Month: December 2021

In 2021 CATAL SCI TECHNOL published article about PONNDORF-VERLEY REDUCTION; EPOXIDATION CATALYSTS; STRUCTURAL-CHARACTERIZATION; TRANSFER HYDROGENATION; OLEFIN POLYMERIZATION; QUINONE METHIDES; ACTIVE-SITES; BETA ZEOLITE; EFFICIENT; ETHERIFICATION in [Garg, Shipra; Unruh, Daniel K.; Krempner, Clemens] Texas Tech Univ, Dept Chem & Biochem, Mem Dr & Boston, Lubbock, TX 79409 USA in 2021, Cited 53. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Safety of (4-Methoxyphenyl)methanol

The polyhedral oligosilsesquioxane complexes, {[(isobutyl)(7)Si7O12]ZrOPri center dot(HOPri)}(2) (I), {[(cyclohexyl)(7)Si7O12]ZrOPri center dot(HOPri)}(2) (II), {[(isobutyl)(7)Si7O12]HfOPri center dot(HOPri)}(2) (III) and {[(cyclohexyl)(7)Si7O12]HfOPri center dot(HOPri)}(2) (IV), were synthesized in good yields from the reactions of M(OPri)(4) (M = Zr, Hf) with R-POSS(OH)(3) (R = isobutyl, cyclohexyl), resp. I-IV were characterized by H-1, C-13 and Si-29 NMR spectroscopy and their dimeric solid-state structures were confirmed by X-ray analysis. I-IV catalyze the reductive etherification of 2-hydroxy- and 4-hydroxy and 2-methoxy and 4-methoxybenzaldehyde and vanillin to their respective isopropyl ethers in isopropanol as a green solvent and reagent. I-IV are durable and robust homogeneous catalysts operating at temperatures of 100-160 degrees C for days without significant loss of catalytic activity. Likewise, I-IV selectively catalyze the conversion of 5-hydroxymethylfurfural (HMF) into 2,5-bis(isopropoxymethyl)furane (BPMF), a potentially high-performance fuel additive. Similar results were achieved by using a combination of M(OPri)(4) and ligand R-POSS(OH)(3) as a catalyst system demonstrating the potential of this in situ approach for applications in biomass transformations. A tentative reaction mechanism for the reductive etherification of aldehydes catalysed by I-IV is proposed.

Welcome to talk about 105-13-5, If you have any questions, you can contact Garg, S; Unruh, DK; Krempner, C or send Email.. Safety of (4-Methoxyphenyl)methanol

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Recently I am researching about BINDING MODE ANALYSIS; DIHYDROPYRIDINE DERIVATIVES; ANTIMOSQUITO PROPERTIES; MULTIDRUG-RESISTANT; LARVICIDAL ACTIVITY; INHA INHIBITORS; DESIGN; 1,4-DIHYDROPYRIDINES; POLYMORPHISM; DISCOVERY, Saw an article supported by the Deanship of Scientific Research, King Faisal University, Kingdom of Saudi Arabia [180128]. HPLC of Formula: C8H10O2. Published in BENTHAM SCIENCE PUBL LTD in SHARJAH ,Authors: Venugopala, KN; Deb, PK; Pillay, M; Chopra, D; Chandrashekharappa, S; Morsy, MA; Aldhubiab, BE; Attimarad, M; Nair, AB; Sreeharsha, N; Kandeel, M; Venugopala, R; Mohanlall, V. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Background: Tuberculosis remains one of the most deadly infectious diseases worldwide due to the emergence of multi-drug resistance (MDR) and extensively drug resistance (XDR) strains of Mycobacterium tuberculosis (MTB). Aims: Currently, available drugs are getting resistant and toxic. Hence, there is an urgent need for the development of potent molecules to treat tuberculosis. Materials and Methods: Herein, the screening of a total of eight symmetrical 1,4-dihydropyridine (1,4-DHP) derivatives (4a-4h) was carried out for whole-cell anti-TB activity against the susceptible H37Rv and MDR strains of MTB. Results and Discussion: Most of the compounds exhibited moderate to excellent activity against the susceptible H37Rv. Moreover, the most promising compound 4f (against H37Rv) having para-trifluoromethyl phenyl group at 4-position and bis para-methoxy benzyl ester group at 3- and 5-positions of 1,4- dihydropyridine pharmacophore, exhibited no toxicity, but demonstrated weak activity against MTB strains resistant to isoniazid and rifampicin. In light of the inhibitory profile of the title compounds, enoyl-acyl carrier protein reductase (InhA) appeared to be the appropriate molecular target. A docking study of these derivatives against InhA receptor revealed favorable binding interactions. Further, in silico predicted ADME properties of these compounds 4a-4h were found to be in the acceptable ranges, including satisfactory Lipinski’s rule of five, thereby indicating their potential as drug-like molecules. Conclusion: In particular, the 1,4-DHP derivative 4f can be considered an attractive lead molecule for further exploration and development of more potent anti-TB agents as InhA inhibitors.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Venugopala, KN; Deb, PK; Pillay, M; Chopra, D; Chandrashekharappa, S; Morsy, MA; Aldhubiab, BE; Attimarad, M; Nair, AB; Sreeharsha, N; Kandeel, M; Venugopala, R; Mohanlall, V or concate me.. HPLC of Formula: C8H10O2

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Alcohol – Wikipedia,
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An article Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis WOS:000611083700061 published article about FRIEDEL-CRAFTS REACTIONS; ONE-POT SYNTHESIS; COUPLING REACTIONS; ALKYL-HALIDES; OXIDATIVE ADDITION; ZINC REAGENTS; ARYL HALIDES; DIARYLMETHANES; BROMIDES; ETHERS in [Guo, Peng; Wang, Ke; Jin, Wen-Jie; Xie, Hao; Qi, Liangliang; Liu, Xue-Yuan; Shu, Xing-Zhong] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China in 2021, Cited 104. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. SDS of cas: 105-13-5

Catalytic transformation of alcohols via metal-catalyzed cross-coupling reactions is very important, but it typically relies on a multistep procedure. We here report a dynamic kinetic cross-coupling approach for the direct functionalization of alcohols. The feasibility of this strategy is demonstrated by a nickel-catalyzed cross-electrophile arylation reaction of benzyl alcohols with (hetero)aryl electrophiles. The reaction proceeds with a broad substrate scope of both coupling partners. The electron-rich, electron-poor, and ortho-/meta-/para-substituted (hetero)aryl electrophiles (e.g., Ar-OTf, Ar-I, Ar-Br, and inert Ar-Cl) all coupled well. Most of the functionalities, including aldehyde, ketone, amide, ester, nitrile, sulfone, furan, thiophene, benzothiophene, pyridine, quinolone, Ar-SiMe3, Ar-Bpin, and Ar-SnBu3, were tolerated. The dynamic nature of this method enables the direct arylation of benzylic alcohol in the presence of various nucleophilic groups, including nonactivated primary/secondary/tertiary alcohols, phenols, and free indoles. It thus offers a robust alternative to existing methods for the precise construction of diarylmethanes. The synthetic utility of the method was demonstrated by a concise synthesis of biologically active molecules and by its application to peptide modification and conjugation. Preliminary mechanistic studies revealed that the reaction of in situ formed benzyl oxalates with nickel, possibly via a radical process, is an initial step in the reaction with aryl electrophiles.

Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.. SDS of cas: 105-13-5

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Alcohol – Wikipedia,
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COA of Formula: C8H10O2. Authors Bains, AK; Yadav, A; Adhikari, D in AMER CHEMICAL SOC published article about in [Bains, Amreen K.; Adhikari, Debashis] Indian Inst Sci Educ & Res IISER Mohali, Dept Chem Sci, Ajitgarh 140306, Punjab, India; [Yadav, Ankit] Indian Inst Sci Educ & Res IISER Mohali, Dept Earth & Environm Sci, Ajitgarh 140306, Punjab, India in 2021, Cited 35. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Herein, we report a combination of pyrenedione (PD) and KO’Bu to achieve facile alcohol dehydrogenation under visible-light excitation, where aerobic oxygen is utilized as the terminal oxidant. The resulting carbonyl compound can be easily converted to vinyl nitriles in a single-pot reaction, at 60 degrees C in 6-8 h. This environmentally benign, organocatalytic approach has distinct advantages over transition-metal-catalyzed a-olefination of nitriles, which often operate at a significantly higher temperature for an extended reaction time.

COA of Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

I found the field of Chemistry very interesting. Saw the article Copper-mediated simple and direct aerobic oxidative esterification of arylacetonitriles with alcohols/phenols published in 2021. Recommanded Product: 105-13-5, Reprint Addresses Dong, JY (corresponding author), Hunan First Normal Univ, Dept Educ Sci, Changsha 410205, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A simple and direct aerobic oxidative esterification reaction of arylacetonitriles with alcohols/phenols is achieved in the presence of a copper salt and molecular oxygen, which produces a broad range of aryl carboxylic acid esters in good to high yields. Copper salt plays multiple roles in the transformation, which allows the oxygenation of C-H bond, cleavage of inert C-C bond, and formation of C-O bond in one pot without the assistance of any of the acids, bases, ligands, and so on. The reaction provides a simple, direct, and efficient protocol towards functionalized esters, especially aryl benzoates, from readily available starting materials.

Recommanded Product: 105-13-5. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Alcohol – Wikipedia,
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Recently I am researching about ONE-POT SYNTHESIS; HOMOPHTHALIC ANHYDRIDE; 3-COMPONENT REACTION; RADICAL CYCLIZATION; TANDEM CATALYSIS; BOND; FUNCTIONALIZATION; BENZAMIDES; ACIDS; HYDROXYALKYLATION, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21672028, 21602019]; Jiangsu Key Laboratory of Advanced Catalytic Materials Technology [BM2012110]. Category: alcohols-buliding-blocks. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Li, YT; Sun, S; Cheng, J; Yu, JT. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A radical-initiated cascade addition and cyclization of N-allylbenzamides with simple ethers to construct ether-substituted dihydroisoquinolinones was performed in the presence of CuI. The cleavage of the sp(3) C-H bond in ether and the sp(2) C-H bond in phenyl was involved in this reaction. Moreover, the arylalkylation of N-allylanilines was also realized under similar reaction conditions, providing ether-functionalized indolines in good to moderate yields.

Welcome to talk about 105-13-5, If you have any questions, you can contact Li, YT; Sun, S; Cheng, J; Yu, JT or send Email.. Category: alcohols-buliding-blocks

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Alcohol – Wikipedia,
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Recently I am researching about BIS(INDOLYL)METHANES; ACTIVATION; TRANSITION; FUNCTIONALIZATION; NANOPARTICLES; ALKALOIDS, Saw an article supported by the Vietnam National Foundation for Science and Technology Development (NAFOSTED)National Foundation for Science & Technology Development (NAFOSTED) [104.01-2017.320]. Published in ELSEVIER in AMSTERDAM ,Authors: Nguyen, NK; Ha, MT; Bui, HY; Trinh, QT; Tran, BN; Nguyen, VT; Hung, TQ; Dang, TT; Vu, XH. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. COA of Formula: C8H10O2

Bis(3-indolyl)methanes (BIM) are highly valuable and appear in the core structure of many natural products and pharmacologically active compounds (anticancer, anti-inflammatory, antiobesity, antimetastatic, antimicrobial, etc.). Herein, we have disclosed an air stable and highly efficient CuFe2O4 heterogeneous catalyst for alkylation of indoles with alcohols to give bis(3-indolyl)methanes in very good yields. The CuFe2O4 catalyst has been found to be magnetically recycled at least five times without losing significant catalytic activity.

COA of Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

HPLC of Formula: C8H10O2. In 2021 ANGEW CHEM INT EDIT published article about SELECTIVE DEUTERATION; LABELED COMPOUNDS; DEOXYGENATION; DEUTERIUM; D2O; TRITIATION; EFFICIENT; FLUORINE; ALCOHOLS; ROUTE in [Ou, Wei; Xiang, Xudong; Zou, Ru; Su, Chenliang] Shenzhen Univ, Int Collaborat Lab 2D Mat Optoelect Sci & Technol, Engn Technol Res Ctr 2D Mat Informat Funct Device, Inst Microscale Optoelect, Shenzhen 518060, Peoples R China; [Xu, Qing] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou, Zhejiang, Peoples R China; [Loh, Kian Ping] Natl Univ Singapore, Dept Chem, 3 Sci Dr 3, Singapore 117543, Singapore in 2021, Cited 50. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Site-specific incorporation of deuterium into drug molecules to study and improve their biological properties is crucial for drug discovery and development. Herein, we describe a palladium-catalyzed room-temperature deuterogenolysis of carbon-oxygen bonds in alcohols and ketones with D-2 balloon for practical synthesis of deuterated pharmaceuticals and chemicals with benzyl-site (sp(3) C-H) D-incorporation. The highlights of this deoxygenative deuteration strategy are mild conditions, broad scope, practicability and high chemoselectivity. To enable the direct use of D2O, electrocatalytic D2O-splitting is adapted to in situ supply D-2 on demand. With this system, the precise incorporation of deuterium in the metabolic position (benzyl-site) of ibuprofen is demonstrated in a sustainable and practical way with D2O.

Welcome to talk about 105-13-5, If you have any questions, you can contact Ou, W; Xiang, XD; Zou, R; Xu, Q; Loh, KP; Su, CL or send Email.. HPLC of Formula: C8H10O2

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Alcohol – Wikipedia,
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Name: (4-Methoxyphenyl)methanol. Authors Alam, MN; Dash, SR; Mukherjee, A; Pandole, S; Marelli, UK; Vanka, K; Maity, P in AMER CHEMICAL SOC published article about in [Alam, Md Nirshad; Mukherjee, Anirban; Pandole, Satish; Marelli, Udaya Kiran; Maity, Pradip] CSIR Natl Chem Lab, Organ Chem Div, Pune 411008, Maharashtra, India; [Alam, Md Nirshad; Dash, Soumya Ranjan; Marelli, Udaya Kiran; Vanka, Kumar] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India; [Dash, Soumya Ranjan; Vanka, Kumar] CSIR Natl Chem Lab, Phys & Mat Chem Div, Pune 411008, Maharashtra, India in 2021, Cited 55. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A thermal O-to-C [1,3]-rearrangement of alpha-hydroxy acid derived enol ethers was achieved under mild conditions. The 2-aminothiophenol protection of carboxylic acids facilitates formation of the [1,3] precursor and its thermal rearrangement via stabilization of a radical intermediate. Experimental and theoretical evidence for dissociative radical pair formation, its captodative stability via aminothiophenol, and a unique solvent effect are presented. The aminothiophenol was deprotected from rearrangement products as well as after derivatization to useful synthons.

Welcome to talk about 105-13-5, If you have any questions, you can contact Alam, MN; Dash, SR; Mukherjee, A; Pandole, S; Marelli, UK; Vanka, K; Maity, P or send Email.. Name: (4-Methoxyphenyl)methanol

Reference:
Alcohol – Wikipedia,
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Formula: C8H10O2. In 2021 ARAB J SCI ENG published article about AEROBIC OXIDATION; SELECTIVE OXIDATION; ALCOHOL OXIDATION; HYDROGENATION; EFFICIENT; NITROARENES; WATER; NANOCLUSTERS; GENERATION; SUZUKI in [Islam, Sayedul; Khan, Wahab] Bangladesh Univ Engn & Technol BUET, Fac Engn, Dept Chem, Dhaka 1000, Bangladesh in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

The dendritic ligand 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:1) 4a, 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:2) 4b, and 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (2:1) 4cbimetallic nanoparticles (NPs) were synthesized successfully by following the co-complexation route in which the desired molar ratio of Zn and Cu was confirmed by the obtained results of electron diffraction X-ray and X-ray fluorescence spectroscopy analysis. The average particle size of these NPs was detected as 15-20 nm from transmission electron microscopy investigations and agglomerate spherical surface morphology was found by scanning electron microscopy, whereas the face-centered cubic structure of these bimetallic NPs was observed by X-ray diffraction assessment. Also, the formation of the ligand was proven by IR,(HNMR)-H-1,(CNMR)-C-13, and elemental analysis. Remarkably, the chemoselective oxidation of aromatic alcohols to the corresponding aldehydes or ketones at 25 min and reduction of aromatic nitro substituents to the corresponding aniline at 20 min in aqueous medium at room temperature have been studied by the most effective catalyst Zn/Cu (2:1) 4cNPs among other molar ratios of Zn/Cu (1:1)4aand Zn/Cu (1:2) 4bNPs under atmospheric air (O-2) conditions with good to excellent yields. This green catalytic approach of Zn/Cu (2:1) 4cNPs catalytic was easily recovered by simple filtration and recycled at least five consecutive runs without a noticeable loss of its catalytic effectiveness.

Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts