Month: December 2022

All-purpose repellent mixtures as clothing treatments against chiggers was written by Gilbert, I. H.;Gouck, H. K.. And the article was included in Florida Entomologist in 1953.Application In Synthesis of 2-Butyl-2-ethylpropane-1,3-diol The following contents are mentioned in the article:

A mixture containing benzyl benzoate 29.7, butylacetanilide 29.7, 2-butyl-2-ethyl-1,3-propanediol 29.7, and lindane 1.0% applied at the rate of 3.6 g./sq. ft. of cloth was the most effective repellant of 11 reported. With an average of 4 soap and water washings, 100% protection was maintained. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Application In Synthesis of 2-Butyl-2-ethylpropane-1,3-diol).

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Application In Synthesis of 2-Butyl-2-ethylpropane-1,3-diol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Simple H₂-free hydrogenation of unsaturated monoterpenoids catalyzed by Raney nickel was written by Philippov, Alexey A.;Chibiryaev, Andrey M.;Martyanov, Oleg N.. And the article was included in Mendeleev Communications in 2019.Application of 106-21-8 The following contents are mentioned in the article:

A series of monoterpenoids (citral, carvone, menthone, camphor) as well as cyclohexanone and hex-5-en-2-one were subjected to transfer hydrogenation with PrⁱOH/Raney nickel system at 82 or 150 °C. Among monoterpenoids, citral and carvone underwent full conversion at 82 °C within 5 h. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application of 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Application of 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Field tests of selected repellents against the American dog tick was written by Cole, Moses M.;Lloyd, George W.. And the article was included in Journal of Economic Entomology in 1951.COA of Formula: C9H20O2 The following contents are mentioned in the article:

Dibutyl adipate, a mixture of 2-butyl-2-ethyl-1,3-propanediol (I), benzyl benzoate (II), and N-butylacetanilide (III), a mixture of N-butyl-4-cyclohexane-1,2-dicarboximide (IV), undecylenic acid (V), and III, and a mixture of IV, V, I, III, and II gave 97-99.6% repellency against Dermacentor variabilis. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4COA of Formula: C9H20O2).

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.COA of Formula: C9H20O2

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Discovery of a New Boron-Containing Antifungal Agent, 5-Fluoro-1,3-dihydro-1-hydroxy-2,1-benzoxaborole (AN2690), for the Potential Treatment of Onychomycosis was written by Baker, Stephen J.;Zhang, Yong-Kang;Akama, Tsutomu;Lau, Agnes;Zhou, Huchen;Hernandez, Vincent;Mao, Weimin;Alley, M. R. K.;Sanders, Virginia;Plattner, Jacob J.. And the article was included in Journal of Medicinal Chemistry in 2006.Electric Literature of C7H6BFO2 The following contents are mentioned in the article:

A structure-activity relationship investigation for a more efficacious therapy to treat onychomycosis, a fungal infection of the toe and fingernails, led to the discovery of a boron-containing small mol., AN2690 (I), which is currently in clin. trials for onychomycosis topical treatment. This study involved multiple reactions and reactants, such as 7-Fluoro-1,3-dihydro-2,1-benzoxaborol-1-ol (cas: 174671-93-3Electric Literature of C7H6BFO2).

7-Fluoro-1,3-dihydro-2,1-benzoxaborol-1-ol (cas: 174671-93-3) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Electric Literature of C7H6BFO2

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Discovery of a New Boron-Containing Antifungal Agent, 5-Fluoro-1,3-dihydro-1-hydroxy-2,1-benzoxaborole (AN2690), for the Potential Treatment of Onychomycosis was written by Baker, Stephen J.;Zhang, Yong-Kang;Akama, Tsutomu;Lau, Agnes;Zhou, Huchen;Hernandez, Vincent;Mao, Weimin;Alley, M. R. K.;Sanders, Virginia;Plattner, Jacob J.. And the article was included in Journal of Medicinal Chemistry in 2006.COA of Formula: C7H6BFO2 The following contents are mentioned in the article:

A structure-activity relationship investigation for a more efficacious therapy to treat onychomycosis, a fungal infection of the toe and fingernails, led to the discovery of a boron-containing small mol., AN2690 (I), which is currently in clin. trials for onychomycosis topical treatment. This study involved multiple reactions and reactants, such as 7-Fluoro-1,3-dihydro-2,1-benzoxaborol-1-ol (cas: 174671-93-3COA of Formula: C7H6BFO2).

7-Fluoro-1,3-dihydro-2,1-benzoxaborol-1-ol (cas: 174671-93-3) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.COA of Formula: C7H6BFO2

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

New Furopyridines Containing Pyridoxal and Pyrazolone Fragments was written by Kibardina, L. K.;Trifonov, A. V.;Burilov, A. R.;Pudovik, M. A.. And the article was included in Russian Journal of General Chemistry in 2018.Application of 65-22-5 The following contents are mentioned in the article:

Reactions of pyridoxal hydrochloride with 5-pyrazolone derivatives in alc. medium in the presence of concentrated hydrochloric acid led to the formation of new pyrazolones with pyridoxal fragments in the mol. The corresponding diarylmethanes were formed when using pyridoxal and pyrazolone in a 1: 2 ratio. This study involved multiple reactions and reactants, such as 3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5Application of 65-22-5).

3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Application of 65-22-5

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Bioorthogonal control of the phosphorescence and singlet oxygen photosensitization properties of iridium(III) tetrazine complexes was written by Leung, Peter Kam-Keung;Lee, Lawrence Cho-Cheung;Yeung, Herman Ho-Yin;Io, Kai-Wa;Lo, Kenneth Kam-Wing. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2021.Recommanded Product: 923-61-5 The following contents are mentioned in the article:

In this work, we demonstrate bioorthogonal control of the phosphorescence and singlet oxygen photosensitization properties of new iridium(III) tetrazine complexes by different reaction partners; the system was exploited for organelle-specific staining and modulated photocytotoxic activity applications. This study involved multiple reactions and reactants, such as (2R)-3-(((2-Aminoethoxy)(hydroxy)phosphoryl)oxy)propane-1,2-diyl dipalmitate (cas: 923-61-5Recommanded Product: 923-61-5).

(2R)-3-(((2-Aminoethoxy)(hydroxy)phosphoryl)oxy)propane-1,2-diyl dipalmitate (cas: 923-61-5) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Recommanded Product: 923-61-5

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Quantitative gas chromatography of insect repellent mixture M-1960 was written by Acree, Fred Jr.;Beroza, Morton. And the article was included in Journal of Economic Entomology in 1962.Application of 115-84-4 The following contents are mentioned in the article:

Repellents in the M-1960 clothing impregnant, 2-butyl-2-ethyl-1,3-propanediol, N-butylacetanilide, and benzyl benzoate, can be analyzed quant. by gas chromatography. The analyses are conducted at 225° using 200 γ of each repellent on an 8-foot column of 5% Dow-Corning Silicone 550 on Haloport-F with a thermal conductivity detector. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Application of 115-84-4).

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Application of 115-84-4

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Visible light induced hydrophosphinylation of unactivated alkenes catalyzed by salicylaldehyde was written by Yuan, Zeqin;Wang, Simin;Li, Miaomiao;Chen, Tian;Fan, Jiaye;Xiong, Fuying;Li, Qianggen;Hu, Ping;Wang, Bi-Qin;Cao, Peng;Li, Yang. And the article was included in Green Chemistry in 2021.Recommanded Product: 65-22-5 The following contents are mentioned in the article:

An air and water insensitive visible light induced hydrophosphinylation of unactivated alkenes is reported. A small amount of a simple and cheap compound, salicylaldehyde, is used as a photosensitizer. The reaction is carried out in a basic aqueous solution which enables the deprotonated salicylaldehyde to show visible light absorption. This study involved multiple reactions and reactants, such as 3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5Recommanded Product: 65-22-5).

3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Recommanded Product: 65-22-5

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Preparation of carboxyl-terminated polyester resin for two-component matting superdurable weather resistant powder coatings was written by He, Tao;Gu, Yuxin;Xie, Jing;Lin, Xien;Ruan, Deliang;Liang, Baorong. And the article was included in Tuliao Gongye in 2014.Category: alcohols-buliding-blocks The following contents are mentioned in the article:

This article has described the preparation of a carboxyl-terminated polyester resin based on isophthalic acid for two-component matting super durable powder coatings. The prepared powder coating showed a matting effect with only 21∼26 gloss. The coating was featured by its lower gloss, smooth appearance and outstanding weather durability. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Category: alcohols-buliding-blocks).

2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts