Author: tianli

Authors Bains, AK; Yadav, A; Adhikari, D in AMER CHEMICAL SOC published article about in [Bains, Amreen K.; Adhikari, Debashis] Indian Inst Sci Educ & Res IISER Mohali, Dept Chem Sci, Ajitgarh 140306, Punjab, India; [Yadav, Ankit] Indian Inst Sci Educ & Res IISER Mohali, Dept Earth & Environm Sci, Ajitgarh 140306, Punjab, India in 2021, Cited 35. Safety of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Herein, we report a combination of pyrenedione (PD) and KO’Bu to achieve facile alcohol dehydrogenation under visible-light excitation, where aerobic oxygen is utilized as the terminal oxidant. The resulting carbonyl compound can be easily converted to vinyl nitriles in a single-pot reaction, at 60 degrees C in 6-8 h. This environmentally benign, organocatalytic approach has distinct advantages over transition-metal-catalyzed a-olefination of nitriles, which often operate at a significantly higher temperature for an extended reaction time.

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Product Details of 105-13-5. Authors Sun, ZL; Yang, XL; Yu, XF; Xia, LH; Peng, YH; Li, Z; Zhang, Y; Cheng, JB; Zhang, KS; Yu, JQ in ELSEVIER published article about in [Sun, Zhaoli; Yang, Xiaolong; Xia, Linhong; Peng, Yanhua; Li, Zhuo; Zhang, Yan; Yu, Jianqiang] Qingdao Univ, Coll Chem & Chem Engn, 308 Ning Xia Rd, Qingdao 266071, Peoples R China; [Yu, Xue-Fang; Cheng, Jianbo] Yantai Univ, Sch Chem & Chem Engn, Lab Theoret & Computat Chem, 32 Qingquan Rd, Yantai 264005, Peoples R China; [Zhang, Kaisheng] Chinese Acad Sci, HFIPS, Inst Solid State Phys, Environm Mat & Pollut Control Lab, Hefei 230031, Peoples R China in 2021, Cited 55. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The recombination of photogenerated carriers seriously restricts their utilization efficiency in photocatalysis. Herein, surface oxygen vacancies (SOVs) were constructed in Pd-Bi2MoO6 interface to bridge ultra-low loading Pd cluster and Bi2MoO6 semiconductor (Pd/BMO-SOVs). It was found SOVs in Pd/Bi2MoO6-x serve as Electron Bridge to bridge ultra-low loading Pd cluster and Bi2MoO6-x, thus tremendously enhance utilization efficiency of photoexcited carriers and ultra-low loading Pd active sites for blue LED driven selective oxidation reaction. The Pd(0.05)/Bi2MoO6-SOVs exhibited 57.8 % conversion for selection oxidation of benzyl which are 6.5, 3.3 and 2.1 times higher than pristine Bi2MoO6, Bi2MoO6-x and Pd(0.05)/Bi2MoO6. Combined with theoretical calculations, SOVs was proposed as Electron Bridge to transfer photogenerated electrons from Bi2MoO6-x to ultra-low loading Pd clusters, thus greatly boosting separation and utilization efficiency of photogenerated electron-hole pairs.

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I found the field of Chemistry very interesting. Saw the article Synthesis of functionalized pyrimidouracils by ruthenium-catalyzed oxidative insertion of (hetero)aryl methanols into N-uracil amidines published in 2021. Computed Properties of C8H10O2, Reprint Addresses Debnath, P (corresponding author), Maharaja Bir Bikram Coll, Dept Chem, Agartala 799004, Tripura, India.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A dehydrogenative coupling of N-uracil amidines with (hetero)aryl methanols has been developed, allowing for the facile synthesis of a broad range of structurally diverse pyrimidouracils. By applying [RuCl2(p-cymene)](2)/Cs2CO3 as an efficient catalytic system, the easily available, cheap (hetero)aryl methanols were firstly employed for oxidative insertion/C-H amination into the N-uracil amidines, providing highly functionalized pyrimido[4,5-d]pyrimidine-2,4-diones. Due to the better stability of alcohols than aldehydes, this synthetic protocol is applicable to a broad range of alcoholic substrates and does not required any protection during the whole preparation process. The presented protocol has the potential to prepare valuable products which cannot be accessed presently or extremely arduous to procure by following regular procedure. Hence, this is a remarkably improved protocol compared with the existing methodologies. The overall reaction sequence is an effective oxidation-imination-cyclization tandem process catalyzed by ruthenium catalyst.

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Lu, XL; Qiu, YY; Yang, BC; He, HB; Gao, SH in [Lu, Xiao-Long; Qiu, Yuanyou; Yang, Baochao; Gao, Shuanhu] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663N Zhongshan Rog, Shanghai 200062, Peoples R China; [He, Haibing; Gao, Shuanhu] East China Normal Univ, Shanghai Engn Res Ctr Mol Therapeut & New Drug De, 3663N Zhongshan Rd, Shanghai 200062, Peoples R China published Asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B in 2021, Cited 76. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

The asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B was achieved in 6-7 steps using an easily accessible meso-cyclohexadienone derivative. The [6,6]-bicyclic decalin B-C ring and the all-carbon quaternary stereocenter at C-6 were prepared via a desymmetric intramolecular Michael reaction with up to 97% ee. The naphthalene diol D-E ring was constructed through a sequence of Ti(Oi-Pr)(4)-promoted photoenolization/Diels-Alder, dehydration, and aromatization reactions. This asymmetric strategy provides a scalable route to prepare target molecules and their derivatives for further biological studies.

Product Details of 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Lu, XL; Qiu, YY; Yang, BC; He, HB; Gao, SH or send Email.

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COA of Formula: C8H10O2. Recently I am researching about N-HETEROCYCLIC CARBENE; CROSS-COUPLING REACTIONS; BETA-ALKYLATION; ALPHA-ALKYLATION; BORROWING HYDROGEN; METHYL KETONES; IRIDIUM; COMPLEXES, Saw an article supported by the IISER Tirupati; SERB, IndiaDepartment of Science & Technology (India)Science Engineering Research Board (SERB), India [CRG/2018/002480/OC]; SwarnaJayanti Fellowship grant [DST/SJF/CSA-04/2019-2020, SERB/F/5892/2020-2021]; SERB-PMRF; UGCUniversity Grants Commission, India. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Babu, R; Subaramanian, M; Midya, SP; Balaraman, E. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Acceptorless double dehydrogenative cross-coupling of secondary and primary alcohols under nickel catalysis is reported. This Guerbet type reaction provides an atom- and a step-economical method for the C-alkylation of secondary alcohols under mild, benign conditions. A broad range of substrates including aromatic, cyclic, acyclic, and aliphatic alcohols was well tolerated. Interestingly, the C-alkylation of cholesterol derivatives and the double C-alkylation of cyclopentanol with various alcohols were also demonstrated.

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Authors Naganawa, Y; Sakamoto, K; Nakajima, Y in AMER CHEMICAL SOC published article about CROSS-COUPLING REACTION; GRIGNARD REACTION; ARYL BROMIDES; VINYL HALIDES; SILANES; SILICON; ELECTROPHILES; CHLOROSILANES; PRECATALYST; METHYLATION in [Naganawa, Yuki; Sakamoto, Kei; Nakajima, Yumiko] Natl Inst Adv Ind Sci & Technol, Interdisciplinary Res Ctr Catalyt Chem IRC3, Tsukuba, Ibaraki 3058565, Japan in 2021, Cited 50. Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Direct catalytic transformation of chlorosilanes into organosilicon compounds remains challenging due to difficulty in cleaving the strong Si-Cl bond(s). We herein report the palladium-catalyzed cross-coupling reaction of chlorosilanes with organoaluminum reagents. A combination of [Pd(C3H5)Cl](2) and DavePhos ligand catalyzed the selective methylation of various dichlorosilanes 1, trichlorosilanes 5, and tetrachlorosilane 6 to give the corresponding monochlorosilanes.

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Recently I am researching about SELECTIVE OXIDATION; N-BROMOSUCCINIMIDE; SULFATED POLYBORATE; BENZYLIC ALCOHOLS; EFFICIENT; CATALYST; ALDEHYDES; COMPLEX; DERIVATIVES; WATER, Saw an article supported by the Department of Science and Technology, India (WOS-A)Department of Science & Technology (India)Department of Science & Technology (DOST), Philippines; Loba Chemie Pvt. Ltd.. Safety of (4-Methoxyphenyl)methanol. Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Palav, A; Misal, B; Ganwir, P; Badani, P; Chaturbhuj, G. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Chlorine is the 20th most abundant element on the earth compared to bromine, iodine, and fluorine, a sulfonimide reagent, N-chloro-N-(phenylsulfonyl)benzenesulfonamide (NCBSI) was identified as a mild and selective oxidant. Without activation, the reagent was proved to oxidize primary and secondary alcohols as well as their symmetrical and mixed ethers to corresponding aldehydes and ketones. With recoverable PS-TEMPO catalyst, selective oxidation over chlorination of primary and secondary alcohols and their ethers with electron-donating substituents was achieved. The reagent precursor of NCBSI was recovered quantitatively and can be reused for synthesizing NCBSI. (C) 2021 Elsevier Ltd. All rights reserved.

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SDS of cas: 105-13-5. I found the field of Chemistry; Environmental Sciences & Ecology very interesting. Saw the article Sustainable production of value-added chemicals and fuels by using a citric acid-modified carbon nitride optical semiconductor published in 2021, Reprint Addresses Silva, CG (corresponding author), Univ Porto, Fac Engn, Associate Lab LSRE LCM, Rua Dr Roberto Frias S-N, P-4200465 Porto, Portugal.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol.

Citric acid-modified graphite-like carbon nitride materials (GCN-zCA) were synthetized by thermal copolymerization of dicyandiamide with different amounts of citric acid (z = between 5 and 25 mg). The resulting materials presented surface porosity, defective polymeric structure, and enhanced visible light absorption in the 450-700 nm range, attributed to the existence of mid-gap states and n-pi* electronic transitions. All the modified catalysts presented high selectivity (>99 %) towards the conversion of p-anisyl alcohol into p-anisaldehyde under visible-LED irradiation, the best performing photocatalyst (GCN-20CA) reaching 63 % yield (contrasting with 22 % obtained with bulk GCN) after 240 min reaction. GCN-20CA was also applied for hydrogen generation from water splitting. The modified material practically duplicated the hydrogen production when compared to bulk GCN (75 and 44 mu mol H-2 evolved in three hours, respectively), by using platinum nanoparticles as co-catalyst and EDTA as sacrificial electron donor. Moreover, p-anisyl alcohol was successfully used as sacrificial agent for water splitting, with simultaneous production of p-anisaldehyde and H-2. Reusability tests showed that GCN-20CA remained stable in a series of consecutive runs both for p-anisaldehyde synthesis and hydrogen production.

Welcome to talk about 105-13-5, If you have any questions, you can contact Fernandes, RA; Sampaio, MJ; Da Silva, ES; Boumeriame, H; Lopes, T; Andrade, L; Mendes, A; Faria, JL; Silva, CG or send Email.. SDS of cas: 105-13-5

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Recently I am researching about BIS(IMINO)PYRIDINE COBALT COMPLEXES; CHEMOSELECTIVE HYDROGENATION; IRON; EFFICIENT; SOLVENT; AMIDES; MILD; HYDROBORATION; ISOMERIZATION; INHIBITION, Saw an article supported by the CSIR, New DelhiCouncil of Scientific & Industrial Research (CSIR) – India [01(2942)/18/EMR-II]; MHRD; DST/INSPIRE fellowship [IF160793]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Singh, A; Maji, A; Joshi, M; Choudhury, AR; Ghosh, K. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. SDS of cas: 105-13-5

Base-metal catalysts Co1, Co2 and Co3 were synthesized from designed pincer ligands L-1, L-2 and L-3 having NNN donor atoms respectively. Co1, Co2 and Co3 were characterized by IR, UV-Vis. and ESI-MS spectroscopic studies. Single crystal X-ray diffraction studies were investigated to authenticate the molecular structures of Co1 and Co3. Catalysts Col, Co2 and Co3 were utilized to study the dehydrogenative activation of alcohols for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines. Under optimized reaction conditions, a broad range of substrates including alcohols, anilines and ketones were exploited. A series of control experiments for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines were examined to understand the reaction pathway. ESI-MS spectral studies were investigated to characterize cobalt-alkoxide and cobalt-hydride intermediates. Reduction of styrene by evolved hydrogen gas during the reaction was investigated to authenticate the dehydrogenative nature of the catalysts. Probable reaction pathways were proposed for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines on the basis of control experiments and detection of reaction intermediates.

SDS of cas: 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Singh, A; Maji, A; Joshi, M; Choudhury, AR; Ghosh, K or send Email.

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Recommanded Product: 105-13-5. Zeng, M; Lou, CL; Xue, JW; Jiang, HW; Li, KW; Chen, ZQ; Fu, ST; Yin, GC in [Zeng, Miao; Lou, Chenlin; Xue, Jing-Wen; Jiang, Hongwu; Li, Kaiwen; Chen, Zhuqi; Fu, Shitao; Yin, Guochuan] Huazhong Univ Sci & Technol, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Mat Chem Energy Convers & Storage, Sch Chem & Chem Engn,Minist Educ, Wuhan 430074, Peoples R China published Palladium (II)-catalyzed homogeneous alcohol oxidations: Disclosing the crucial contribution of palladium nanoparticles in catalysis in 2021, Cited 35. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Versatile redox catalysts play the significant roles in alcohol oxidations, in which the mechanisms for homogeneous and heterogeneous alcohol oxidations are generally different. This work introduced a Lewis acid (LA) promoted homogeneous alcohol oxidation with Pd (OAc)(2) catalyst by using oxygen balloon as the oxidant source. It was found that adding Lewis acid such as Sc (OTf)(3) significantly accelerated Pd (II)-catalyzed alcohol oxidations; notably, the time courses of oxidations monitored by GC and H-1 NMR disclosed that there existed two processes including the initial sluggish oxidation followed by a rapid oxidation. The promotional effect of Lewis acid was attributed to the formation of heterobimetallic Pd (II)/LA species, which improved the oxidizing power of the palladium (II) species, thus accelerating alcohol oxidation in the induction period. Correlating the sizes of in situ generated palladium nanoparticles with the time course of alcohol oxidation further disclosed that the loosely, spherically large nanoparticles, which were composed of many tiny nanoparticles having the size less than 10 nm, were responsible for the rapid oxidation, whereas those highly dispersed, tiny nanoparticles having the size less than 10 nm were not responsible for the rapid oxidation.

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