Author: tianli

An article Electrochemical Arylation of Aldehydes, Ketones, and Alcohols: from Cathodic Reduction to Convergent Paired Electrolysis WOS:000621048400001 published article about C-H FUNCTIONALIZATION; PHOTOREDOX CATALYSIS; CARBONYL-COMPOUNDS; COUPLING REACTIONS; NICKEL CATALYSIS; GRIGNARD; HYDROGEN; HALIDES; IMINES; REAGENTS in [Zhang, Sheng; Li, Lijun; Li, Jingjing; Shi, Jianxue; Xu, Kun; Gao, Wenchao; Zong, Luyi] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Engn Technol Res Ctr Henan Prov Photo & Electroch, Nanyang, Peoples R China; [Li, Guigen; Findlater, Michael] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79423 USA in 2021, Cited 67. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Arylation of carbonyls, one of the most common approaches toward alcohols, has received tremendous attention, as alcohols are important feedstocks and building blocks in organic synthesis. Despite great progress, there is still a great gap to develop an ideal arylation method featuring mild conditions, good functional group tolerance, and readily available starting materials. We now show that electrochemical arylation can fill the gap. By taking advantage of synthetic electrochemistry, commercially available aldehydes (ketones) and benzylic alcohols can be readily arylated to provide a general and scalable access to structurally diverse alcohols (97 examples, >10 gram-scale). More importantly, convergent paired electrolysis, the ideal but challenging electrochemical technology, was employed to transform low-value alcohols into more useful alcohols. Detailed mechanism study suggests that two plausible pathways are involved in the redox neutral alpha-arylation of benzylic alcohols.

Product Details of 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Zhang, S; Li, LJ; Li, JJ; Shi, JX; Xu, K; Gao, WC; Zong, LY; Li, GG; Findlater, M or concate me.

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Category: alcohols-buliding-blocks. Authors Aydin, BO; Anil, D; Demir, Y in WILEY-V C H VERLAG GMBH published article about in [Aydin, Busra O.; Anil, Derya] Ataturk Univ, Dept Chem, Fac Sci, Erzurum, Turkey; [Anil, Derya] Ataturk Univ, Tech Sci Vocat Sch, Dept Chem & Chem Proc Technol, Erzurum, Turkey; [Demir, Yeliz] Ardahan Univ, Nihat Delibalta Gole Vocat Sch, Dept Pharm Serv, Ardahan, Turkey in 2021, Cited 53. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Fused pyrimidines, especially pyrazolo[3,4-d]pyrimidines, are among the most preferred building blocks for pharmacology studies, as they exhibit a broad spectrum of biological activity. In this study, new derivatives of pyrazolo[3,4-d]pyrimidine were synthesized by alkylation of the N1 nitrogen atom. We synthesized 3-iodo-1H-pyrazolo[3,4-d]pyrimidin-4-amine 2 from commercially available aminopyrazolopyrimidine 1 using N-iodosuccinimide as an iodinating agent. The synthesis of compound 2 started with nucleophilic substitution of 3-iodo-1H-pyrazolo[3,4-d]pyrimidin-4-amine with R-X (X: -OMs, -Br, -Cl), affording N-alkylated pyrazolo[3,4-d]pyrimidine. We performed this synthesis using a weak inorganic base and the mild temperature was also used for a two-step procedure to generate N-alkylated pyrazolo[3,4-d]pyrimidine derivatives. Also, all compounds were tested for their ability to inhibit acetylcholinesterase (AChE) and the human carbonic anhydrase (hCA) isoforms I and II, with K-i values in the range of 15.41 +/- 1.39-63.03 +/- 10.68 nM for AChE, 17.68 +/- 1.92-66.27 +/- 5.43 nM for hCA I, and 8.41 +/- 2.03-28.60 +/- 7.32 nM for hCA II. Notably, compound 10 was the most selective and potent CA I inhibitor with a significant selectivity ratio of 26.90.

Category: alcohols-buliding-blocks. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Aydin, BO; Anil, D; Demir, Y or concate me.

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An article Strong metal-support interaction induced O-2 activation over Au/MNb2O6 (M= Zn2+, Ni2+ and Co2+) for efficient photocatalytic benzyl alcohol oxidative esterification WOS:000600017200006 published article about SELECTIVE AEROBIC OXIDATION; GOLD NANOPARTICLES; ALIPHATIC-ALCOHOLS; ATMOSPHERIC-PRESSURE; OXYGEN ACTIVATION; MOLECULAR-OXYGEN; METHYL-ESTERS; CATALYSTS; REDUCTION; OXIDE in [Wang, Jie; Gu, Xianmo; Pei, Linjuan; Kong, Peng; Zhang, Jin; Wang, Xiaoyu; Wang, Ruiyi; Zheng, Zhanfeng] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China; [Wang, Jie; Pei, Linjuan; Zhang, Jin; Wang, Xiaoyu; Zheng, Zhanfeng] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China; [Waclawik, Eric R.] Queensland Univ Technol, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia in 2021, Cited 61. Computed Properties of C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A series of metal niobates (MNb2O6, M = Zn2+, Ni2+ and Co2+) were prepared from H-niobate precursor under hydrothermal conditions, in which amino groups of L-lysine play an important role. Au nanoparticles were then supported on these niobates by NaBH4 reduction method. More importantly, the strong interaction between Au nanoparticles and ZnNb2O6 generates negatively charged Au which can activate molecular oxygen to form the exclusive high-active peroxide (NbOOAu) species on Au/ZnNb2O6 surface under visible light irradiation, observed in situ by diffuse reflectance infrared Fourier transform spectra (DRIFTS). The optimal NbOOAu species produced on the surface of Au/ZnNb2O6 can remove the H atom of the methylene group (-CH2-) of benzyl alcohol, leading to high photocatalytic activity of Au/ZnNb2O6 compared with Au/NiNb2O6 and Au/CoNb2O6. This modulation of interaction of Au and niobates for the activation of molecular oxygen provides a new prospect for highly selective photocatalytic oxidation reactions.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wang, J; Gu, XM; Pei, LJ; Kong, P; Zhang, J; Wang, XY; Wang, RY; Waclawik, ER; Zheng, ZF or concate me.. Computed Properties of C8H10O2

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Authors Cavallo, M; Arnodo, D; Mannu, A; Blangetti, M; Prandi, C; Baratta, W; Baldino, S in PERGAMON-ELSEVIER SCIENCE LTD published article about in [Cavallo, Marzia; Arnodo, Davide; Mannu, Alberto; Blangetti, Marco; Prandi, Cristina; Baldino, Salvatore] Dipartimento Chim, Via P Giuria 7, I-10125 Turin, Italy; [Baratta, Walter] Univ Udine, Dipartimento DI4A, Via Cotonificio 108, I-33100 Udine, Italy in 2021, Cited 52. Name: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The employment of easily affordable ruthenium(II)-complexes as pre-catalysts in the transfer hydrogenation of carbonyl compounds in deep eutectic media is described for the first time. The eutectic mixture tetrabutylammonium bromide/formic acid = 1/1 (TBABr/HCOOH = 1/1) acts both as reaction medium and hydrogen source. The addition of a base is required for the process to occur. An extensive optimization of the reaction conditions has been carried out, in terms of catalyst loading, type of complexes, H-2-donors, reaction temperature and time. The combination of the dimeric complex [RuCl(p-cymene)-mu-Cl](2) (0.01-0.05 eq.) and the ligand dppf (1,10-ferrocenediyl-bis(diphenylphosphine)ferrocene) in 1/1 molar ratio has proven to be a suitable catalytic system for the reduction of several and diverse aldehydes and ketones to their corresponding alcohols under mild conditions (40-60 degrees C) in air, showing from moderate to excellent tolerability towards different functional groups (halogen, cyano, nitro, phenol). The reduction of imine compounds to their corresponding amine derivatives was also studied. In addition, the comparison between the results obtained in TBABr/HCOOH and in organic solvents suggests a non-innocent effect of the DES medium during the process. (C) 2021 Elsevier Ltd. All rights reserved.

Name: (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Cavallo, M; Arnodo, D; Mannu, A; Blangetti, M; Prandi, C; Baratta, W; Baldino, S or concate me.

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I found the field of Chemistry very interesting. Saw the article Dual-Role Catalysis by Thiobenzoic Acid in C alpha-H Arylation under Photoirradiation published in 2021. COA of Formula: C8H10O2, Reprint Addresses Hamashima, Y (corresponding author), Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, Shizuoka 4228526, Japan.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Thiobenzoic acid (TBA) can serve as a single-electron reducing agent under photoirradiation from a blue light-emitting diode, in the presence of appropriate electron acceptors, and the resulting sulfur-centered radical species undergoes hydrogen atom abstraction. This dual-role catalysis by TBA enables regioselectivie C alpha-H arylation of benzylamines, benzyl alcohols, and ethers, as well as dihydroimidazoles, with cyano(hetero)arenes in good yield, without the need for a transition-metal photocatalyst and/or synthetically elaborated organic dyes.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Kobayashi, F; Fujita, M; Ide, T; Ito, Y; Yamashita, K; Egami, H; Hamashima, Y or concate me.. COA of Formula: C8H10O2

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In 2021 J SUPERCRIT FLUID published article about CARBON-DIOXIDE EXTRACTION; FLUID EXTRACTION; ANTIOXIDANT ACTIVITY; CHEMICAL-COMPOSITION; FRACTIONATION; PERFORMANCE; VOLATILES; KINETICS; LUPEOL; LINK in [Casas, Maria P.; Lopez-Hortas, Lucia; Moure, Andres; Dominguez, Herminia] Univ Vigo, Dept Chem Engn, CINBIO, Campus Ourense,Edificio Politen, Orense 32004, Spain; [Diaz-Reinoso, Beatriz] Univ Vigo, CITI, Parque Tecnol Galicia,Rua Galicia 2, Orense 32900, Spain in 2021, Cited 38. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Quality Control of (4-Methoxyphenyl)methanol

Supercritical CO2 was used for the production of extracts from Acacia dealbata flowers. Pressures from 10 to 35 MPa and temperatures from 35? to 55?C were studied to assess their influence on the yield, antiradical properties and composition of the volatiles. The use of ethanol as modifier was also evaluated. Operating at 30 MPa and 45 ?C with 10% ethanol, up to 15% of the ethanol extractables were obtained in 3 h. The selectivity towards alcohol type compounds decreased with time and was enhanced in a sequence of static extraction with pure and ethanol modified CO2 followed by a dynamic stage. The most active fractions showed ABTS radical scavenging activity of 0.22 g Trolox/g extract. Different mathematical models were used to describe the kinetic data. The most abundant compounds in the supercritical extracts were oxygenated triterpenes whereas in conventional ethanolic extracts the main constituents were aliphatic compounds.

Quality Control of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Casas, MP; Lopez-Hortas, L; Diaz-Reinoso, B; Moure, A; Dominguez, H or concate me.

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In 2021 MOL CATAL published article about SELECTIVE N-ALKYLATION; ONE-POT SYNTHESIS; BORROWING HYDROGEN; EFFICIENT CATALYSTS; BETA-ALKYLATION; IRIDIUM COMPLEX; ALCOHOLS; RUTHENIUM; SULFONAMIDES; AMINATION in [Wu, Di; Bu, Qingqing; Dai, Bin; Liu, Ning] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, North Fourth Rd, Shihezi 832003, Xinjiang, Peoples R China; [Guo, Cheng] Zhejiang Univ, Affiliated Hosp 2, Sch Med, Canc Inst, Hangzhou 310009, Zhejiang, Peoples R China in 2021, Cited 73. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Computed Properties of C8H10O2

Multi-amino groups and nitrogen donors compound was discovered as an organocatalyst for N-alkylation of alcohols with amines in the presence of Mo(CO)6. The Mo(CO)6/organocatalyst binary system has shown to be a highly active catalyst for the N-alkylation reaction between alcohols and amines with excellent tolerance of variable starting materials bearing different functional groups. Of particular note, this method possessing a superiority selectivity in the synthesis of N-alkylated amines or imines, which can be controlled by the reaction temperature. The cooperative catalysis mechanism in combination of Mo(CO)6 with organocatalyst was elucidated by control experiments.

Computed Properties of C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wu, D; Bu, QQ; Guo, C; Dai, B; Liu, N or concate me.

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SDS of cas: 105-13-5. Authors Yang, SN; Liu, XY; Lu, SJ; Li, Z; Zhang, YM; Yu, SN; Song, J; Ding, CF; Yang, HY in WILEY-V C H VERLAG GMBH published article about in [Yang, Shouning; Yu, Shaoning; Yang, Huayan] Ningbo Univ, Sch Mat Sci & Chem Engn, Inst Mass Spectrometry, Zhejiang Prov Key Lab Adv Mass Spectrometry & Mol, Ningbo 315211, Zhejiang, Peoples R China; [Zhang, Yanmin; Song, Jian] Henan Normal Univ, Sch Phys, Xinxiang 453007, Henan, Peoples R China; [Yang, Shouning; Liu, Xiaoyang; Lu, Sijia; Li, Zhuo; Yang, Huayan] Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Key Lab Green Chem Media & React, Minist Educ,Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China in 2021, Cited 65. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The development of eco-friendly and low cost catalysts is challenging. Here, heterostructures of Bi2S3 quantum dots (QDs) doped onto ultrathin BiOCl nanosheets were synthesized by a facile hydrothermal method to exploit efficient photosensitizers with appropriate electronic states to enhance the transfer of electrons. The obtained Bi2S3-BiOCl showed highly efficient photocatalytic ability for selective oxidation of aromatic alcohols to aldehydes. More oxygen vacancies are formed on the exposed 001 facet of the ultrathin BiOCl, which can effectively trap electrons and form O-.(2)- radicals. The cooperation between the BiOCl and the Bi2S3 QDs effectively separates photogenerated electron-hole pairs at the heterointerface and facilitates the cooperative actions of O-.(2)- radicals and holes, which brings about a desirable photocatalytic eciency for the selective oxidation of aromatic alcohols. This work highlights the synergistic effect of semiconductor QDs and two-dimensional materials on selective conversion processes and provides a new design paradigm using noble metal-free heteromaterials with high photocatalytic activity. This opens new possibilities for photocatalyst design using heteromaterials with high photocatalytic activity.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Yang, SN; Liu, XY; Lu, SJ; Li, Z; Zhang, YM; Yu, SN; Song, J; Ding, CF; Yang, HY or concate me.. Product Details of 105-13-5

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Product Details of 105-13-5. Authors Bisht, NS; Mehta, SPS; Sahoo, NG; Dandapat, A in ROYAL SOC CHEMISTRY published article about in [Bisht, Narendra Singh; Mehta, S. P. S.; Sahoo, Nanda Gopal; Dandapat, Anirban] Kumaun Univ, Dept Chem, DSB Campus, Naini Tal, Uttarakhand, India in 2021, Cited 74. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The room temperature synthesis of an all-solid-state Z-scheme CuO-doped BiOBr (CuO-Bi-BiOBr) photocatalyst has been described. These CuO-Bi-BiOBr ternary heterojunctions exhibit efficient photocatalytic activities for selective alcohol oxidation. The structures, morphologies, and compositions of the nanostructures were well characterized using field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and atomic absorption spectroscopy (AAS). The X-ray diffraction (XRD) pattern of the as-synthesized nanostructures confirms the formation of phase-segregated CuO and BiOBr nanocrystals, whereas X-ray photoelectron spectroscopy (XPS) and high-resolution transmission electron microscopy (HRTEM) analyses clearly indicate the formation of metallic bismuth nanoparticles (NPs). Next, the developed CuO-Bi-BiOBr ternary heterojunctions were applied as an efficient photocatalyst for the oxidation of alcohols into their corresponding aldehydes/ketones with high selectivity (>99%) and high conversion ratios (>99%). Herein, Bi metal NPs act as an electron mediator and bridge the connectivity between the two semiconductors, BiOBr and CuO, and, thus, a Z-scheme heterojunction is established. As expected, CuO-Bi-BiOBr has shown significantly superior activities compared to those of pure BiOBr. A possible mechanism for the photocatalytic oxidation process has been proposed. Radical scavenging experiments suggest that the active species, h(+), OH, e(-), and O-2(-), are dominant in the alcohol oxidation process. The as-synthesized CuO-Bi-BiOBr was reused several times without any significant deterioration in the original activities and it thus possesses relatively high stability for practical applications.

Product Details of 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Bisht, NS; Mehta, SPS; Sahoo, NG; Dandapat, A or concate me.

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Computed Properties of C8H10O2. Authors Wang, ZH; Wang, H; Wang, H; Li, L; Zhou, MD in AMER CHEMICAL SOC published article about in [Wang, Zhao-Hui; Wang, He; Wang, Hua; Li, Lei; Zhou, Ming-Dong] Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

In this work, ruthenium(II)-catalyzed C-C/C-N annulation of 2-arylquinazolinones with vinylene carbonate is reported to synthesize fused quinazolinones. This catalytic system tolerates a wide range of substrates with excellent functional-group compatibility. In this transformation, the vinylene carbonate acts as an ethynol surrogate without any external oxidant involved. Furthermore, preliminary mechanistic studies were conducted, and a plausible catalytic cycle was also proposed.

Computed Properties of C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wang, ZH; Wang, H; Wang, H; Li, L; Zhou, MD or concate me.

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