Month: November 2021

An article A new catalytic approach for aerobic oxidation of primary alcohols based on a Copper(I)-thiophene carbaldimines WOS:000670364300005 published article about EFFICIENT; COPPER; REDUCTION; OXYGEN; LIGAND; IRON in [Lagerspets, Emi; Valbonetti, Evelyn; Eronen, Aleksi; Repo, Timo] Univ Helsinki, Dept Chem, AI Virtasen Aukio 1, Helsinki 00014, Finland in 2021, Cited 30. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Computed Properties of C8H10O2

We report here novel Cu(I) thiophene carbaldimine catalysts for the selective aerobic oxidation of primary alcohols to their corresponding aldehydes and various diols to lactones or lactols. In the presence of the in situ generated Cu(I) species, a persistent radical (2,2,6,6-tetramethylpiperdine-N-oxyl (TEMPO)) and N-methylimidazole (NMI) as an auxiliary ligand, the reaction proceeds under aerobic conditions and at ambient temperature. Especially the catalytic system of 1-(thiophen-2-yl)-N-(4-(trifluoromethoxy)phenyl)methanimine (ligand L2) with copper(I)-iodide showed high reactivity for all kind of alcohols (benzylic, allylic and aliphatic). In the case of benzyl alcohol even 2.5 mol% of copper loading gave quantitative yield. Beside high activity under aerobic conditions, the catalysts ability to oxidize 1,5-pentadiol to the corresponding lactol (86% in 4 h) and Nphenyldiethanolamine to the corresponding morpholine derivate lactol (86% in 24 h) is particularly noteworthy.

Welcome to talk about 105-13-5, If you have any questions, you can contact Lagerspets, E; Valbonetti, E; Eronen, A; Repo, T or send Email.. Computed Properties of C8H10O2

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I found the field of Chemistry very interesting. Saw the article Stereoselective 1,4-Addition of Primary Alcohols to gamma-Alkoxy-alpha,beta-unsaturated Esters published in 2021. Safety of (4-Methoxyphenyl)methanol, Reprint Addresses Nakamura, S (corresponding author), Nagoya City Univ, Grad Sch Pharmaceut Sci, Mizuho Ku, 3-1 Tanabe Dori, Nagoya, Aichi 4678603, Japan.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

The scope and limitations of the diastereoselective 1,4-addition reaction of primary alcohols to gamma-alkoxy-alpha,beta-unsaturated esters were investigated. We found that a variety of sodium alkoxides, generated from the corresponding primary alcohols with NaH, underwent 1,4-addition reactions with (E)-enoates in CH(2)Cl(2)at -23 degrees C to give beta-alkoxy esters in modest yields with good to excellentsyn-selectivity, whereas stereoselectivity was not observed with the use of glycerol derivatives as nucleophiles. Cyclic acetal protection was found to play a pivotal role for the reaction to proceed.

Welcome to talk about 105-13-5, If you have any questions, you can contact Inatomi, S; Takayanagi, Y; Watanabe, K; Toita, A; Yamakoshi, H; Nakamura, S or send Email.. Safety of (4-Methoxyphenyl)methanol

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In J PAEDIATR CHILD H published article about INTRAVENOUS IMMUNOGLOBULIN TREATMENT; CORONARY-ARTERY ABNORMALITIES; PREDICTION; RESISTANCE; EFFICACY; THERAPY; PREDNISOLONE; PREVENTION; ANEURYSMS; TRIAL in [Davidson, Hannah; Kelly, Andrew] Univ Adelaide, Womens & Childrens Hosp, Dept Cardiol, Adelaide, SA, Australia; [Agrawal, Rishi] Univ Adelaide, Womens & Childrens Hosp, Dept Gen Paediat Med, Adelaide, SA, Australia; [Kelly, Andrew; Agrawal, Rishi] Univ Adelaide, Fac Hlth & Med Sci, Dept Paediat Adelaide, Adelaide, SA, Australia in , Cited 25. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: 105-13-5

Aim Kawasaki disease (KD) is one of the most common causes of acquired cardiac disease in children in high-income countries. The incidence of coronary artery disease (CAD), despite treatment with intravenous immunoglobulin, ranges from 5 to 20%. Determining risk factors for CAD may assist with management and reduce long-term complications. Methods Retrospective data were collected for all patients presenting to the Women’s and Children’s Hospital with a discharge diagnosis of KD over a 10.5-year period, from 2007 to 2018. Results A total of 141 patients were included in the review; 101 patients fulfilled complete criteria for KD; 25 incomplete criteria and 15 did not meet criteria but were treated for KD. CAD was present in 27.7% of all patients, ranging from ectasia to giant aneurysms based on Z-scores and echocardiogram descriptions. Medium to large aneurysms accounted for 8.5% of all patients with suspected KD. Patients with CAD were more likely to: fulfil incomplete criteria (odds ratio (OR) 4.3, 95% confidence interval (CI) 1.7-10.8, P = 0.0027), be less than 12 months of age (OR 11.38, 95% CI 2.94-44.11, P = 0.0001), have CRP > 100 (OR 2.8, 95% CI 1.31-6.02, P = 0.0068) and have a delay in treatment (average day of illness prior to treatment 8.89 vs. 6.78 (OR 1.19, 95% CI 1.05-1.35, P = 0.0055)). Patients with a Kobayashi score >= 4 had a higher rate of re-treatment with intravenous immunoglobulin (OR 3.16, 95% CI 1.27-7.83, P = 0.013). Conclusion Our data are consistent with previously reported risk factors, and high rates of CAD despite standard treatment.

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Formula: C8H10O2. In 2021 J COORD CHEM published article about AEROBIC OXIDATION; EFFICIENT in [Kurbah, Sunshine Dominic] Pandit Deendayal Upadhyaya Adarsha Mahavidyalaya, Dept Chem, Eraligool 788723, Assam, India in 2021, Cited 47. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

We report the synthesis of a vanadium(V) complex characterized by FT-IR and H-1 NMR spectroscopy. The structure of the complex was established by single crystal X-ray crystallography. We also carried out the catalytic oxidation of benzyl alcohol, hetero-aryl alcohols and propargylic alcohols. Tandem synthesis of oximes from alcohols were also carried out using our vanadium(V) complex. The newly synthesized complex acts as a catalyst for oxidation reactions and tandem synthesis of oxime from alcohols. [GRAPHICS] .

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Computed Properties of C8H10O2. In 2021 APPL CATAL A-GEN published article about SELECTIVE OXIDATION; HIGHLY EFFICIENT; PHOTOCATALYTIC OXIDATION; HYDROGEN EVOLUTION; AROMATIC ALCOHOLS; QUANTUM DOTS; G-C3N4; WATER; BENZALDEHYDE; FABRICATION in [Fernandes, Raquel A.; Sampaio, Maria J.; Da Silva, Eliana S.; Boumeriame, Hanane; Faria, Joaquim L.; Silva, Claudia G.] Univ Porto, Fac Engn, Associate Lab LSRE LCM, Rua Dr Roberto Frias S-N, P-4200465 Porto, Portugal; [Boumeriame, Hanane] Univ Abdelmalek Essaadi, Fac Sci & Tech, Lab Chem Engn & Valorizat Resources LGCVR UAE L01, Tangier, Morocco; [Lopes, Tania; Andrade, Luisa; Mendes, Adelio] Univ Porto, Fac Engn, LEPABE Lab Proc Engn Environm Biotechnol & Energy, Rua Dr Roberto Frias, P-4200465 Porto, Portugal in 2021, Cited 70. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Citric acid-modified graphite-like carbon nitride materials (GCN-zCA) were synthetized by thermal copolymerization of dicyandiamide with different amounts of citric acid (z = between 5 and 25 mg). The resulting materials presented surface porosity, defective polymeric structure, and enhanced visible light absorption in the 450-700 nm range, attributed to the existence of mid-gap states and n-pi* electronic transitions. All the modified catalysts presented high selectivity (>99 %) towards the conversion of p-anisyl alcohol into p-anisaldehyde under visible-LED irradiation, the best performing photocatalyst (GCN-20CA) reaching 63 % yield (contrasting with 22 % obtained with bulk GCN) after 240 min reaction. GCN-20CA was also applied for hydrogen generation from water splitting. The modified material practically duplicated the hydrogen production when compared to bulk GCN (75 and 44 mu mol H-2 evolved in three hours, respectively), by using platinum nanoparticles as co-catalyst and EDTA as sacrificial electron donor. Moreover, p-anisyl alcohol was successfully used as sacrificial agent for water splitting, with simultaneous production of p-anisaldehyde and H-2. Reusability tests showed that GCN-20CA remained stable in a series of consecutive runs both for p-anisaldehyde synthesis and hydrogen production.

Welcome to talk about 105-13-5, If you have any questions, you can contact Fernandes, RA; Sampaio, MJ; Da Silva, ES; Boumeriame, H; Lopes, T; Andrade, L; Mendes, A; Faria, JL; Silva, CG or send Email.. Computed Properties of C8H10O2

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An article Types and spatial contexts of neighborhood greenery matter in associations with weight status in women across 28 US communities WOS:000663724900007 published article about ECOSYSTEM SERVICES; PHYSICAL-ACTIVITY; RESIDENTIAL GREENNESS; OBESITY; SPACE; WALKING; HEALTH; COHORT; CLASSIFICATION; ACCESSIBILITY in [Tsai, Wei-Lun; Rosenbaum, Daniel J.; Prince, Steven E.; Neale, Anne C.; Buckley, Timothy J.; Jackson, Laura E.] US EPA, Off Res & Dev, Res Triangle Pk, NC 27711 USA; [Nash, Maliha S.] US EPA, Off Res & Dev, Newport, OR USA; [D’Aloisio, Aimee A.] Social & Sci Syst, Durham, NC USA; [Sandler, Dale P.] NIEHS, POB 12233, Res Triangle Pk, NC 27709 USA in 2021, Cited 72. Computed Properties of C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Excess body weight is a risk factor for many chronic diseases. Studies have identified neighborhood greenery as supportive of healthy weight. However, few have considered plausible effect pathways for ecosystem services (e. g., heat mitigation, landscape aesthetics, and venues for physical activities) or potential variations by climate. This study examined associations between weight status and neighborhood greenery that capture ecosystem services most relevant to weight status across 28 U.S. communities. Weight status was defined by body mass index (BMI) reported for 6591 women from the U.S. Sister Study cohort. Measures of greenery within street and circular areas at 500 m and 2000 m buffer distances from homes were derived for each participant using 1 m land cover data. Street area was defined as a 25 m-wide zone on both sides of street centerlines multiplied by the buffer distances, and circular area was the area of the circle centered on a home within each of the buffer distances. Measures of street greenery characterized the pedestrian environment to capture physically and visually accessible greenery for shade and aesthetics. Circular greenery was generated for comparison. Greenery types of tree and herbaceous cover were quantified separately, and a combined measure of tree and herbaceous cover (i.e., aggregate greenery) was also included. Mixed models accounting for the clustering at the community level were applied to evaluate the associations between neighborhood greenery and the odds of being overweight or obese (BMI > 25) with adjustment for covariates selected using gradient boosted regression trees. Analyses were stratified by climate zone (arid, continental, and temperate). Tree cover was consistently associated with decreased odds of being overweight or obese. For example, the adjusted odds ratio [AOR] was 0.92, 95% Confidence Interval [CI]: 0.88-0.96, given a 10% increase in street tree cover at the 2000 m buffer across the 28 U.S. communities. These associations held across climate zones, with the lowest AOR in the arid climate (AOR: 0.74, 95% CI: 0.54-1.01). In contrast, associations with herbaceous cover varied by climate zone. For the arid climate, a 10% increase in street herbaceous cover at the 2000 m buffer was associated with lower odds of being overweight or obese (AOR: 0.75, 95% CI: 0.55-1.03), whereas the association was reversed for the temperate climate, the odds increased (AOR: 1.19, 95% CI: 1.05-1.35). Associations between greenery and overweight/obesity varied by type and spatial context of greenery, and climate. Our findings add to a growing body of evidence that greenery design in urban planning can support public health. These findings also justify further defining the mechanism that underlies the observed associations.

Computed Properties of C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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I found the field of Environmental Sciences & Ecology very interesting. Saw the article Properties and Assessment of Applications of Red Mud (Bauxite Residue): Current Status and Research Needs published in 2021. Name: (4-Methoxyphenyl)methanol, Reprint Addresses Rao, BH (corresponding author), ITT Bhubaneswar, Sch Infrastruct, Khorda 752050, Odisha, India.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

In order to conserve natural resources and prevent waste generation, effective utilization of industrial wastes and/or by-products for beneficial engineering applications becomes inevitable. In order to accomplish this, extensive research studies, exploring properties and new applications of waste materials in a sustainable and environmentally friendly manner, have been initiated worldwide. Red mud (RM, also known as bauxite residue) is one of the wastes generated by the aluminium industry and its disposal and utilization have been traditionally hindered due to the extreme alkalinity (pH about 10.5-13.5). To date, no comprehensive review on various properties of RM of different origin and associated challenges in using it as a beneficial engineering material has been performed. The objective of this study is first to critically appraise the current understanding of properties of RM through a comprehensive literature review and detailed laboratory investigations conducted on Indian RM by the authors, to assess and identify the potential engineering applications, and to finally discuss associated challenges in using it in practical applications. Physical, chemical, mineralogical and geotechnical properties of RMs of different origin and production processes are reviewed. Mechanisms behind the pozzolanic reaction of RM under different chemical and mineralogical compositional conditions are discussed. Environmental concerns associated with the use of RM are also raised. Studies relevant to leachability characteristics reveal that most of the measured chemical concentrations are within the permissible regulatory limits. Overall, the review shows that RM disposal and reuse is complicated by its extreme alkalinity, which is also noticed to be influencing multiple engineering properties. But with selected pH amendments, the treated RM is found to have significant potential to be used as an effective and sustainable geomaterial. The assessment is majorly based on the characteristics of Indian RMs; hence the adaptation of the findings to other RMs should be assessed on a case-by-case basis. Moreover, field studies demonstrating the performance of RM in various engineering applications are warranted. [GRAPHICS] .

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Product Details of 105-13-5. Recently I am researching about SELECTIVE OXIDATION; HIGHLY EFFICIENT; COPPER NANOPARTICLES; GALACTOSE-OXIDASE; GRAPHENE OXIDE; COMPLEXES; LIGAND; CONVERSION; CHEMISTRY; SYSTEM, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21571083]; Natural Science Foundation of Zhejiang ProvinceNatural Science Foundation of Zhejiang Province [LY18B010007, LY19B010001]; Government of Zhejiang Province (Qianjiang Professorship); Jiaxing University (Summit Program of Jiaxing University ); Municipal Government of Jiaxing. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Senthilkumar, S; Zhong, W; Natarajan, M; Lu, CX; Xu, BY; Liu, XM. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

An efficient and green protocol for aerobic oxidation of benzylic alcohols in ethanol using Cu-I-Y zeolite catalysts assisted by TEMPO (TEMPO = 2,2,6,6-tetramethyl-1-piperidine-N-oxyl) as the radical co-catalyst in the presence of atmospheric air under mild conditions is reported. The Cu-I-Y zeolite prepared via ion exchange between CuCl and HY zeolite was fully characterized by a variety of spectroscopic techniques including XRD, XPS, SEM, EDX and HRTEM. The incorporation of Cu(i) into the 3D-framework of the zeolite rendered the catalyst with good durability. The results of repetitive runs revealed that in the first three runs, there was hardly a decline in activity and a more substantial decrease in yield was observed afterwards, while the selectivity remained almost unchanged. The loss in activity was attributed to both the formation of CuO and the bleaching of copper into the liquid phase during the catalysis, of which the formation of CuO was believed to be the major contributor since the bleaching loss for each run was negligible (<2%). In this catalytic system, except TEMPO, no other additives were needed, either a base or a ligand, which was essential in some reported catalytic systems for the oxidation of alcohols. The aerobic oxidation proceeded under mild conditions (60 degrees C, and 18 hours) to quantitatively and selectively convert a wide range of benzylic alcohols to corresponding aldehydes, which shows great potential in developing green and environmentally benign catalysts for aerobic oxidation of alcohols. The system demonstrated excellent tolerance against electron-withdrawing groups on the phenyl ring of the alcohols and showed sensitivity to steric hindrance of the substrates, which is due to the confinement of the pores of the zeolite in which the oxidation occurred. Based on the mechanism reported in the literature for homogenous oxidation, a mechanism was analogously proposed for the aerobic oxidation of benzylic alcohols catalysed by this Cu(i)-containing zeolite catalyst. Product Details of 105-13-5. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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An article OH/Na co-functionalized carbon nitride: directional charge transfer and enhanced photocatalytic oxidation ability WOS:000509894100024 published article about FACILE SYNTHESIS; REACTANTS ACTIVATION; NO ADSORPTION; DOPED G-C3N4; EFFICIENT; NANOSHEETS; ZIRCONIA; REACTIVITY; VACANCIES; MECHANISM in [Wang, Jiadong; Chen, Ruimin; Yuan, Chaowei; Dong, Fan; Sun, Yanjuan] Chongqing Technol & Business Univ, Coll Environm & Resources, Chongqing Key Lab Catalysis & New Environm Mat, Chongqing 400067, Peoples R China; [Wang, Jiadong; Cui, Wen; He, Ye; Yuan, Chaowei; Sheng, Jianping; Li, Jieyuan; Dong, Fan; Sun, Yanjuan] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Res Ctr Environm Sci & Technol, Chengdu 611731, Peoples R China; [Cui, Wen] Southwest Petr Univ, Sch Mat Sci & Engn, Ctr New Energy Mat & Thchnol, Chengdu 610500, Peoples R China; [Zhan, Yuxin] Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China in 2020, Cited 60. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Product Details of 105-13-5

Graphitic carbon nitride (g-C3N4, CN for short) is a compelling visible-light responsive photocatalyst. However, its photocatalytic efficiency is low due to the random carrier transfer in planes and insufficient redox potential. Herein, we build oxygen functional group modified sodium-doped carbon nitride (OH/Na co-functionalized carbon nitride) to promote directional transfer of charge carriers for acceleration of separation and enhance redox potential for efficient oxidation of NO in air. Specifically, the function of sodium atoms could control the directional transfer of random carriers from the intralayer to the oxygen functional group-modified surface for the purpose of effectively reducing photogenerated electron-hole recombination. Meanwhile, the modification by oxygen-containing functional groups could adjust the band structure of CN, thereby increasing the oxidation-reduction potential of NO in the photocatalyst. The transformation pathways and reaction mechanism of photocatalytic NO oxidation on CN and OH/Na co-functionalized carbon nitride have also been explicated by ESR spectroscopy and in situ DRIFTS and compared. This work provides a new method for simultaneously controlling the random transfer of carriers and adjusting the energy band structure of CN to optimize its photocatalytic efficiency. It is also possible to extend this strategy to improve the performance of other 2D layered catalysts for photocatalytic oxidation.

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An article Electrochemical Arylation of Aldehydes, Ketones, and Alcohols: from Cathodic Reduction to Convergent Paired Electrolysis WOS:000621048400001 published article about C-H FUNCTIONALIZATION; PHOTOREDOX CATALYSIS; CARBONYL-COMPOUNDS; COUPLING REACTIONS; NICKEL CATALYSIS; GRIGNARD; HYDROGEN; HALIDES; IMINES; REAGENTS in [Zhang, Sheng; Li, Lijun; Li, Jingjing; Shi, Jianxue; Xu, Kun; Gao, Wenchao; Zong, Luyi] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Engn Technol Res Ctr Henan Prov Photo & Electroch, Nanyang, Peoples R China; [Li, Guigen; Findlater, Michael] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79423 USA in 2021, Cited 67. Safety of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Arylation of carbonyls, one of the most common approaches toward alcohols, has received tremendous attention, as alcohols are important feedstocks and building blocks in organic synthesis. Despite great progress, there is still a great gap to develop an ideal arylation method featuring mild conditions, good functional group tolerance, and readily available starting materials. We now show that electrochemical arylation can fill the gap. By taking advantage of synthetic electrochemistry, commercially available aldehydes (ketones) and benzylic alcohols can be readily arylated to provide a general and scalable access to structurally diverse alcohols (97 examples, >10 gram-scale). More importantly, convergent paired electrolysis, the ideal but challenging electrochemical technology, was employed to transform low-value alcohols into more useful alcohols. Detailed mechanism study suggests that two plausible pathways are involved in the redox neutral alpha-arylation of benzylic alcohols.

Welcome to talk about 105-13-5, If you have any questions, you can contact Zhang, S; Li, LJ; Li, JJ; Shi, JX; Xu, K; Gao, WC; Zong, LY; Li, GG; Findlater, M or send Email.. Safety of (4-Methoxyphenyl)methanol

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