Author: tianli

Application In Synthesis of (4-Methoxyphenyl)methanol. Recently I am researching about MESOPOROUS MOLECULAR-SIEVE; METAL-SUPPORT INTERACTION; SELECTIVE HYDROGENATION; UNSATURATED ALDEHYDES; CINNAMYL ALCOHOL; ACTIVATED CARBON; HIGHLY EFFICIENT; CINNAMALDEHYDE; RUTHENIUM; COMPLEXES, Saw an article supported by the C1 Gas Refinery Program [2018M3D3A1A01018006]; National Research Foundation of Korea (NRF) – Ministry of Science, ICT, and Future Planning, Republic of Korea [2020M3H7A1098259]. Published in ELSEVIER SCIENCE INC in NEW YORK ,Authors: Padmanaban, S; Lee, Y; Yoon, S. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Selective hydrogenation of the carbonyl functional group of alpha,beta-unsaturated carbonyl compounds affords industrially important allylic alcohols. However, achieving the selective reduction of the carbonyl group in the presence of the activated olefinic group is challenging. Therefore, the development of a highly chemoselective, efficient, and recyclable catalyst for this transformation is greatly desirable from the industrial and environmental viewpoints. In this study, a Ru-immobilized bisphosphine-based porous organic polymer (Ru@PP-POP) was used as an efficient heterogeneous catalyst for chemoselective hydrogenation of cinnamaldehyde (CAL) to cinnamyl alcohol with high chemoselectivity (98%) and excellent recyclability. To the best of our knowledge, the catalyst, Ru@PP-POP showed a high turnover number (970) and a high turnover frequency (240h(1)) which is the best activity obtained using a phosphine based heterogeneous Ru-catalyst in this transformation. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

Application In Synthesis of (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Padmanaban, S; Lee, Y; Yoon, S or send Email.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

COA of Formula: C8H10O2. Authors Feng, XY; Pi, YH; Song, Y; Xu, ZW; Li, Z; Lin, WB in AMER CHEMICAL SOC published article about in [Feng, Xuanyu; Pi, Yunhong; Song, Yang; Xu, Ziwan; Lin, Wenbin] Univ Chicago, Dept Chem, Chicago, IL 60637 USA; [Pi, Yunhong; Li, Zhong] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

We report here the construction of two metal-organic frameworks (MOFs), Zr-6-Cu/Fe-1 and Zr-6–Cu/Fe-2, by integrating earth-abundant cuprous photosensitizers (Cu-PSs) and Fe catalysts for photocatalytic aerobic oxidation. Site isolation and pore confinement stabilize both Cu-PSs and Fe catalysts, while the proximity between active centers facilitates electron and mass transfer. Upon visible light irradiation and using O-2 as the only oxidant, Zr-6-Cu/Fe-1 and Zr-6-Cu/ Fe-2 efficiently oxidize alcohols and benzylic compounds to afford corresponding carbonyl products with broad substrate scopes, high turnover numbers of up to 500 with a 9.4-fold enhancement over homogeneous analogues, and excellent recyclability in four consecutive runs. Control experiments, spectroscopic evidence, and computational studies revealed the photooxidation mechanism: oxidative quenching of [Cu-PS]* by O-2 affords [Cu-II-PS], which efficiently oxidizes Fe-III-OH to generate a hydroxyl radical for substrate oxidation. This work highlights the potential of MOFs in promoting earth-abundant metal-based photocatalysis.

Welcome to talk about 105-13-5, If you have any questions, you can contact Feng, XY; Pi, YH; Song, Y; Xu, ZW; Li, Z; Lin, WB or send Email.. COA of Formula: C8H10O2

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

Product Details of 105-13-5. In 2021 CATAL SCI TECHNOL published article about GAS SHIFT REACTION; PRIMARY AMINES; NUCLEOPHILIC ALLYLATION; MOLECULAR COMPLEXITY; ALDEHYDES; RUTHENIUM; HYDROGEN; KETONES; CL; NITROARENES in [Biriukov, Klim O.; Vinogradov, Mikhail M.; Afanasyev, Oleg, I; Tsygankov, Alexey A.; Godovikova, Maria; Nelyubina, Yulia, V; Loginov, Dmitry A.; Chusov, Denis] Russian Acad Sci INEOS RAS, AN Nesmeyanov Inst Organoelement Cpds, Vavilova St 28, Moscow, Russia; [Vasilyev, Dmitry V.] Forschungszentrum Julich, Helmholtz Inst Erlangen Nurnberg Renewable Energy, Egerlandstr 3, D-91058 Erlangen, Germany; [Loginov, Dmitry A.; Chusov, Denis] GV Plekhanov Russian Univ Econ, 36 Stremyanny Per, Moscow 117997, Russia in 2021, Cited 71. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Herein, we present the first example of Os-catalyzed efficient reductive amination under water-gas shift reaction conditions. The developed catalytic systems are formed in situ in aqueous solutions, employ as small as 0.0625 mol% osmium and are capable of delivering reductive amination products for a broad range of aliphatic and aromatic carbonyl compounds and amines. The scope of the reaction, active catalytic systems, possible limitations of the method and DFT-supported mechanistic considerations are discussed in detail in the manuscript.

Product Details of 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Biriukov, KO; Vinogradov, MM; Afanasyev, OI; Vasilyev, DV; Tsygankov, AA; Godovikova, M; Nelyubina, YV; Loginov, DA; Chusov, D or send Email.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

Recently I am researching about CRYSTAL-STRUCTURES; DIOXIDOVANADIUM(V) COMPLEXES; ALKALI-METAL; OXIDOVANADIUM(IV) COMPLEXES; STRUCTURAL-CHARACTERIZATION; TARGETED SYNTHESIS; HYDROGEN-PEROXIDE; RECENT PROGRESS; OXIDATION; CHEMISTRY, Saw an article supported by the UGC, New DelhiUniversity Grants Commission, India. Category: alcohols-buliding-blocks. Published in ELSEVIER SCIENCE SA in LAUSANNE ,Authors: Kumar, A; Kurbah, SD; Syiemlieh, I; Dhanpat, SA; Borthakur, R; Lal, RA. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Six heterobimetallic alkali metal dioxidovanadium(V) coordination polymer complexes {[M-6{VO(mu-O)}(2)(mu-OH)(4)(mu(4)-slox/nph)].n DMF}(infinity) where M = Na, K, and Cs; n = 1 for (1), 0 for (2)-(6) of two dihydrazone ligands, disalicylaldehydeoxaloyldihydrazone (H4slox) and bis(2-hydroxy-1-naphthaldehyde)oxaloyldihydrazone (H4nph) are reported. All the complexes have been characterized by various physicochemical techniques such as elemental analyses, molar conductance, IR, NMR, UV-vis, and cyclic voltammetry. The IR, (HNMR)-H-1, and (CNMR)-C-13 spectral data suggest that the dihydrazones are coordinated through phenolate/naphtholate oxygen, enolate oxygen, and azine nitrogen atoms to the metal centres. The structure of complex {[Na-6{VO(mu-O)}(2)(mu-OH)(4)(mu(4)-slox)].DMF}(infinity) (1) is also determined by single crystal X-ray data, which revealed that the H(4)slox coordinated via all possible dative sites to metal centres as tetrabasic octadentate ligand. The vanadium metal centres adopted distorted square-pyramidal coordination geometries, and the sodium atoms are also in five coordination atmospheres. The electronic spectra of the complexes showed LMCT bands in addition to intra-ligand pi -> pi* and n -> pi* transitions. As evident from the cyclic voltammetry, the complexes showed two metal centred electron transfer reactions {[((VVV)-V-V(slox)(2-)/(VVIV)-V-V(slox)(3-)] and [((VVIV)-V-V(slox)(3-)/(VVIV)-V-V(slox)(4-)]}, in addition to the ligand centred electron transfer reactions. Further, bovine serum albumin (BSA interaction studies of the complexes {[Na (6){VO(mu-O)} (2)(mu-OH) (4)(mu(4)-slox)].DMF} (infinity) (1) and [Na-6{VO(mu-O)}(2)(mu-OH)(4)(mu(4)nph)](infinity) (4) revealed strong binding affinity. Moreover, the catalytic studies of the complexes (1) and (4) were found to be effective for the oxidation of alcohols into their corresponding aldehydes and ketones and bromination of some organic substrates in the presence of H2O2 as an oxidizing agent.

Category: alcohols-buliding-blocks. Welcome to talk about 105-13-5, If you have any questions, you can contact Kumar, A; Kurbah, SD; Syiemlieh, I; Dhanpat, SA; Borthakur, R; Lal, RA or send Email.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

Recommanded Product: 105-13-5. Authors Ryan, RYM; Fernandez, A; Wong, Y; Miles, JJ; Cock, IE in NATURE RESEARCH published article about in [Ryan, Rachael Y. M.; Wong, Yide; Miles, John J.] James Cook Univ, Australian Inst Trop Hlth & Med AITHM, Cairns, Qld 4878, Australia; [Ryan, Rachael Y. M.; Wong, Yide; Miles, John J.] James Cook Univ, Ctr Mol Therapeut, Cairns 4878, Australia; [Ryan, Rachael Y. M.; Fernandez, Alejandra; Cock, Ian E.] Griffith Univ, Sch Environm & Sci, Brisbane, Qld 4111, Australia; [Wong, Yide; Miles, John J.] James Cook Univ, Ctr Trop Bioinformat & Mol Biol, Cairns 4878, Australia; [Fernandez, Alejandra; Cock, Ian E.] Griffith Univ, Environm Futures Res Inst, Brisbane, Qld 4111, Australia in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Bark from the Handroanthus impetiginosus (Mart. ex DC.) Mattos (Bignoniaceae) tree has long been used in traditional South American healing practises to treat inflammation. However, its anti-inflammatory activity has not been closely examined. Here we use chemical extraction, qualitative phytochemical examination, toxicity testing and quantitative examination of anti-inflammatory activity on human cells ex vivo. All extracts were found to be nontoxic. We found different extracts exhibited unique cytokine profiles with some extracts outperforming a positive control used in the clinic. These results verify the immunomodulatory activity of Handroanthus impetiginosus (Mart. ex DC.) Mattos (Bignoniaceae) tree bark-derived compounds. Collectively, combining a lack of toxicity and potency in human immune cells supports further fractionation and research.

Recommanded Product: 105-13-5. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

An article Effect of the ancillary ligand in N-heterocyclic carbene iridium(III) catalyzed N-alkylation of amines with alcohols WOS:000672701700013 published article about ONE-POT SYNTHESIS; SELECTIVE ALKYLATION; EFFICIENT; COMPLEX; ANILINES; SUBSTITUTION; OXIDATION; AMIDES in [Feng, Xinshu; Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Guangzhou 510006, Peoples R China in 2021, Cited 40. Name: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A series of air-stable N-heterocyclic carbene (NHC) Ir(III) complexes (Ir1-6), bearing various combinations of chlorine, pyridine and NHC ligands, were assayed for the N-alkylation of amines with alcohols. It was found that Ir3, with two monodentate 1,3-bis-methyl-imidazolylidene (IMe) ligands, emerged as the most active complex. A large variety of amines and primary alcohols were efficiently converted into mono-N-alkylated amines in 53-96% yields. As a special highlight, for the challenging MeOH, selective N-monomethylation could be achieved using KOH as a base under an air atmosphere. Moreover, this catalytic system was successfully applied to the gram-scale synthesis of some valuable compounds. (C) 2021 Elsevier Ltd. All rights reserved.

Name: (4-Methoxyphenyl)methanol. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

An article Vanadium C-scorpionate supported on mesoporous aptes-functionalized SBA-15 as catalyst for the peroxidative oxidation of benzyl alcohol WOS:000652645700004 published article about CYCLOHEXANE OXIDATION; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; HIGHLY EFFICIENT; METAL-COMPLEXES; II COMPLEX; SOLVENT; SILICA; DESULFURIZATION in [Correia, Luis M. M.; Soliman, Mohamed M. A.; Alegria, Elisabete C. B. A.] Inst Politecn Lisboa, Inst Super Engn Lisboa, Dept Engn Quim, R Conselheiro Emidio Navarro 1, P-1959007 Lisbon, Portugal; [Correia, Luis M. M.; Soliman, Mohamed M. A.; Martins, Luisa M. D. R. S.; Pombeiro, Armando J. L.; Alegria, Elisabete C. B. A.] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, Av Rovisco Pais, P-1049001 Lisbon, Portugal; [Correia, Luis M. M.; Soliman, Mohamed M. A.; Martins, Luisa M. D. R. S.; Pombeiro, Armando J. L.; Alegria, Elisabete C. B. A.] Univ Lisbon, Inst Super Tecn, Dept Engn Quim, Av Rovisco Pais, P-1049001 Lisbon, Portugal; [Granadeiro, Carlos M.; Balula, Salete S.] Univ Porto, Dept Quim & Bioquim, LAQV REQUIMTE, Fac Ciencias, Rua Campo Alegre S-N, P-4169007 Porto, Portugal in 2021, Cited 62. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: 105-13-5

The neutral trichloro[hydrotris(1-pyrazolyl)methane]vanadium(III) [VCl3(Tpm)] (Tpm = HC(pz)(3); pz = pyrazolyl) C-scorpionate complex was immobilized on amine-functionalized mesoporous silica (aptesSBA-15) via an impregnation method forming the [VCl3(Tpm)]@aptesSBA-15 composite. The immobilization of the vanadium compound was confirmed by several characterization techniques, namely SEM/EDS, powder XRD, FT-IR/ATR, ICP and BET surface area analysis, revealing the successful incorporation of the complex, and confirming the structural and morphological preservation of the porous support and the vanadium complex. The vanadium composite was tested as heterogeneous catalyst for the peroxidative oxidation of benzyl alcohol under mild conditions and its catalytic performance was compared to that of the analogous homogeneous [VCl3(Tpm)] complex. The catalytic studies were extended to other substrates. The effect of various parameters, such as amount and type of oxidant, catalyst and additives, temperature and reaction time were investigated allowing to reach overall yields of ca. 60% and turnover numbers (TONs) up to ca. 7.6 x 10(3). The results obtained demonstrated the higher performance of the heterogeneous catalyst using much less [VCl3(Tpm)] complex under a solvent-free system. Furthermore, consecutive reaction cycles could be performed, showing its recycling capacity. Structural stability was also investigated, indicating the viability of the vanadium C-scorpionate composite as catalyst for other oxidative reactions with high industrial interest.

Recommanded Product: 105-13-5. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

I found the field of Chemistry very interesting. Saw the article alpha-Alkylation of arylacetonitriles with primary alcohols catalyzed by backbone modified N-heterocyclic carbene iridium(I) complexes published in 2021. COA of Formula: C8H10O2, Reprint Addresses Gulcemal, S (corresponding author), Ege Univ, Dept Chem, TR-35100 Izmir, Turkey.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A series of backbone-modified N-heterocyclic carbene (NHC) complexes of iridium(I) (1d-f) have been synthesized and characterized. The electronic properties of the NHC ligands have been assessed by comparison of the IR carbonyl stretching frequencies of the in situ prepared [IrCl(CO)(2)(NHC)] complexes in CH2Cl2. These new complexes (1d-f), together with previously prepared 1a-c, were applied as catalysts for the alpha-alkylation of arylacetonitriles with an equimolar amount of primary alcohols or 2-aminobenzyl alcohol. The catalytic activities of these complexes could be controlled by modifying the N-substituents and backbone of the NHC ligands. The NHC-Ir-I complex 1f bearing 4-methoxybenzyl substituents on the N-atoms and 4-methoxyphenyl groups at the 4,5-positions of imidazole exhibited the highest catalytic activity in the alpha-alkylation of arylacetonitriles with primary alcohols. Various alpha-alkylated nitriles and aminoquinolines were obtained in high yields through a borrowing hydrogen pathway by using 0.1 mol% 1f and a catalytic amount of KOH (5 mol%) under an air atmosphere within significantly short reaction times.

COA of Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

An article Enantioselective Protonation of Cyclic Carbonyl Ylides by Chiral Lewis Acid Assisted Alcohols WOS:000658032300001 published article about 1,3-DIPOLAR CYCLOADDITION REACTIONS; ASYMMETRIC CYCLOADDITIONS; RHODIUM; CARBENOIDS; DIAZOESTERS; COMPLEXES; CATALYSTS in [Toda, Yasunori; Yoshida, Takayuki; Arisue, Kaoru; Kikuchi, Ayaka; Suga, Hiroyuki] Shinshu Univ, Fac Engn, Dept Mat Chem, 4-17-1 Wakasato, Nagano 3808553, Japan; [Fukushima, Kazuaki; Esaki, Hiroyoshi] Hyogo Coll Med, Dept Chem, 1-1 Mukogawa Cho, Nishinomiya, Hyogo 6638501, Japan in 2021, Cited 60. Safety of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Chiral Lewis acid-catalyzed asymmetric alcohol addition reactions to cyclic carbonyl ylides generated from N-(alpha-diazocarbonyl)-2-oxazolidinones featuring a dual catalytic system are reported. Construction of a chiral quaternary heteroatom-substituted carbon center was accomplished in which the unique heterobicycles were obtained in good yields with high stereoselection. The alcohol adducts were successfully converted to optically active oxazolidine-2,4-diones by hydrolysis. Mechanistic studies by DFT calculations revealed that alcohols could be activated by Lewis acids, enabling enantioselective protonation of the carbonyl ylides.

Safety of (4-Methoxyphenyl)methanol. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

I found the field of Chemistry very interesting. Saw the article Synthesis of the C1-C16 fragment of bryostatin for incorporation into 20,20-fluorinated analogues published in 2021. Safety of (4-Methoxyphenyl)methanol, Reprint Addresses Thomas, EJ (corresponding author), Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

The stereoselective synthesis of a carboxylic acid ester corresponding to the C1 -C16 fragment of bryostatin, with 4-methoxybenzyl (PMB) protection for the 7-hydroxyl group, is reported. The key steps included a Horner-Wadsworth-Emmons reaction between (5R)-3-[ (E)-2-tri- isop ropyls ilyloxy ethylidene]-6-(4-methoxybenzyloxy)-5-triethylsilyloxyhexanal and dimethyl (4,5,6R,85)-10-hydroxy-6,8-di-O-isopropylidene 4 (4 methoxybenzyloxy)-3,3-dimethyl-2-oxodecan-1-yl phosphonate, that gave the corresponding (E)-alkene, followed by selective cleavage of the triethylsilyl ether and cyclisation to give the required 2,6-cis-disubstituted 4-[(Z)-tri-isopropylsilyloxyethylide]tetrahydropyran. Oxidation of the primary alcohol gave the corresponding carboxylic acid that was converted into the required allyl ester. (C) 2020 Elsevier Ltd. All rights reserved.

Welcome to talk about 105-13-5, If you have any questions, you can contact Mears, PR; Thomas, EJ or send Email.. Safety of (4-Methoxyphenyl)methanol

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts