Month: November 2021

An article Nickel-catalyzed C3-alkylation of indoles with alcohols via a borrowing hydrogen strategy WOS:000651900200001 published article about C BOND FORMATION; ALPHA-ALKYLATION; UNACTIVATED AMIDES; KETONES; METHYLATION; ESTERS; ARYLACETONITRILES; FUNCTIONALIZATION; COMPLEXES; METHANOL in [Hu, Miao; Jiang, Yong; Sun, Nan; Hu, Baoxiang; Shen, Zhenlu; Hu, Xinquan; Jin, Liqun] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Peoples R China; [Jin, Liqun] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China in 2021, Cited 65. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Quality Control of (4-Methoxyphenyl)methanol

An efficient method for the Ni-catalyzed C3-alkylation of indoles using readily available alcohols as the alkylating reagents has been developed. The alkylation was addressed with an air and moisture-stable binuclear nickel complex ligated by tetrahydroquinolin-8-one as the effective pre-catalyst. The newly developed transformation could accommodate a broad substrate scope including primary/secondary benzylic and aliphatic alcohols and substituted indoles. Mechanistic studies suggested that the reaction proceeds through a borrowing hydrogen pathway.

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Application In Synthesis of (4-Methoxyphenyl)methanol. Recently I am researching about CONJUGATED MICROPOROUS POLYMERS; AEROBIC OXIDATION; ORGANIC FRAMEWORKS; CATALYTIC-SYSTEM; SUPPORTED TEMPO; CORE-SHELL; SPHERES; DESIGN, Saw an article supported by the National Key Research and Development Program of China [2017YFF0204602]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21861013]; Natural Science Foundation of Guizhou Province [20185769]; Department of Education of Guizhou Province [YJSCXJH (2019)045]; State Key Laboratory of Physical Chemistry of Solid Surfaces (Xiamen University)Xiamen University [201823]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Shen, YM; Xue, Y; Yan, M; Mao, HL; Cheng, H; Chen, Z; Sui, ZW; Zhu, SB; Yu, XJ; Zhuang, JL. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A bottom-up approach was developed to prepare TEMPO radical decorated hollow aromatic frameworks (HPAF-TEMPO) by using TEMPO radical functionalized monomers and SiO2 nanospheres as templates. The accessible inner layer, high density of TEMPO sites, and hybrid micro-/mesopores of the HPAF-TEMPO enable the aerobic oxidation of a broad range of alcohols with high efficiency and excellent selectivity.

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An article Engineered Superparamagnetic Core-Shell Metal-Organic Frame-Work (Fe3O4@Ni-Co-BTC NPs) with Enhanced Photocatalytic Activity for Selective Aerobic Oxidation of Alcohols Under Solar Light Irradiation WOS:000543030400002 published article about BENZYL ALCOHOL; EFFICIENT CATALYST; AROMATIC ALCOHOLS; GRAPHENE OXIDE; NANOPARTICLES; PERFORMANCE; WATER; OXYGEN; BI2WO6; MOF in [Mohammadinezhad, Arezou; Akhlaghinia, Batool] Ferdowsi Univ Mashhad, Fac Sci, Dept Chem, Mashhad 9177948974, Razavi Khorasan, Iran in 2021, Cited 70. Name: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

This paper reported an environmentally benign strategy for the synthesis of a magnetic metal-organic framework (Fe3O4@Ni-Co-BTCNPs) via a multi-step procedure. The catalytic performance of Fe3O4@Ni-Co-BTCNPs was evaluated in the selective aerobic oxidation of alcohol substrates (including primary and secondary aliphatic and benzylic alcohols) in water and under solar light irradiation. [GRAPHICS] .

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An article Electrochemical Arylation of Aldehydes, Ketones, and Alcohols: from Cathodic Reduction to Convergent Paired Electrolysis WOS:000621048400001 published article about C-H FUNCTIONALIZATION; PHOTOREDOX CATALYSIS; CARBONYL-COMPOUNDS; COUPLING REACTIONS; NICKEL CATALYSIS; GRIGNARD; HYDROGEN; HALIDES; IMINES; REAGENTS in [Zhang, Sheng; Li, Lijun; Li, Jingjing; Shi, Jianxue; Xu, Kun; Gao, Wenchao; Zong, Luyi] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Engn Technol Res Ctr Henan Prov Photo & Electroch, Nanyang, Peoples R China; [Li, Guigen; Findlater, Michael] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79423 USA in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Safety of (4-Methoxyphenyl)methanol

Arylation of carbonyls, one of the most common approaches toward alcohols, has received tremendous attention, as alcohols are important feedstocks and building blocks in organic synthesis. Despite great progress, there is still a great gap to develop an ideal arylation method featuring mild conditions, good functional group tolerance, and readily available starting materials. We now show that electrochemical arylation can fill the gap. By taking advantage of synthetic electrochemistry, commercially available aldehydes (ketones) and benzylic alcohols can be readily arylated to provide a general and scalable access to structurally diverse alcohols (97 examples, >10 gram-scale). More importantly, convergent paired electrolysis, the ideal but challenging electrochemical technology, was employed to transform low-value alcohols into more useful alcohols. Detailed mechanism study suggests that two plausible pathways are involved in the redox neutral alpha-arylation of benzylic alcohols.

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An article Tungsten-Catalyzed Direct N-Alkylation of Anilines with Alcohols WOS:000605642300001 published article about BORROWING HYDROGEN; ALPHA-ALKYLATION; AROMATIC-AMINES; BOND FORMATION; COMPLEXES; EFFICIENT; KETONES; STRATEGY; LIGANDS; IMINES in [Lan, Xiao-Bing; Ye, Zongren; Yang, Chenhui; Li, Weikang; Liu, Jiahao; Huang, Ming; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Mat Sci & Engn, PCFM Lab, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China; [Lan, Xiao-Bing] Xiangnan Univ, Sch Chem & Biol & Environm Engn, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423000, Hunan, Peoples R China in 2021, Cited 63. Quality Control of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The implementation of non-noble metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of non-noble metal catalysts. Herein, we report a tungsten-catalyzed N-alkylation reaction of anilines with primary alcohols via BH/HA. This phosphine-free W(phen)(CO)(4) (phen=1,10-phenthroline) system was demonstrated as a practical and easily accessible in-situ catalysis for a broad range of amines and alcohols (up to 49 examples, including 16 previously undisclosed products). Notably, this tungsten system can tolerate numerous functional groups, especially the challenging substrates with sterically hindered substituents, or heteroatoms. Mechanistic insights based on experimental and computational studies are also provided.

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I found the field of Chemistry very interesting. Saw the article Iron-Catalyzed Hydrogen Transfer Reduction of Nitroarenes with Alcohols: Synthesis of Imines and Aza Heterocycles published in 2021. Recommanded Product: 105-13-5, Reprint Addresses Darcel, C (corresponding author), Univ Rennes, CNRS ISCR, Inst Sci Chim Rennes, UMR 6226, F-35000 Rennes, France.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A straightforward and selective reduction of nitroarenes with various alcohols was efficiently developed using an iron catalyst via a hydrogen transfer methodology. This protocol led specifically to imines in 30-91% yields, with a good functional group tolerance. Noticeably, starting from o-nitroaniline derivatives, in the presence of alcohols, benzimidazoles can be obtained in 64-72% yields when the reaction was performed with an additional oxidant, DDQ, and quinoxalines were prepared from 1,2-diols in 28-96% yields. This methodology, unprecedented at iron for imines, also provides a sustainable alternative for the preparation of quinoxalines and benzimidazoles.

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An article Novel oxovanadium and dioxomolybdenum complexes of tridentate ONO-donor Schiff base ligand: Synthesis, characterization, crystal structures, Hirshfeld surface analysis, DFT computational studies and catalytic activity for the selective oxidation of benzylic alcohols WOS:000652819900001 published article about AEROBIC OXIDATION; CIS-DIOXOMOLYBDENUM(VI) COMPLEXES; MOLYBDENUM(VI) COMPLEX; HYDROGEN-PEROXIDE; MOLECULAR-OXYGEN; SC-XRD; EPOXIDATION; METAL; EFFICIENT; BENZALDEHYDE in [Kargar, Hadi] Ardakan Univ, Dept Chem Engn, Fac Engn, POB 184, Ardakan, Iran; [Forootan, Pooran; Fallah-Mehrjardi, Mehdi; Behjatmanesh-Ardakani, Reza] Payame Noor Univ, Dept Chem, Tehran 193953697, Iran; [Rudbari, Hadi Amiri] Univ Isfahan, Dept Chem, Esfahan 8174673441, Iran; [Munawar, Khurram Shahzad] Univ Sargodha, Dept Chem, Punjab, Pakistan; [Munawar, Khurram Shahzad] Univ Mianwali, Dept Chem, Mianwali, Pakistan; [Ashfaq, Muhammad; Tahir, Muhammad Nawaz] Univ Sargodha, Dept Phys, Punjab, Pakistan in 2021, Cited 98. Category: alcohols-buliding-blocks. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Two new oxovanadium and dioxomolybdenum Schiff base complexes, [VvO(L)(OCH3)(CH3OH)] and [MoVIO2(L) (CH2CH3OH)], were synthesized by treating an ONO-donor type Schiff base ligand (H2L) derived by condensation of 5-nitrosalicylaldehyde and nicotinic hydrazide with oxo and dioxo acetylacetonate salts of vanadium and molybdenum, [VO(acac)2 and MoO2(acac)2], respectively. The synthesized ligand and complexes were characterized by various spectroscopic techniques like FT-IR, multinuclear (1H, 13C) NMR, elemental analysis and the most authentic single crystal X-ray diffraction analysis. In both complexes the geometry around the central metal ions was distorted octahedral as revealed by the data collected from diffraction studies. Theoretical calculation of the synthesized compounds were carried out by DFT as well as TD-DFT using B3LYP method by employing the Def2-TZVP basis set. The findings of theoretical data indicated that the calculated results are in accordance with the experimental findings. Moreover, the catalytic efficiencies of both complexes were investigated by oxidizing the benzylic alcohols in the presence of urea hydrogen peroxide (UHP) in acetonitrile.

Category: alcohols-buliding-blocks. Welcome to talk about 105-13-5, If you have any questions, you can contact Kargar, H; Forootan, P; Fallah-Mehrjardi, M; Behjatmanesh-Ardakani, R; Rudbari, HA; Munawar, KS; Ashfaq, M; Tahir, MN or send Email.

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Product Details of 105-13-5. Zeng, M; Lou, CL; Xue, JW; Jiang, HW; Li, KW; Chen, ZQ; Fu, ST; Yin, GC in [Zeng, Miao; Lou, Chenlin; Xue, Jing-Wen; Jiang, Hongwu; Li, Kaiwen; Chen, Zhuqi; Fu, Shitao; Yin, Guochuan] Huazhong Univ Sci & Technol, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Mat Chem Energy Convers & Storage, Sch Chem & Chem Engn,Minist Educ, Wuhan 430074, Peoples R China published Palladium (II)-catalyzed homogeneous alcohol oxidations: Disclosing the crucial contribution of palladium nanoparticles in catalysis in 2021, Cited 35. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Versatile redox catalysts play the significant roles in alcohol oxidations, in which the mechanisms for homogeneous and heterogeneous alcohol oxidations are generally different. This work introduced a Lewis acid (LA) promoted homogeneous alcohol oxidation with Pd (OAc)(2) catalyst by using oxygen balloon as the oxidant source. It was found that adding Lewis acid such as Sc (OTf)(3) significantly accelerated Pd (II)-catalyzed alcohol oxidations; notably, the time courses of oxidations monitored by GC and H-1 NMR disclosed that there existed two processes including the initial sluggish oxidation followed by a rapid oxidation. The promotional effect of Lewis acid was attributed to the formation of heterobimetallic Pd (II)/LA species, which improved the oxidizing power of the palladium (II) species, thus accelerating alcohol oxidation in the induction period. Correlating the sizes of in situ generated palladium nanoparticles with the time course of alcohol oxidation further disclosed that the loosely, spherically large nanoparticles, which were composed of many tiny nanoparticles having the size less than 10 nm, were responsible for the rapid oxidation, whereas those highly dispersed, tiny nanoparticles having the size less than 10 nm were not responsible for the rapid oxidation.

Product Details of 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Zeng, M; Lou, CL; Xue, JW; Jiang, HW; Li, KW; Chen, ZQ; Fu, ST; Yin, GC or send Email.

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Authors Yoshida, Y; Kukita, M; Omori, K; Mino, T; Sakamoto, M in ROYAL SOC CHEMISTRY published article about in [Yoshida, Yasushi; Kukita, Mayu; Omori, Kazuki; Mino, Takashi; Sakamoto, Masami] Chiha Univ, Grad Sch Engn, Mol Chiral Res Ctr, Inage Ku, 1-33 Yayoi Cho, Chiba, Chiba 2638522, Japan in 2021, Cited 96. SDS of cas: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Umpolung reactions of imines, especially the asymmetric reactions, have been extensively studied as they provide access to important chiral amines in an efficient manner. The reactions studied range from simple Michael reactions to several kinds of other reactions such as the aza-benzoin reaction, aza-Stetter reaction, addition with MBH carbonate, and Ir-catalysed allylation. Herein, we report the first umpolung alkylation reaction of alpha-iminoesters with alkyl halides mediated by iminophosphorane as an organic superbase. The desired products were obtained in up to 82% yield with almost perfect regioselectivities. The key to the regioselectivity of this reaction was the use of 4-trifluoromethyl benzyl imines as a substrate. The products were successfully derivatised into the more functionalised molecules in good yields.

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Recently I am researching about N,N-DIMETHYLFORMAMIDE-STABILIZED PALLADIUM NANOCLUSTERS; ALPHA-ALKYLATION; BORROWING HYDROGEN; GUERBET REACTION; N-BUTANOL; METHYLATION; KETONES; METHANOL; DIMETHYLFORMAMIDE; ALPHA,OMEGA-DIOLS, Saw an article supported by the JSPS KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [19K05573]. Formula: C8H10O2. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Kobayashi, M; Yamaguchi, H; Suzuki, T; Obora, Y. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A simple method for the cross beta-alkylation of linear alcohols with benzyl alcohols in the presence of DMF-stabilized iridium nanoparticles was developed. The nanoparticles were prepared in one-step and thoroughly characterized. Furthermore, the optimum reaction conditions have a wide substrate scope and excellent product selectivity.

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