers to support Mn heterogeneous catalysts (Mn/TFP-DPM, Mn/TFP-DPM-2, Mn/TFP-DPM-3, and Mn/TFP-DPM-4) (TFP-DPM is a copolymer of 1,3,5-triformylphloroglucinol and 2,2′-dipyrrolylmethane) in the selective oxidation of alcs. was designed and synthesized. TFP-DPM and TFP-DPM-2 demonstrated micro/nanoscale spherical morphol., whereas TFP-DPM-3 and TFP-DPM-4 exhibited nanosheets structure. According to surface area and porosity anal. results, the sp. surface areas of these catalysts were less than 300 m2 g-1. Thermogravimetric anal. indicated that the synthesized catalysts maintain their stability even at 300°C. Catalysts Mn/TFP-DPM and Mn/TFP-DPM-3, which had the smallest and largest sp. surface area among the four catalysts, resp., were used to perform selective oxidation reaction of alcs., with exptl. results indicating that both have excellent catalytic performance. These catalysts possess good catalytic performance despite their low sp. surface area, suggesting that porphyrin-based porous polymer-supported Mn heterogeneous catalysts are promising materials for selective oxidation of alcs. The results came from multiple reactions, including the reaction of 3-Pyridinemethanol(cas: 100-55-0Category: alcohols-buliding-blocks)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine derivatives lend themselves to many roles in the spirited field of supramolecular chemistry – whether as the ligand backbone of metal-organic polymers or presiding over the key electronic stations of nanodevices. In biochemistry, pyridine-containing cofactors are necessary nutrients on which our lives depend. Category: alcohols-buliding-blocks

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Direct oxidation of alcohols catalysed by heterometallic complex [CuNi(bz)3(bpy)2]ClO4 to aldehydes and ketones mediated by hydrogen peroxide as a terminal oxidant》 was published in Inorganica Chimica Acta in 2020. These research results belong to Asthana, Mrityunjaya; Syiemlieh, Ibanphylla; Kumar, Arvind; Lal, Ram A.. Reference of 3-Pyridinemethanol The article mentions the following:

A ligand and additive-free [CuNi(bz)3(bpy)2]ClO4 catalyst system that efficiently and selectively catalyzed the oxidation of a range of primary and secondary benzylic alcs., 1-heteroaryl alcs., cinnamyl alc. and aliphatic alcs. mediated by hydrogen peroxide to the corresponding aldehydes and ketones, resp. In the experimental materials used by the author, we found 3-Pyridinemethanol(cas: 100-55-0Reference of 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.Reference of 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Yadav, Vinita; Balaraman, Ekambaram; Mhaske, Santosh B. published an article in 2021. The article was titled 《Phosphine-Free Manganese(II)-Catalyst Enables Acceptorless Dehydrogenative Coupling of Alcohols with Indoles》, and you may find the article in Advanced Synthesis & Catalysis.Related Products of 100-55-0 The information in the text is summarized as follows:

Herein, an air-stable, molecularly defined NNN-Mn(II) pincer complex catalyzed acceptorless dehydrogenative coupling of alcs. with indoles is reported [e.g., 4-isopropylbenzyl alc. + indole → I (96%)]. A wide variety of sym. and unsym. bis(indolyl)methane derivatives as well as some structurally important products such as vibrindole A, turbomycin B alkaloid, antileukemic, and anticancer agents were synthesized. Mechanistic studies illustrate the importance of the NH moiety in the complex and the crucial role of metal-ligand cooperation during catalysis.3-Pyridinemethanol(cas: 100-55-0Related Products of 100-55-0) was used in this study.

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is a relatively complex molecule and exhibits a number of different bands in IR spectra. Among others, the bands characterizing the ν8a and ν19b modes have been found to be sensitive to the coordination or protonation of the molecule. Note that the band that is diagnostic for the PyH+ ion at about 1545 cm− 1 (ν19b mode) does not overlap with any of the other bands.Related Products of 100-55-0

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Cyclometalated Ruthenium Pincer Complexes as Catalysts for the α-Alkylation of Ketones with Alcohols》 was published in Chemistry – A European Journal in 2020. These research results belong to Piehl, Patrick; Amuso, Roberta; Alberico, Elisabetta; Junge, Henrik; Gabriele, Bartolo; Neumann, Helfried; Beller, Matthias. Related Products of 100-55-0 The article mentions the following:

Ruthenium PNP pincer complexes bearing supplementary cyclometalated C,N-bound ligands have been prepared and fully characterized for the first time. By replacing CO and H- as ancillary ligands in such complexes, addnl. electronic and steric modifications of this topical class of catalysts are possible. The advantages of the new catalysts are demonstrated in the general α-alkylation of ketones with alcs. following a hydrogen autotransfer protocol. Herein, various aliphatic and benzylic alcs. were applied as green alkylating agents for ketones bearing aromatic, heteroaromatic or aliphatic substituents as well as cyclic ones. Mechanistic investigations revealed that during catalysis, Ru carboxylate complexes are predominantly formed whereas neither the PNP nor the CN ligand are released from the catalyst in significant amounts In the experimental materials used by the author, we found 3-Pyridinemethanol(cas: 100-55-0Related Products of 100-55-0)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is very deactivated towards electrophilic substitution with respect to benzene. For this reason classical formylation, using methods such as the Gattermann or Vilsmeier reactions, are not generally successful. Related Products of 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Iron-Catalyzed Direct Julia-Type Olefination of Alcohols》 was written by Landge, Vinod G.; Babu, Reshma; Yadav, Vinita; Subaramanian, Murugan; Gupta, Virendrakumar; Balaraman, Ekambaram. Synthetic Route of C6H7NO And the article was included in Journal of Organic Chemistry in 2020. The article conveys some information:

Herein, we report an iron-catalyzed, convenient, and expedient strategy for the synthesis of styrene and naphthalene derivatives with the liberation of dihydrogen. The use of a catalyst derived from an earth-abundant metal provides a sustainable strategy to olefins. This method exhibits wide substrate scope (primary and secondary alcs.) functional group tolerance (amino, nitro, halo, alkoxy, thiomethoxy, and S- and N-heterocyclic compounds) that can be scaled up. The unprecedented synthesis of 1-Me naphthalenes proceeds via tandem methenylation/double dehydrogenation. Mechanistic study shows that the cleavage of the C-H bond of alc. is the rate-determining step. The experimental part of the paper was very detailed, including the reaction process of 3-Pyridinemethanol(cas: 100-55-0Synthetic Route of C6H7NO)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is a relatively complex molecule and exhibits a number of different bands in IR spectra. Among others, the bands characterizing the ν8a and ν19b modes have been found to be sensitive to the coordination or protonation of the molecule. Note that the band that is diagnostic for the PyH+ ion at about 1545 cm− 1 (ν19b mode) does not overlap with any of the other bands.Synthetic Route of C6H7NO

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Journal of Catalysis included an article by Thiruvengetam, Prabaharan; Chakravarthy, Rajan Deepan; Chand, Dillip Kumar. Application of 100-55-0. The article was titled 《A molybdenum based metallomicellar catalyst for controlled and chemoselective oxidation of activated alcohols in aqueous medium》. The information in the text is summarized as follows:

A surfactant based oxodiperoxo molybdenum complex, which could activate mol. oxygen, has been employed as a catalyst for controlled oxidation of benzylic alcs. to corresponding carbonyls I (R = 4-OMe, 3-Br, 4-NMe2, etc.) and II (R = 4-NO2, 4-SMe, 4-allyloxy, etc.; R’ = Me, Et, Ph, etc.). The oxidation reactions were carried out under aqueous environment, however, in the absence of any extraneous base or co-catalyst. Sensitive/oxidizable functional groups like cyano, sulfide, hydroxyl, aryl-hydroxyl, alkene (internal/terminal), alkyne (internal/terminal), and acetal were tolerated during the transformations. Such selectivity is attributed to the mild nature of the catalyst. The methodol. could also be scaled-up for multi-gram synthesis and the protocol is likely to find practical use since it requires an inexpensive recyclable-catalyst and easily available oxidant (under green conditions). A plausible mechanism is proposed with the help of preliminary computational study. The experimental process involved the reaction of 3-Pyridinemethanol(cas: 100-55-0Application of 100-55-0)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.Application of 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Photoelectrocatalytic oxidation of 3-pyridinemethanol to 3-pyridinemethanal and vitamin B3 by TiO2 nanotubes》 was written by Yurdakal, Sedat; Cetinkaya, Sidika; Sarlak, Muhsine Beyza; Ozcan, Levent; Loddo, Vittorio; Palmisano, Leonardo. Reference of 3-Pyridinemethanol And the article was included in Catalysis Science & Technology in 2020. The article conveys some information:

In this paper, the first photoelectrocatalytic (PEC) 3-pyridinemethanol oxidation to 3-pyridinemethanal and vitamin B3 was investigated. To meet this aim, efficient nanotube structured TiO2 on a Ti plate as a photoanode was prepared by an anodic oxidation method in ethylene glycol and characterized by XRD, SEM, and photocurrent techniques. The effect of nanotube morphol., applied potential, Na2SO4 concentration, stirring speed of solution, and pH on the reaction activity and product selectivities were investigated. The TiO2 phase of all of the anodes was mainly the anatase one. The PEC activity, the intensity of the XRD peak and the photocurrent increased by increasing the nanotube length. The activity decreased by decreasing both the Na2SO4 concentration and the applied potential, whereas 3-pyridinemethanal selectivity increased. By increasing the stirring speed of the solution, both the activity and the 3-pyridinemethanal selectivity increased. A lower or no activity was observed for photocatalytic (PC) and electrocatalytic runs, resp., which were carried out for the sake of comparison. No PC activity was obtained in the presence of N2, but PEC reactions in the presence of N2 were faster than those in the presence of O2. The produced 3-pyridinemethanal in both N2 and O2 atmosphere was reduced at the cathode in the PEC reaction, but its oxidation appeared to be much more favorable. The PC reactions could not be carried out under acidic conditions, while the PEC ones could be performed in the pH range of 2-12. Moreover, the results indicate that the PEC method allows higher conversions and selectivities to vitamin B3 to be obtained at pH 7 with respect to those reported in the literature. In the experiment, the researchers used many compounds, for example, 3-Pyridinemethanol(cas: 100-55-0Reference of 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine derivatives lend themselves to many roles in the spirited field of supramolecular chemistry – whether as the ligand backbone of metal-organic polymers or presiding over the key electronic stations of nanodevices. In biochemistry, pyridine-containing cofactors are necessary nutrients on which our lives depend. Reference of 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Name: 3-PyridinemethanolIn 2022 ,《Reductive Alkylation of Azides and Nitroarenes with Alcohols: A Selective Route to Mono- and Dialkylated Amines》 appeared in Journal of Organic Chemistry. The author of the article were Borthakur, Ishani; Maji, Milan; Joshi, Abhisek; Kundu, Sabuj. The article conveys some information:

Herein, we demonstrated an efficient protocol for reductive alkylation of azides/nitro compounds via a borrowing hydrogen (BH) method. By following this protocol, selective mono- and dialkylated amines were obtained under mild and solvent-free conditions. A series of control experiments and deuterium-labeling experiments were performed to understand this catalytic process. Mechanistic studies suggested that the Ir(III)-H was the active intermediate in this reaction. KIE study revealed that the breaking of the C-H bond of alc. might be the rate-limiting step. Notably, this solvent-free strategy disclosed a high TON of around 5600. Based on kinetic studies and control experiments, a metal-ligand cooperative mechanism was proposed. The results came from multiple reactions, including the reaction of 3-Pyridinemethanol(cas: 100-55-0Name: 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine and pyridine-derived structures are privileged pharmacophores in medicinal chemistry and an essential functionality for organic chemists. As the prototypical π-deficient heterocycle, pyridine illustrates distinctive chemistry as both substrate and reagent. Name: 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts