Author: tianli

COA of Formula: C8H10O2. Authors Xia, YY; Lv, QY; Yuan, H; Wang, JY in SPRINGER INTERNATIONAL PUBLISHING AG published article about in [Xia, Yu-Yan; Lv, Qing-Yang; Yuan, Hua; Wang, Jia-Yi] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430073, Peoples R China in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

An efficient method for catalyzing the ammoxidation of aromatic alcohols to aromatic nitriles was developed, in which a new heterogeneous catalyst based on transition metal elements was employed, the new catalyst was named Co-[Bmim]Br/C-700 and then characterized by X-ray photo-electronic spectroscopy, transmission electron microscope and X-ray diffraction. The reaction was carried out by two consecutive dehydrogenations under the catalysis of Co-[Bmim]Br/C-700, which catalytically oxidized the alcohol to the aldehyde, and then the aldehyde was subjected to ammoxidation to the nitrile. The catalyst system was suitable for a wide range of substrates and nitriles obtained in high yields, especially, the conversion rate of benzyl alcohol, 4-methoxybenzyl alcohol, 4-chlorobenzyl alcohol and 4-nitrobenzyl alcohol reached 100%. The substitution of ammonia and oxygen for toxic cyanide to participate in the reaction accords with the theory of green chemistry.

COA of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Xia, YY; Lv, QY; Yuan, H; Wang, JY or concate me.

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An article Palladium(II) N boolean AND O Chelating Complexes Catalyzed One-Pot Approach for Synthesis of Quinazolin-4(3H)-ones via Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and 2-Aminobenzamide WOS:000636740800011 published article about AEROBIC OXIDATIVE SYNTHESIS; CASCADE SYNTHESIS; QUINAZOLINONES; LIGANDS; FUNCTIONALIZATION; AMINOBENZAMIDES; BENZIMIDAZOLES; HYDROPEROXIDE; HETEROCYCLES; CHEMISTRY in [Balaji, Sundarraman; Balamurugan, Gunasekaran; Ramesh, Rengan] Bharathidasan Univ, Ctr Organometall Chem, Sch Chem, Tiruchirappalli 620024, Tamil Nadu, India; [Semeril, David] Univ Strasbourg, Inst Chim, Lab Chim Inorgan & Catalyse, UMR 7177,CNRS, F-67070 Strasbourg, France in 2021, Cited 78. Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A convenient protocol for the one-pot synthesis of quinazolin-4(3H)-ones using palladium(II) complexes via dehydrogenative coupling of readily available benzyl alcohols and 2-aminobenzamide has been described. New structurally related Pd(II) N boolean AND O chelating complexes of general configuration [Pd(L)Cl(PPh3)] (where L = dimethylamino benzoylhydrazone ligands) have been designed and synthesized. The formation of the complexes has been recognized by analytical and spectral methods (FT-IR, NMR, HR-MS). The presence of a square-planar geometry around the palladium(II) ion was confirmed by single crystal X-ray diffraction study. A wide range of substituted quinazolinones have been successfully achieved from a diverse range of benzyl alcohols in good to excellent yields using 1.0 mol % of catalyst loading under aerobic conditions. Furthermore, control experiments reveal that the dehydrogenative coupling reaction involves initially the formation of an aldehyde intermediate and subsequent formation of a cyclic aminal intermediate.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Balaji, S; Balamurugan, G; Ramesh, R; Semeril, D or concate me.. Formula: C8H10O2

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An article Iron-Catalyzed Hydrogen Transfer Reduction of Nitroarenes with Alcohols: Synthesis of Imines and Aza Heterocycles WOS:000606840200084 published article about ONE-POT SYNTHESIS; BORROWING HYDROGEN; 2-SUBSTITUTED BENZIMIDAZOLES; TRANSITION-METAL; N-ALKYLATION; SELECTIVE HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; QUINOXALINE DERIVATIVES; SWITCHABLE SYNTHESIS; AROMATIC DIAMINES in [Wu, Jiajun; Darcel, Christophe] Univ Rennes, CNRS ISCR, Inst Sci Chim Rennes, UMR 6226, F-35000 Rennes, France in 2021, Cited 137. COA of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A straightforward and selective reduction of nitroarenes with various alcohols was efficiently developed using an iron catalyst via a hydrogen transfer methodology. This protocol led specifically to imines in 30-91% yields, with a good functional group tolerance. Noticeably, starting from o-nitroaniline derivatives, in the presence of alcohols, benzimidazoles can be obtained in 64-72% yields when the reaction was performed with an additional oxidant, DDQ, and quinoxalines were prepared from 1,2-diols in 28-96% yields. This methodology, unprecedented at iron for imines, also provides a sustainable alternative for the preparation of quinoxalines and benzimidazoles.

COA of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wu, JJ; Darcel, C or concate me.

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Quality Control of (4-Methoxyphenyl)methanol. In 2021 J CHEM TECHNOL BIOT published article about AROMATIC ALCOHOLS; MULTICOMPONENT SYNTHESIS; TIO2 NANOPARTICLES; AEROBIC OXIDATION; TITANIUM-DIOXIDE; IONIC LIQUIDS; METAL-OXIDES; EFFICIENT; ALDEHYDES; DEGRADATION in [Taghavi, Shaghayegh; Amoozadeh, Ali; Nemati, Firouzeh] Semnan Univ, Fac Chem, Dept Organ Chem, Semnan 3513119111, Iran in 2021, Cited 76. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

BACKGROUND Deep eutectic solvents (DESs) are prepared by mixing solid organic precursors to form a liquid driven from strong hydrogen-bond interactions. The physical and chemical properties of these compounds have been widely investigated, and it has been shown that they are benign media for biotransformations, organicsynthesis, biodieselpreparation, and a sustainable media for nanoscale and functional materials. RESULTS This study is the first report on the synthesis of n-TiO2-P25@TDI@DES (urea: ZnCl2) with photo catalytic activity. This nano photocatalyst was obtained through covalent grafting of TiO2-P25 nanoparticles to an inexpensive and highly reactive linker (2,4-toluene diisocyanate). The presented nano photocatalyst has been employed as a covalently grafted Lewis acidic deep eutectic solvent to oxidize various primary benzyl alcohols to their corresponding carbonyl compounds by sodium nitrate as oxidant, under visible light exposure. CONCLUSION This highly efficient nanocatalyst was investigated by various characterization techniques including fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy (SEM with EDX), and elemental analysis. Owing to its enhanced catalytic activity, thermal stability, and environmentally friendly nature, the present method can be regarded as an attractive green chemistry approach. (c) 2020 Society of Chemical Industry (SCI)

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An article Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis WOS:000661138500021 published article about ALCOHOLS; OLEFINATION; ARYLACETONITRILES; ALKYLATION in [Midya, Siba P.; Subaramanian, Murugan; Babu, Reshma; Balaraman, Ekambaram] Indian Inst Sci Educ & Res IISER Tirupati, Dept Chem, Tirupati 517507, Andhra Pradesh, India; [Yadav, Vinita] CSIR Natl Chem Lab CSIR NCL, Organ Chem Div, Pune 411008, Maharashtra, India in 2021, Cited 55. Computed Properties of C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Midya, SP; Subaramanian, M; Babu, R; Yadav, V; Balaraman, E or concate me.. Computed Properties of C8H10O2

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An article Ultrasmall amphiphilic zeolitic nanoreactors for the aerobic oxidation of alcohols in water WOS:000649428200001 published article about METAL-ORGANIC FRAMEWORK; SELECTIVE OXIDATION; SOLID NANOPARTICLES; CATALYZED REACTIONS; PHASE INVERSION; EMULSIONS; PARTICLES; INTERFACE; CLUSTERS; SIZE in [Jing, Wendan; Li, Hui; Liu, Bolun; Wang, Runwei; Qiu, Shilun; Zhang, Zongtao] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China; [Xiao, Peiwen; Luo, Jianhui] PetroChina, Res Inst Petr Explorat & Dev, Beijing 100083, Peoples R China; [Xiao, Peiwen; Luo, Jianhui] CNPC, Key Lab Nano Chem KLNC, Beijing 100083, Peoples R China in 2021, Cited 43. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Name: (4-Methoxyphenyl)methanol

Organic reactors in a green solvent (water) is the goal of sustainable development. Green nanoreactors with excellent amphiphilicity and catalytic activity are strongly desired. Herein, a novel amphiphilic nanoreactor Pd@amZSM-5 with ultrasmall size has been successfully synthesized via a simple one-step oil bath method, subjected to the modification-etching-modification strategy and in situ reduction of Pd2+. Ultrasmall Pd@amZSM-5 nanoreactors (60 nm) with hierarchical structures showed outstanding amphiphilicity for forming Pickering emulsions with fine uniform droplets (50 mu m). Fine droplets formed short diffusion distances, which can significantly improve the catalytic activity in biphasic reactions. Moroever, the ultrasmall Pd@amZSM-5 nanoreactors demonstrated excellent catalytic activity for the selective oxidation of alcohols in water using air as the oxidant. Alkali was not present in the reaction system. The hydrophilic aminopropyl groups on the surface of the Pd@amZSM-5 nanoreactors not only changed the affinity of the zeolite surface and provided targeting points for Pd nanoparticles but also provided an alkaline environment for the selective oxidation of alcohols. The ultrasmall Pd@amZSM-5 nanoreactors presented excellent universality for aromatic alcohols (with >90% conversion and >90% selectivity) and allylic alcohols (with 100% conversion and 100% selectivity).

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Jing, WD; Li, H; Xiao, PW; Liu, BL; Luo, JH; Wang, RW; Qiu, SL; Zhang, ZT or concate me.. Name: (4-Methoxyphenyl)methanol

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In 2021 CATAL LETT published article about METAL-ORGANIC FRAMEWORK; SELECTIVE OXIDATION; AROMATIC ALCOHOLS; HYDROGEN-PRODUCTION; REACTIVE DYE; NANOCOMPOSITE; EFFICIENT; MIL-101; NANOPARTICLES; PERFORMANCE in [Wang, Mingming; Ma, Yali; Lv, Bolin; Hua, Fenglin; Meng, Shuangyan; Lei, Xuedi; Wang, Qingtao; Su, Bitao; Lei, Ziqiang; Yang, Zhiwang] Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Polymer Mat Gansu Prov, Key Lab Ecofunct Polymer Mat,Minist Educ, Lanzhou 730070, Peoples R China in 2021, Cited 44. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: 105-13-5

A novel photoactive porous material of GR/FeMIL-101 based on FeMIL-101 metal organic frameworks (MOFs) was successfully synthesized via a simple hydrothermal method. The structural and photoelectric properties of the GR/FeMIL-101 was analyzed by XRD, SEM, TEM, TGA, XPS, UV-vis DRS, FT-IR, PL and EIS methods. The photocatalytic performance for the selective oxidation of benzyl alcohol with GR/FeMIL-101 as catalysts was evaluated under visible light irradiation. The results showed that the GR/FeMIL-101 nanohybrid had better photocatalytic performance than both of FeMIL-101 and the pristine MIL-101. It was further found that the incorporation of Fe and MIL-101 caused valence fluctuations of Fe3+/Fe2+ which improved the absorption of visible-light and increased the separation efficiency of photogenerated charges. In addition, the combination of FeMIL-101 and GR could further promote the transfer rate of the photoelectrons. The mechanism of the reaction revealed that center dot O-2(-) was the dominating active specie in this reaction through active species trapping experiments. [GRAPHICS] .

Recommanded Product: 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wang, MM; Ma, YL; Lv, BL; Hua, FL; Meng, SY; Lei, XD; Wang, QT; Su, BT; Lei, ZQ; Yang, ZW or concate me.

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Li, DF; Wang, JG; Xu, FX; Zhang, NC; Men, Y in [Li, Dianfeng; Wang, Jinguo; Xu, Fengxia; Zhang, Nianchen; Men, Yong] Shanghai Univ Engn Sci, Sch Chem & Chem Engn, Shanghai 201620, Peoples R China published Mesoporous (001)-TiO2 nanocrystals with tailored Ti3+ and surface oxygen vacancies for boosting photocatalytic selective conversion of aromatic alcohols in 2021, Cited 46. Category: alcohols-buliding-blocks. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Selective conversion of aromatic alcohols to value-added chemicals is becoming an emerging research hotspot in heterogeneous photocatalysis, but its critical challenge is how to construct highly efficient photocatalysts. Herein, mesoporous (001)-TiO2 nanocrystals with tailored Ti3+ and surface oxygen vacancies have been fabricated by a facile hydrothermal route, showing remarkably boosted photoactivity for selective conversion of aromatic alcohols to carbonyl compounds in water medium under visible-light irradiation. Results attest that the remarkably boosted photoactivity was mainly correlated with the strong synergetic effect of exposed (001) facets, Ti3+ self-doping, and surface oxygen vacancies, leading to the enhanced reactant (aromatic alcohols and O-2) activation via the high surface energy of (001) facets, the improved visible-light absorbance via the intrinsic band gap narrowing, and the escalated photoelectron-hole separation efficiency via Ti3+ and surface oxygen vacancies acting as electron sinks. Meanwhile, a plausible photocatalytic mechanism for selective conversion of aromatic alcohols to carbonyl compounds has been elucidated in detail based on active species identified by capture experiments. It is hoped that this work can deliver some new insights into the rational design of highly efficient photocatalysts applied in future green organic selective transformation reactions.

Category: alcohols-buliding-blocks. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Li, DF; Wang, JG; Xu, FX; Zhang, NC; Men, Y or concate me.

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Formula: C8H10O2. Authors Zhang, YY; Liu, Q; Zhang, LY; Bao, YM; Tan, JY; Zhang, N; Zhang, JY; Liu, ZJ in ROYAL SOC CHEMISTRY published article about in [Zhang, Ying-Ying] Zhongyuan Univ Technol, Ctr Adv Mat Res, Zhengzhou 450007, Peoples R China; [Liu, Qing; Zhang, Lin-Yan; Bao, Yu-Mei; Tan, Jing-Yi; Zhang, Na; Zhang, Jian-Yong; Liu, Zhen-Jiang] Shanghai Inst Technol, Shanghai 201418, Peoples R China in 2021, Cited 82. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Three new Ni-II/Co-II-metal organic frameworks were self-assembled by the reaction of C-3 symmetric 1,3,5-tribenzoic acid (H3BTC) and 2,4,6-tris(4-pyridyl)-1,3,5-triazine (4-TPT) ligands and Ni-II/Co-II salts under solvothermal conditions. Isomorphous MOF1 and MOF2 exhibit a 3D pillar-layer framework based on binuclear M-2(OH)(COO)(2) units connected by tritopic BTC3- and 4-TPT ligands with a novel (3,5)-connected topology net. MOF3 displays a 3-fold interpenetrated 3D network exhibiting a (3,4)-connected topology net. The porous MOF3 can reversibly take up I-2. The activated MOFs contain both Lewis acid (Ni-II center) and basic (uncoordinated pyridyl or carboxylic groups) sites, and act as bifunctional acid-base catalysts. The catalytic measurements demonstrate that the activated MOF3 exhibits good activities for benzyl alcohol oxidation and the Knoevenagel reaction and can be recycled and reused for at least four cycles without losing its structural integrity and high catalytic activity. Thus, the catalytic properties for the oxidation-Knoevenagel cascade reaction have also been studied.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Zhang, YY; Liu, Q; Zhang, LY; Bao, YM; Tan, JY; Zhang, N; Zhang, JY; Liu, ZJ or concate me.. Formula: C8H10O2

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Safety of (4-Methoxyphenyl)methanol. I found the field of Chemistry very interesting. Saw the article Synthesis of TEMPO radical decorated hollow porous aromatic frameworks for selective oxidation of alcohols published in 2021, Reprint Addresses Zhuang, JL (corresponding author), Guizhou Normal Univ, Key Lab Funct Mat Chem Guizhou Prov, Sch Chem & Mat Sci, 116 Baoshan Rd North, Guiyang 550001, Peoples R China.; Sui, ZW (corresponding author), Natl Inst Metrol, Ctr Adv Measurement Sci, Beijing, Peoples R China.; Zhu, SB; Zhuang, JL (corresponding author), NanoFCM INC, Xiamen Pioneering Pk Overseas Chinese Scholars, Xiamen 361005, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol.

A bottom-up approach was developed to prepare TEMPO radical decorated hollow aromatic frameworks (HPAF-TEMPO) by using TEMPO radical functionalized monomers and SiO2 nanospheres as templates. The accessible inner layer, high density of TEMPO sites, and hybrid micro-/mesopores of the HPAF-TEMPO enable the aerobic oxidation of a broad range of alcohols with high efficiency and excellent selectivity.

Safety of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Shen, YM; Xue, Y; Yan, M; Mao, HL; Cheng, H; Chen, Z; Sui, ZW; Zhu, SB; Yu, XJ; Zhuang, JL or concate me.

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