Month: December 2021

An article Synthesis of Dendritic Ligand Assisted Zn/Cu Bimetallic Nanoparticles as a Highly Active Green Catalyst for Chemoselective Oxidation and Reduction Reaction WOS:000564504600011 published article about AEROBIC OXIDATION; SELECTIVE OXIDATION; ALCOHOL OXIDATION; HYDROGENATION; EFFICIENT; NITROARENES; WATER; NANOCLUSTERS; GENERATION; SUZUKI in [Islam, Sayedul; Khan, Wahab] Bangladesh Univ Engn & Technol BUET, Fac Engn, Dept Chem, Dhaka 1000, Bangladesh in 2021, Cited 46. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The dendritic ligand 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:1) 4a, 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:2) 4b, and 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (2:1) 4cbimetallic nanoparticles (NPs) were synthesized successfully by following the co-complexation route in which the desired molar ratio of Zn and Cu was confirmed by the obtained results of electron diffraction X-ray and X-ray fluorescence spectroscopy analysis. The average particle size of these NPs was detected as 15-20 nm from transmission electron microscopy investigations and agglomerate spherical surface morphology was found by scanning electron microscopy, whereas the face-centered cubic structure of these bimetallic NPs was observed by X-ray diffraction assessment. Also, the formation of the ligand was proven by IR,(HNMR)-H-1,(CNMR)-C-13, and elemental analysis. Remarkably, the chemoselective oxidation of aromatic alcohols to the corresponding aldehydes or ketones at 25 min and reduction of aromatic nitro substituents to the corresponding aniline at 20 min in aqueous medium at room temperature have been studied by the most effective catalyst Zn/Cu (2:1) 4cNPs among other molar ratios of Zn/Cu (1:1)4aand Zn/Cu (1:2) 4bNPs under atmospheric air (O-2) conditions with good to excellent yields. This green catalytic approach of Zn/Cu (2:1) 4cNPs catalytic was easily recovered by simple filtration and recycled at least five consecutive runs without a noticeable loss of its catalytic effectiveness.

Welcome to talk about 105-13-5, If you have any questions, you can contact Islam, S; Khan, W or send Email.. Product Details of 105-13-5

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Formula: C8H10O2. In 2020 CATAL SCI TECHNOL published article about FACILE SYNTHESIS; REACTANTS ACTIVATION; NO ADSORPTION; DOPED G-C3N4; EFFICIENT; NANOSHEETS; ZIRCONIA; REACTIVITY; VACANCIES; MECHANISM in [Wang, Jiadong; Chen, Ruimin; Yuan, Chaowei; Dong, Fan; Sun, Yanjuan] Chongqing Technol & Business Univ, Coll Environm & Resources, Chongqing Key Lab Catalysis & New Environm Mat, Chongqing 400067, Peoples R China; [Wang, Jiadong; Cui, Wen; He, Ye; Yuan, Chaowei; Sheng, Jianping; Li, Jieyuan; Dong, Fan; Sun, Yanjuan] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Res Ctr Environm Sci & Technol, Chengdu 611731, Peoples R China; [Cui, Wen] Southwest Petr Univ, Sch Mat Sci & Engn, Ctr New Energy Mat & Thchnol, Chengdu 610500, Peoples R China; [Zhan, Yuxin] Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China in 2020, Cited 60. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Graphitic carbon nitride (g-C3N4, CN for short) is a compelling visible-light responsive photocatalyst. However, its photocatalytic efficiency is low due to the random carrier transfer in planes and insufficient redox potential. Herein, we build oxygen functional group modified sodium-doped carbon nitride (OH/Na co-functionalized carbon nitride) to promote directional transfer of charge carriers for acceleration of separation and enhance redox potential for efficient oxidation of NO in air. Specifically, the function of sodium atoms could control the directional transfer of random carriers from the intralayer to the oxygen functional group-modified surface for the purpose of effectively reducing photogenerated electron-hole recombination. Meanwhile, the modification by oxygen-containing functional groups could adjust the band structure of CN, thereby increasing the oxidation-reduction potential of NO in the photocatalyst. The transformation pathways and reaction mechanism of photocatalytic NO oxidation on CN and OH/Na co-functionalized carbon nitride have also been explicated by ESR spectroscopy and in situ DRIFTS and compared. This work provides a new method for simultaneously controlling the random transfer of carriers and adjusting the energy band structure of CN to optimize its photocatalytic efficiency. It is also possible to extend this strategy to improve the performance of other 2D layered catalysts for photocatalytic oxidation.

Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Category: alcohols-buliding-blocks. Authors Aydin, BO; Anil, D; Demir, Y in WILEY-V C H VERLAG GMBH published article about in [Aydin, Busra O.; Anil, Derya] Ataturk Univ, Dept Chem, Fac Sci, Erzurum, Turkey; [Anil, Derya] Ataturk Univ, Tech Sci Vocat Sch, Dept Chem & Chem Proc Technol, Erzurum, Turkey; [Demir, Yeliz] Ardahan Univ, Nihat Delibalta Gole Vocat Sch, Dept Pharm Serv, Ardahan, Turkey in 2021, Cited 53. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Fused pyrimidines, especially pyrazolo[3,4-d]pyrimidines, are among the most preferred building blocks for pharmacology studies, as they exhibit a broad spectrum of biological activity. In this study, new derivatives of pyrazolo[3,4-d]pyrimidine were synthesized by alkylation of the N1 nitrogen atom. We synthesized 3-iodo-1H-pyrazolo[3,4-d]pyrimidin-4-amine 2 from commercially available aminopyrazolopyrimidine 1 using N-iodosuccinimide as an iodinating agent. The synthesis of compound 2 started with nucleophilic substitution of 3-iodo-1H-pyrazolo[3,4-d]pyrimidin-4-amine with R-X (X: -OMs, -Br, -Cl), affording N-alkylated pyrazolo[3,4-d]pyrimidine. We performed this synthesis using a weak inorganic base and the mild temperature was also used for a two-step procedure to generate N-alkylated pyrazolo[3,4-d]pyrimidine derivatives. Also, all compounds were tested for their ability to inhibit acetylcholinesterase (AChE) and the human carbonic anhydrase (hCA) isoforms I and II, with K-i values in the range of 15.41 +/- 1.39-63.03 +/- 10.68 nM for AChE, 17.68 +/- 1.92-66.27 +/- 5.43 nM for hCA I, and 8.41 +/- 2.03-28.60 +/- 7.32 nM for hCA II. Notably, compound 10 was the most selective and potent CA I inhibitor with a significant selectivity ratio of 26.90.

Welcome to talk about 105-13-5, If you have any questions, you can contact Aydin, BO; Anil, D; Demir, Y or send Email.. Category: alcohols-buliding-blocks

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COA of Formula: C8H10O2. Recently I am researching about ALCOHOLS; OLEFINATION; ARYLACETONITRILES; ALKYLATION, Saw an article supported by the SERB, IndiaDepartment of Science & Technology (India)Science Engineering Research Board (SERB), India [CRG/2018/002480]; IISER-Tirupati; SwarnaJayanti Fellowship [DST/SJF/CSA-04/2019-2020, SERB/F/5892/2020-2021]; SERB-PMRF, India; UGC, IndiaUniversity Grants Commission, India. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Midya, SP; Subaramanian, M; Babu, R; Yadav, V; Balaraman, E. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.

Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.. COA of Formula: C8H10O2

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SDS of cas: 105-13-5. Authors Duong, U; Ansari, TN; Parmar, S; Sharma, S; Kozlowski, PM; Jasinski, JB; Plummer, S; Gallou, F; Handa, S in AMER CHEMICAL SOC published article about in [Duong, Uyen; Ansari, Tharique N.; Parmar, Saurav; Sharma, Sudripet; Kozlowski, Pawel M.; Handa, Sachin] Univ Louisville, Dept Chem, Louisville, KY 40292 USA; [Jasinski, Jacek B.] Univ Louisville, Mat Characterizat, Conn Ctr Renewable Energy Res, Louisville, KY 40292 USA; [Plummer, Scott] Novartis Inst Biomed Res, Cambridge, MA 02139 USA; [Gallou, Fabrice] Novartis Pharma AG, CH-4056 Basel, Switzerland in 2021, Cited 34. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Upon visible-light irradiation, the heterogeneous polymer of PDI-Cu(I)-PDI (PDI = perylene diimide) generates charge transfer states that are subsequently quenched by molecular oxygen for their participation in redox activity. This insoluble polymeric Cu(I) is catalytically active for the oxidation of benzylic alcohols to corresponding aldehydes when suspended in dynamic micelles of PS-750-M. A broad substrate scope, excellent selectivity, and no over-oxidation reveal the catalyst robustness. The catalytic activity, control experiments, and time-dependent DFT calculations show the charge transfer states. The polymeric catalyst is entirely recyclable, as evidenced by the recycle studies using Scott’s recyclability test. The morphology, structure, copper’s oxidation state, and the catalyst’s thermal stability are determined by SEM, XPS, and TGA analysis.

Welcome to talk about 105-13-5, If you have any questions, you can contact Duong, U; Ansari, TN; Parmar, S; Sharma, S; Kozlowski, PM; Jasinski, JB; Plummer, S; Gallou, F; Handa, S or send Email.. SDS of cas: 105-13-5

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Formula: C8H10O2. Authors Paul, A; Shipman, MA; Onabule, DY; Sproules, S; Symes, MD in ROYAL SOC CHEMISTRY published article about in [Paul, Avishek; Shipman, Michael A.; Onabule, Dolapo Y.; Sproules, Stephen; Symes, Mark D.] Univ Glasgow, Sch Chem, WestCHEM, Univ Ave, Glasgow G12 8QQ, Lanark, Scotland in 2021, Cited 30. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The enhancement of reactivity inside supramolecular coordination cages has many analogies to the mode of action of enzymes, and continues to inspire the design of new catalysts for a range of reactions. However, despite being a near-ubiquitous class of reactions in organic chemistry, enhancement of the reduction of carbonyls to their corresponding alcohols remains very much underexplored in supramolecular coordination cages. Herein, we show that encapsulation of small aromatic aldehydes inside a supramolecular coordination cage allows the reduction of these aldehydes with the mild reducing agent sodium cyanoborohydride to proceed with high selectivity (ketones and esters are not reduced) and in good yields. In the absence of the cage, low pH conditions are essential for any appreciable conversion of the aldehydes to the alcohols. In contrast, the specific microenvironment inside the cage allows this reaction to proceed in bulk solution that is pH-neutral, or even basic. We propose that the cage acts to stabilise the protonated oxocarbenium ion reaction intermediates (enhancing aldehyde reactivity) whilst simultaneously favouring the encapsulation and reduction of smaller aldehydes (which fit more easily inside the cage). Such dual action (enhancement of reactivity and size-selectivity) is reminiscent of the mode of operation of natural enzymes and highlights the tremendous promise of cage architectures as selective catalysts.

Welcome to talk about 105-13-5, If you have any questions, you can contact Paul, A; Shipman, MA; Onabule, DY; Sproules, S; Symes, MD or send Email.. Formula: C8H10O2

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I found the field of Chemistry very interesting. Saw the article Ruthenium-Catalyzed Synthesis of alpha-Alkylated Ketones and Quinolines in an Aqueous Medium via a Hydrogen-Borrowing Strategy Using Ketones and Alcohols published in 2021. Name: (4-Methoxyphenyl)methanol, Reprint Addresses Elias, AJ (corresponding author), Indian Inst Technol, Dept Chem, New Delhi 110016, India.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Herein, we report a simple, efficient, and sustainable method for the synthesis of alpha-alkylated ketones and quinolines using a hydrogen-borrowing strategy, which has emerged as a greener alternative in organic transformation reactions. Synthesis of a range of alpha-alkylated ketones and quinoline derivatives was achieved by using the water-soluble [Ru(8-AQ)Cl(p-cym.)]Cl-+(-) [Ru]-1 (AQ=aminoquinoline) catalyst with water as the reaction medium. By adopting this strategy, we have synthesized alpha-alkylated ketones and quinolines using ketones or secondary alcohols as starting materials and the primary alcohol as a green and naturally abundant alkylating agent.

Welcome to talk about 105-13-5, If you have any questions, you can contact Verma, A; Hazra, S; Dolui, P; Elias, AJ or send Email.. Name: (4-Methoxyphenyl)methanol

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An article The pattern-recognition molecule H-ficolin in relation to diabetic kidney disease, mortality, and cardiovascular events in type 1 diabetes WOS:000647144000013 published article about MANNOSE-BINDING LECTIN; IMMUNE COMPONENT FICOLIN-3; ALL-CAUSE MORTALITY; VASCULAR COMPLICATIONS; COMPLEMENT; ASSOCIATION; MICROALBUMINURIA; POPULATION; DEFICIENCY; SEVERITY in [Ostergaard, Jakob Appel] Aarhus Univ Hosp, Dept Endocrinol & Internal Med, Aarhus, Denmark; [Ostergaard, Jakob Appel; Hansen, Troels Krarup] Aarhus Univ Hosp, Steno Diabet Ctr Aarhus, Aarhus, Denmark; [Sigfrids, Fanny Jansson; Forsblom, Carol; Dahlstrom, Emma H.; Thorn, Lena M.; Harjutsalo, Valma; Groop, Per-Henrik] Folkhalsan Res Ctr, Folkhalsan Inst Genet, Helsinki, Finland; [Sigfrids, Fanny Jansson; Forsblom, Carol; Dahlstrom, Emma H.; Thorn, Lena M.; Harjutsalo, Valma; Groop, Per-Henrik] Univ Helsinki, Nephrol, Abdominal Ctr, Helsinki, Finland; [Sigfrids, Fanny Jansson; Forsblom, Carol; Dahlstrom, Emma H.; Thorn, Lena M.; Harjutsalo, Valma; Groop, Per-Henrik] Helsinki Univ Hosp, Helsinki, Finland; [Sigfrids, Fanny Jansson; Forsblom, Carol; Dahlstrom, Emma H.; Thorn, Lena M.; Harjutsalo, Valma; Groop, Per-Henrik] Univ Helsinki, Res Program Clin & Mol Metab, Fac Med, Helsinki, Finland; [Thorn, Lena M.] Univ Helsinki, Dept Gen Practice & Primary Hlth Care, Helsinki, Finland; [Harjutsalo, Valma] Natl Inst Hlth & Welf, Helsinki, Finland; [Flyvbjerg, Allan] Capital Reg Denmark, Steno Diabet Ctr Copenhagen, Copenhagen, Denmark; [Thiel, Steffen] Aarhus Univ, Dept Biomed, Aarhus, Denmark; [Groop, Per-Henrik] Monash Univ, Cent Clin Sch, Dept Diabet, Melbourne, Vic, Australia in 2021, Cited 39. Safety of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

H-ficolin recognizes patterns on microorganisms and stressed cells and can activate the lectin pathway of the complement system. We aimed to assess H-ficolin in relation to the progression of diabetic kidney disease (DKD), all-cause mortality, diabetes-related mortality, and cardiovascular events. Event rates per 10-unit H-ficolin-increase were compared in an observational follow-up of 2,410 individuals with type 1 diabetes from the FinnDiane Study. DKD progression occurred in 400 individuals. The unadjusted hazard ratio (HR) for progression was 1.29 (1.18-1.40) and 1.16 (1.05-1.29) after adjustment for diabetes duration, sex, HbA(1c), systolic blood pressure, and smoking status. After adding triglycerides to the model, the HR decreased to 1.07 (0.97-1.18). In all, 486 individuals died, including 268 deaths of cardiovascular causes and 192 deaths of complications to diabetes. HRs for all-cause mortality and cardiovascular mortality were 1.13 (1.04-1.22) and 1.05 (0.93-1.17), respectively, in unadjusted analyses. These estimates lost statistical significance in adjusted models. However, the unadjusted HR for diabetes-related mortality was 1.19 (1.05-1.35) and 1.18 (1.02-1.37) with the most stringent adjustment level. Our results, therefore, indicate that H-ficolin predicts diabetes-related mortality, but neither all-cause mortality nor fatal/non-fatal cardiovascular events. Furthermore, H-ficolin is associated with DKD progression, however, not independently of the fully adjusted model.

Welcome to talk about 105-13-5, If you have any questions, you can contact Ostergaard, JA; Sigfrids, FJ; Forsblom, C; Dahlstrom, EH; Thorn, LM; Harjutsalo, V; Flyvbjerg, A; Thiel, S; Hansen, TK; Groop, PH or send Email.. Safety of (4-Methoxyphenyl)methanol

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Authors Yang, SN; Liu, XY; Lu, SJ; Li, Z; Zhang, YM; Yu, SN; Song, J; Ding, CF; Yang, HY in WILEY-V C H VERLAG GMBH published article about in [Yang, Shouning; Yu, Shaoning; Yang, Huayan] Ningbo Univ, Sch Mat Sci & Chem Engn, Inst Mass Spectrometry, Zhejiang Prov Key Lab Adv Mass Spectrometry & Mol, Ningbo 315211, Zhejiang, Peoples R China; [Zhang, Yanmin; Song, Jian] Henan Normal Univ, Sch Phys, Xinxiang 453007, Henan, Peoples R China; [Yang, Shouning; Liu, Xiaoyang; Lu, Sijia; Li, Zhuo; Yang, Huayan] Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Key Lab Green Chem Media & React, Minist Educ,Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China in 2021, Cited 65. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The development of eco-friendly and low cost catalysts is challenging. Here, heterostructures of Bi2S3 quantum dots (QDs) doped onto ultrathin BiOCl nanosheets were synthesized by a facile hydrothermal method to exploit efficient photosensitizers with appropriate electronic states to enhance the transfer of electrons. The obtained Bi2S3-BiOCl showed highly efficient photocatalytic ability for selective oxidation of aromatic alcohols to aldehydes. More oxygen vacancies are formed on the exposed 001 facet of the ultrathin BiOCl, which can effectively trap electrons and form O-.(2)- radicals. The cooperation between the BiOCl and the Bi2S3 QDs effectively separates photogenerated electron-hole pairs at the heterointerface and facilitates the cooperative actions of O-.(2)- radicals and holes, which brings about a desirable photocatalytic eciency for the selective oxidation of aromatic alcohols. This work highlights the synergistic effect of semiconductor QDs and two-dimensional materials on selective conversion processes and provides a new design paradigm using noble metal-free heteromaterials with high photocatalytic activity. This opens new possibilities for photocatalyst design using heteromaterials with high photocatalytic activity.

Product Details of 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Yang, SN; Liu, XY; Lu, SJ; Li, Z; Zhang, YM; Yu, SN; Song, J; Ding, CF; Yang, HY or send Email.

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In 2021 APPL CATAL B-ENVIRON published article about SELECTIVE AEROBIC OXIDATION; GOLD NANOPARTICLES; ALIPHATIC-ALCOHOLS; ATMOSPHERIC-PRESSURE; OXYGEN ACTIVATION; MOLECULAR-OXYGEN; METHYL-ESTERS; CATALYSTS; REDUCTION; OXIDE in [Wang, Jie; Gu, Xianmo; Pei, Linjuan; Kong, Peng; Zhang, Jin; Wang, Xiaoyu; Wang, Ruiyi; Zheng, Zhanfeng] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China; [Wang, Jie; Pei, Linjuan; Zhang, Jin; Wang, Xiaoyu; Zheng, Zhanfeng] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China; [Waclawik, Eric R.] Queensland Univ Technol, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia in 2021, Cited 61. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Computed Properties of C8H10O2

A series of metal niobates (MNb2O6, M = Zn2+, Ni2+ and Co2+) were prepared from H-niobate precursor under hydrothermal conditions, in which amino groups of L-lysine play an important role. Au nanoparticles were then supported on these niobates by NaBH4 reduction method. More importantly, the strong interaction between Au nanoparticles and ZnNb2O6 generates negatively charged Au which can activate molecular oxygen to form the exclusive high-active peroxide (NbOOAu) species on Au/ZnNb2O6 surface under visible light irradiation, observed in situ by diffuse reflectance infrared Fourier transform spectra (DRIFTS). The optimal NbOOAu species produced on the surface of Au/ZnNb2O6 can remove the H atom of the methylene group (-CH2-) of benzyl alcohol, leading to high photocatalytic activity of Au/ZnNb2O6 compared with Au/NiNb2O6 and Au/CoNb2O6. This modulation of interaction of Au and niobates for the activation of molecular oxygen provides a new prospect for highly selective photocatalytic oxidation reactions.

Welcome to talk about 105-13-5, If you have any questions, you can contact Wang, J; Gu, XM; Pei, LJ; Kong, P; Zhang, J; Wang, XY; Wang, RY; Waclawik, ER; Zheng, ZF or send Email.. Computed Properties of C8H10O2

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