Author: tianli

Recommanded Product: (4-Methoxyphenyl)methanol. I found the field of Chemistry very interesting. Saw the article Dinuclear Copper(II) Complexes with N,O Donor Ligands: Partial Ligand Hydrolysis and Alcohol Oxidation Catalysis published in 2021, Reprint Addresses Roy, P (corresponding author), Jadavpur Univ, Dept Chem, Kolkata 700032, India.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol.

Two copper(II) complexes [Cu-2(L-1)(2)] (1) and [Cu-2(L-2)(2)] (2) where H2L1=2-hydroxy-3-((3-hydroxy-2,2-dimethylpropylimino)methyl)-5-methylbenzaldehyde and H2L2=2-hydroxy-3-(((1-hydroxypropan-2-yl)imino)methyl)-5-methylbenzaldehyde have been synthesized and used as catalysts in alcohol oxidation. 2,6-Diformyl-4-methylphenol (DFP) based Schiff-base ligands, 3,3 ‘-(2-hydroxy-5-methyl-1,3-phenylene)bis(methan-1-yl-1-ylidene)bis(azan-1-yl-1-ylidene)bis(2,2-dimethylpropan-1-ol) (H3L ‘) and 2,2 ‘-(((2-hydroxy-5-methyl-1,3-phenylene)bis(methanylylidene))bis(azanylylidene))bis(propan-1-ol) (H3L ”), undergo partial hydrolysis to convert one of the azomethine groups to aldehyde group to give H2L1 and H2L2, and then react with copper(II) acetate to yield complex 1 and 2, respectively. These complexes have been characterized by standard methods such as elemental analysis, room temperature magnetic studies, FT-IR, UV-vis, ESI-mass spectral analyses, cyclic voltammogram, etc. The structures of dinuclear complexes with modified ligands have been confirmed by single crystal X-ray diffraction analysis. Complex 1 and 2 have been used as catalysts for the oxidation of benzyl alcohol, 4-methyl benzyl alcohol, 4-methoxy benzyl alcohol, 4-nitro benzyl alcohol and 4-bromo benzyl alcohol to the corresponding aldehyde as the sole product. Efficiency of the catalyst depends on the chain length and substitution on the chain of the ligand.

Recommanded Product: (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Barma, A; Bhattacharjee, A; Roy, P or concate me.

Reference:
Alcohol – Wikipedia,
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Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Zhuang, XH; Shi, XY; Zhu, R; Sun, B; Su, WK; Jin, C in ROYAL SOC CHEMISTRY published article about in [Zhuang, Xiaohui; Sun, Bin; Su, WeiKe; Jin, Can] Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou, Peoples R China; [Shi, Xiayue; Zhu, Rui; Su, WeiKe; Jin, Can] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou, Peoples R China in 2021, Cited 58. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A mild and metal-free protocol for visible-light induced intramolecular radical cyclization of N-allyl(propargyl)-2-bromo-2,2-difluoro-N-arylacetamide has been developed. This strategy showed excellent regioselectivity and simple operation to synthesize 4-substituted 3,3-difluoro-gamma-lactams with a broad substrate scope. Moreover, mechanistic studies revealed that this transformation proceeded through a cascade radical-type cyclization and hydrogen atom transfer process with PMDETA as a hydrogen-atom donor.

Application In Synthesis of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Zhuang, XH; Shi, XY; Zhu, R; Sun, B; Su, WK; Jin, C or concate me.

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Product Details of 105-13-5. Authors Wei, DY; Yang, P; Yu, CM; Zhao, FK; Wang, YL; Peng, ZH in AMER CHEMICAL SOC published article about in [Wei, Dongyue; Yang, Peng; Yu, Chuanman; Zhao, Fengkai; Wang, Yilei; Peng, Zhihua] China Univ Petr East China, Coll Sci, Dept Chem, Qingdao 266580, Shandong, Peoples R China in 2021, Cited 51. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A manganese-catalyzed N-alkylation reaction of amines with alcohols via hydrogen autotransfer strategy has been demonstrated. The developed practical catalytic system including an inexpensive, nontoxic, commercially available MnCl2 or MnBr(CO) s as the metal salt and triphenylphosphine as a ligand provides access to diverse aromatic, heteroaromatic, and aliphatic secondary amines in moderate-to-high yields. In addition, this operationally simple protocol is scalable to the gram level and suitable for synthesizing heterocycles such as indole and resveratrol-derived amines known to be active for Alzheimer’s disease.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wei, DY; Yang, P; Yu, CM; Zhao, FK; Wang, YL; Peng, ZH or concate me.. Product Details of 105-13-5

Reference:
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An article Cu-Mn Bimetallic Complex Immobilized on Magnetic NPs as an Efficient Catalyst for Domino One-Pot Preparation of Benzimidazole and Biginelli Reactions from Alcohols WOS:000567788200001 published article about AEROBIC OXIDATION; AROMATIC DIAMINES; MULTICOMPONENT REACTIONS; SELECTIVE OXIDATION; COUPLING REACTIONS; SCHIFF-BASE; NANOCATALYST; NANOPARTICLES; HANTZSCH; COPPER in [Nasseri, Mohammad Ali; Rezazadeh, Zinat; Kazemnejadi, Milad; Allahresani, Ali] Univ Birjand, Dept Chem, Fac Sci, Birjand 97175615, Iran in 2021, Cited 73. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

An efficient magnetically recyclable bimetallic catalyst by anchoring copper and manganese complexes on the Fe(3)O(4)NPs was prepared and named as Fe3O4@Cu-Mn. It was founded as a powerful catalyst for the domino one-pot oxidative benzimidazole and Biginelli reactions from benzyl alcohols as a green protocol in the presence of air, under solvent-free and mild conditions. Fe3O4@Cu-Mn NPs were well characterized by FT-IR, XRD, FE-SEM, TEM, VSM, TGA, EDX, DLS, and ICP analyses. The optimum range of parameters such as time, temperature, amount of catalyst, and solvent were investigated for the domino one-pot benzimidazole and Biginelli reactions to find the optimum reaction conditions. The catalyst was compatible with a variety of benzyl alcohols, which provides favorable products with good to high yields for all of derivatives. Hot filtration and Hg poisoning tests from the nanocatalyst revealed the stability, low metal leaching and heterogeneous nature of the catalyst. To prove the synergistic and cooperative effect of the catalytic system, the various homologues of the catalyst were prepared and then applied to a model reaction separately. Finally, the catalyst could be filtered from the reaction mixture simply, and reused for five consecutive cycles with a minimum loss in catalytic activity and performance. Graphic A new magnetically recyclable Cu/Mn bimetallic catalyst has been developed for domino one-pot oxidation-condensation of benzimidazole and Biginelli reactions from alcohols.

Product Details of 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Nasseri, MA; Rezazadeh, Z; Kazemnejadi, M; Allahresani, A or concate me.

Reference:
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In 2021 ORGANOMETALLICS published article about AEROBIC OXIDATIVE SYNTHESIS; CASCADE SYNTHESIS; QUINAZOLINONES; LIGANDS; FUNCTIONALIZATION; AMINOBENZAMIDES; BENZIMIDAZOLES; HYDROPEROXIDE; HETEROCYCLES; CHEMISTRY in [Balaji, Sundarraman; Balamurugan, Gunasekaran; Ramesh, Rengan] Bharathidasan Univ, Ctr Organometall Chem, Sch Chem, Tiruchirappalli 620024, Tamil Nadu, India; [Semeril, David] Univ Strasbourg, Inst Chim, Lab Chim Inorgan & Catalyse, UMR 7177,CNRS, F-67070 Strasbourg, France in 2021, Cited 78. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. HPLC of Formula: C8H10O2

A convenient protocol for the one-pot synthesis of quinazolin-4(3H)-ones using palladium(II) complexes via dehydrogenative coupling of readily available benzyl alcohols and 2-aminobenzamide has been described. New structurally related Pd(II) N boolean AND O chelating complexes of general configuration [Pd(L)Cl(PPh3)] (where L = dimethylamino benzoylhydrazone ligands) have been designed and synthesized. The formation of the complexes has been recognized by analytical and spectral methods (FT-IR, NMR, HR-MS). The presence of a square-planar geometry around the palladium(II) ion was confirmed by single crystal X-ray diffraction study. A wide range of substituted quinazolinones have been successfully achieved from a diverse range of benzyl alcohols in good to excellent yields using 1.0 mol % of catalyst loading under aerobic conditions. Furthermore, control experiments reveal that the dehydrogenative coupling reaction involves initially the formation of an aldehyde intermediate and subsequent formation of a cyclic aminal intermediate.

HPLC of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Balaji, S; Balamurugan, G; Ramesh, R; Semeril, D or concate me.

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Safety of (4-Methoxyphenyl)methanol. Authors Epifanov, M; Mo, JY; Dubois, R; Yu, H; Sammis, GM in AMER CHEMICAL SOC published article about in [Epifanov, Maxim; Mo, Jia Yi; Dubois, Rudy; Yu, Hao; Sammis, Glenn M.] Univ British Columbia, Dept Chem, Columbia, BC V6T 1Z1, Canada in 2021, Cited 48. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Sulfuryl fluoride is a valuable reagent for the one-pot activation and derivatization of aliphatic alcohols, but the highly reactive alkyl fluorosulfate intermediates limit both the types of reactions that can be accessed as well as the scope. Herein, we report the SO2F2-mediated alcohol substitution and deoxygenation method that relies on the conversion of fluorosulfates to alkyl halide intermediates. This strategy allows the expansion of SO2F2-mediated one-pot processes to include radical reactions, where the alkyl halides can also be exploited in the one-pot deoxygenation of primary alcohols under mild conditions (52-95% yield). This strategy can also enhance the scope of substitutions to nucleophiles that are previously incompatible with one-pot SO2F2-mediated alcohol activation and enables substitution of primary and secondary alcohols in 54-95% yield. Chiral secondary alcohols undergo a highly stereospecific (90-98% ee) double nucleophilic displacement with an overall retention of configuration.

Safety of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Epifanov, M; Mo, JY; Dubois, R; Yu, H; Sammis, GM or concate me.

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Category: alcohols-buliding-blocks. In 2021 CHEMSUSCHEM published article about BORROWING HYDROGEN; ALPHA-ALKYLATION; AROMATIC-AMINES; BOND FORMATION; COMPLEXES; EFFICIENT; KETONES; STRATEGY; LIGANDS; IMINES in [Lan, Xiao-Bing; Ye, Zongren; Yang, Chenhui; Li, Weikang; Liu, Jiahao; Huang, Ming; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Mat Sci & Engn, PCFM Lab, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China; [Lan, Xiao-Bing] Xiangnan Univ, Sch Chem & Biol & Environm Engn, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423000, Hunan, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

The implementation of non-noble metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of non-noble metal catalysts. Herein, we report a tungsten-catalyzed N-alkylation reaction of anilines with primary alcohols via BH/HA. This phosphine-free W(phen)(CO)(4) (phen=1,10-phenthroline) system was demonstrated as a practical and easily accessible in-situ catalysis for a broad range of amines and alcohols (up to 49 examples, including 16 previously undisclosed products). Notably, this tungsten system can tolerate numerous functional groups, especially the challenging substrates with sterically hindered substituents, or heteroatoms. Mechanistic insights based on experimental and computational studies are also provided.

Category: alcohols-buliding-blocks. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Lan, XB; Ye, ZR; Yang, CH; Li, WK; Liu, JH; Huang, M; Liu, Y; Ke, ZF or concate me.

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Alcohol – Wikipedia,
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In 2021 CATAL LETT published article about AEROBIC OXIDATION; AROMATIC DIAMINES; MULTICOMPONENT REACTIONS; SELECTIVE OXIDATION; COUPLING REACTIONS; SCHIFF-BASE; NANOCATALYST; NANOPARTICLES; HANTZSCH; COPPER in [Nasseri, Mohammad Ali; Rezazadeh, Zinat; Kazemnejadi, Milad; Allahresani, Ali] Univ Birjand, Dept Chem, Fac Sci, Birjand 97175615, Iran in 2021, Cited 73. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Computed Properties of C8H10O2

An efficient magnetically recyclable bimetallic catalyst by anchoring copper and manganese complexes on the Fe(3)O(4)NPs was prepared and named as Fe3O4@Cu-Mn. It was founded as a powerful catalyst for the domino one-pot oxidative benzimidazole and Biginelli reactions from benzyl alcohols as a green protocol in the presence of air, under solvent-free and mild conditions. Fe3O4@Cu-Mn NPs were well characterized by FT-IR, XRD, FE-SEM, TEM, VSM, TGA, EDX, DLS, and ICP analyses. The optimum range of parameters such as time, temperature, amount of catalyst, and solvent were investigated for the domino one-pot benzimidazole and Biginelli reactions to find the optimum reaction conditions. The catalyst was compatible with a variety of benzyl alcohols, which provides favorable products with good to high yields for all of derivatives. Hot filtration and Hg poisoning tests from the nanocatalyst revealed the stability, low metal leaching and heterogeneous nature of the catalyst. To prove the synergistic and cooperative effect of the catalytic system, the various homologues of the catalyst were prepared and then applied to a model reaction separately. Finally, the catalyst could be filtered from the reaction mixture simply, and reused for five consecutive cycles with a minimum loss in catalytic activity and performance. Graphic A new magnetically recyclable Cu/Mn bimetallic catalyst has been developed for domino one-pot oxidation-condensation of benzimidazole and Biginelli reactions from alcohols.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Nasseri, MA; Rezazadeh, Z; Kazemnejadi, M; Allahresani, A or concate me.. Computed Properties of C8H10O2

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

An article Switchable beta-alkylation of Secondary Alcohols with Primary Alcohols by a Well-Defined Cobalt Catalyst WOS:000651063700005 published article about ALPHA-ALKYLATION; N-ALKYLATION; EFFICIENT CATALYSTS; BORROWING HYDROGEN; PINCER COMPLEXES; AROMATIC-AMINES; MANGANESE; KETONES; METHYLATION; IMINES in [Pandey, Bedraj; Xu, Shi; Ding, Keying] Middle Tennessee State Univ, Dept Chem, Murfreesboro, TN 37132 USA; [Ding, Keying] Middle Tennessee State Univ, Mol Biosci Program, Murfreesboro, TN 37132 USA in 2021, Cited 72. Safety of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

beta-alkylation of secondary alcohols with primary alcohols to selectively generate alcohols by a well-defined Co catalyst is presented. Remarkably, a low catalyst loading of 0.7 mol % can be employed for the reaction. More significantly, this study represents the first Co-catalyzed switchable alcohol/ketone synthesis by simply manipulating the reaction parameters. In addition, the transformation is environmentally friendly, with water as the only byproduct.

Safety of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Pandey, B; Xu, S; Ding, KY or concate me.

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Recommanded Product: 105-13-5. Authors Sait, N; Aliouane, N; Toukal, L; Hammache, H; Al-Noaimi, M; Helesbeux, JJ; Duval, O in ELSEVIER published article about in [Sait, N.; Aliouane, N.; Hammache, H.] Univ Bejaia, Dept Genie Proc, Lab Electrochim Corros & Valorisat Energet, Bejaia 06000, Algeria; [Toukal, L.] Univ Ferhat Abbas Setif 1, Dept Genie Proc, Lab Electrochim Ingn Mol & Catalyse Redox, Setif, Algeria; [Al-Noaimi, M.] Hashemite Univ, Fac Sci, Dept Chem, POB 330127, Zarqa 13133, Jordan; [Helesbeux, J. J.; Duval, O.] Univ Angers, Univ Bretagne Loire, SFR QUASAV 4207, Lab SONAS,EA921, 42 Rue Georges Morel, Beaucouze, France in 2021, Cited 83. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The inhibition performance of the newly synthesized Ethylene bis [(2-hydroxy-5,1,3-phenylene) bismethylene] tetraphosphonic acid (ETPA) toward carbon steel in 3% NaCl was investigated at different concentrations using potentiodynamic polarization (PDP) and impedance spectroscopy (EIS) methods. It was found that the inhibition capability was increased with increasing inhibitor dose and reach 92% at 10(-3) mol/L. Also, Polarization curves showed that ETPA acts as a mixed type inhibitor with predominantly control of anodic reaction. The new inhibitor was investigated by different spectroscopic methods such as H-1, C-13 and (PNMR)-P-31. The quantum parameters such as absolute electronegativity (chi), energy gap Delta(E) (E-HOMO-E-LUMO), global softness (sigma), global hardness (eta), electrophilicity index (omega) and the number of transfer electrons (Delta N) are calculated by density functional theory (DFT). The experimental also correlated with density functional theory results. The calculations show that ETPA has high density of negative charge located on the oxygen atoms of the phosphonate group facilitating the adsorption of ETPA on the surface of carbon steel. The inhibition efficiency of ETPA was discussed in terms of blocking of electrode surface by adsorption of ETPA molecules through active centers. The adsorption of ETPA on the surface of carbon steel obeyed the Langmuir isotherm paradigm. (C) 2021 Elsevier B.V. All rights reserved.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Sait, N; Aliouane, N; Toukal, L; Hammache, H; Al-Noaimi, M; Helesbeux, JJ; Duval, O or concate me.. Recommanded Product: 105-13-5

Reference:
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